Abstract
The results of theoretical analysis of the properties of crystal structure and bonding in relation to thermal decomposition process in chosen anhydrous metal oxalates (Cd, Co, Zn) are presented. The methods used in this analysis — the Bader’s quantum theory of atoms in molecules and bond order model (as defined by Cioslowski and Mixon), applied to topological properties of the electron density, obtained from DFT calculations performed by Wien2k package (full potential linearized augmented plane wave method), as well as Brown’s bond valence model (bonds valences and strengths, and bond and crystal strains, calculated from crystal structure and bonds lengths data) are described.
Presented results allow us to state, that these methods, when used simultaneously, make possible the description and analysis of the crystal structure and bonding properties and give us the additional insight into its behavior during thermal decomposition process. The proposed theoretical approach can be considered as promising and reliable tool for theoretical analysis, allowing explanation and prediction of the properties of the structure and bonding and hence the most probable way of thermal decomposition process to take place in such structure.
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Y. D. Kondrashev, V. S. Bogdanov, S. N. Golubev and G. F. Pron, Zh. Struct. Khim., 26 (1985) 90.
E. Jeanneau, N. Audebrand and D. Louer, Acta Cryst., C57 (2001) 1012.
B. Małecka, E. Drożdż-Cieśla and A. Małecki, Thermochim. Acta, 423 (2004) 13.
M. E. Brown, D. Dollimore and A. K. Galwey, Comprehensive Chemical Kinetics, Vol. 22. Reactions In Solid State, C. H. Bamford and C. F. H. Tipper, Eds, Amsterdam, Elsevier 1980.
V. V. Boldyrev, I. S. Nevyantsev, Y. I. Mikhailov and E. F. Khayretdinov, Kinet. Katal., 11 (1970) 367.
H. J. Borchardt and F. Daniels, J. Am. Chem. Soc., 79 (1957) 41.
D. Dollimore, Thermochim. Acta, 117 (1987) 331.
B. S. Randhawa and M. Kaur, J. Therm. Anal. Cal., 89 (2007) 251.
A. K. Galwey and M. E. Brown, J. Therm. Anal. Cal., 90 (2007) 9.
J. Fujita, K. Nakamoto and M. Kobayashi, J. Phys. Chem., 61 (1957) 1014.
S. Rane, H. Uskaikar, R. Pednekar and R. Mhalsikar, J. Therm. Anal. Cal., 90 (2007) 627.
R. F. W. Bader, Atoms in Molecules: A Quantum Theory, Clarendon Press, Oxford 1990.
L. Pauling, J. Am. Chem. Soc., 51 (1929) 1010.
I. D. Brown, The Chemical Bond in Inorganic Chemistry. The Bond Valence Model, Oxford University Press, 2002.
A. Koleżyński and A. Małecki, J. Therm. Anal. Cal., 96 (2009) 161.
A. Koleżyński and A. Małecki, J. Therm. Anal. Cal., 96 (2009) 167.
A. Koleżyński and A. Małecki, J. Therm. Anal. Cal., DOI: 10.1007/s10973-008-9494-0.
P. Blaha, K. Schwarz, G. K. H. Madsen, D. Kvasnicka and J. Luitz, WIEN2k, An Augmented Plane Wave+Local Orbitals Program for Calculating Crystal Properties (Karlheinz Schwarz, Techn. Universität Wien, Austria), ISBN 3-9501031-1-2, (2001).
J. C. Slater, Phys. Rev., 51 (1937) 151.
T. L. Loucks, Augmented Plane Wave Method, Benjamin, New York 1967.
O. K. Andersen, Solid State Commun., 13 (1973) 133.
D. R. Hamann, Phys. Rev. Lett., 42 (1979) 662.
E. Wimmer, H. Krakauer, M. Weinert and A. J. Freeman, Phys. Rev., B24 (1981) 864.
D. J. Singh, Planewaves, Pseudopotentials and the LAPW Method, Kluwer Academic Publishers, Dordrecht 1994.
J. P. Perdew, K. Burke and M. Ernzerhof, Phys. Rev. Lett., 77 (1996) 3865.
A. Koleżyński, E. Cieśla-Drożdż and B. Handke, sent to Acta Cryst. C.
J. Cioslowski and S. T. Mixon, J. Am. Chem. Soc., 113 (1991) 4142.
S. T. Howard and O. Lamarche, J. Phys. Org. Chem., 16 (2003) 133.
J. L. Jules and J. R. Lombardi, J. Mol. Struct. (Teochem), 664–665 (2003) 255.
R. F. W. Bader, T. S. Slee, D. Cremer and E. Kraka, J. Am. Chem. Soc., 105 (1983) 5061.
L. Pauling, The Nature of the Chemical Bond, Cornell University Press, Ithaca, New York 1960.
A. Byström and K. A.Wilhelmi, Acta Chem. Scand., 5 (1951) 1003.
W. H. Zachariasen, Acta Cryst., 7 (1954) 795.
J. V. Smith, Am. Mineral., 38 (1953) 643.
G. Donnay and R. Allmann, Am. Mineral., 55 (1970) 1003.
R. Allmann, Monatsh. Chem., 106 (1975) 779.
W. H. Zachariasen, J. Less-Common Met., 62 (1978) 1.
V. S. Urusov and I. P. Orlov, Crystall. Rep., 44 (1999) 686.
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Koleżyński, A., Małecki, A. Theoretical approach to thermal decomposition process of chosen anhydrous oxalates. J Therm Anal Calorim 97, 77–83 (2009). https://doi.org/10.1007/s10973-008-9718-3
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DOI: https://doi.org/10.1007/s10973-008-9718-3