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Polymorphism and thermal decomposition of [Ni(DMSO)4]I2

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Abstract

Tetrakis(dimethyl sulphoxide)nickel(II) bis(iodide) was studied by thermogravimetry (TG) and simultaneous differential thermal analysis (SDTA) and differential scanning calorimetry (DSC). The gaseous products of the decomposition were on-line identified by a quadrupole mass spectrometer (QMS). Thermal decomposition of the title compound proceeds in three main stages. In the first stage, which starts just above ca. 419 K, the compound loses two dimethyl sulphoxide (DMSO) molecules per one formula unit and small amount of iodide ion. In the second stage (464–552 K) the next DMSO ligands and the iodide ion simultaneously are released. In the last stage (552–900 K) NiSO4 is created which next decomposes to NiO and SO3.

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References

  1. A. Migdał-Mikuli, E. Mikuli, E. Szostak and J. Serwońska, Z. Naturforsch., 58a (2003) 341.

    Google Scholar 

  2. A. Migdał-Mikuli and E. Szostak, Thermochim. Acta, 426 (2005) 191.

    Article  Google Scholar 

  3. A. Migdał-Mikuli and E. Szostak, Z. Naturforsch., 60a (2005) 289.

    Google Scholar 

  4. A. Migdał-Mikuli, Ł. Skoczylas and E. Szostak, Z. Naturforsch., 61a (2006) 180.

    Google Scholar 

  5. A. Migdał-Mikuli and E. Szostak, Thermochim. Acta, 444 (2006) 195.

    Article  Google Scholar 

  6. E. Szostak, W. Nitek and A. Migdał-Mikuli, Acta Cryst., E 62 (2006) m2581.

    Google Scholar 

  7. A. Migdał-Mikuli and E. Szostak, Z. Naturforsch., 62a (2007) 67.

    Google Scholar 

  8. A. Migdał-Mikuli and N. Górska, J. Therm. Anal. Cal., 90 (2007) 833.

    Article  Google Scholar 

  9. Raman/IR Atlas, Verlag Chemie GmbH, Weinheim, Bergstr., 1974.

  10. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part B, 5th Ed., A. Wiley Intersience Publ., NY 1997.

    Google Scholar 

  11. N. T. Madhu, P.K. Radhakrishnan and W. Linert, J. Therm. Anal. Cal., 84 (2006) 607.

    Article  CAS  Google Scholar 

  12. D. A. Blank, S. W. North, D. Stranges, A. G. Suits and T. Yuan, J. Chem. Phys., 106 (1997) 539.

    Article  CAS  Google Scholar 

  13. S. G. Smith and S. Winstein, Tetrahedron, 3 (1958) 317.

    Article  CAS  Google Scholar 

  14. A. T. J. Klein and M. Holschbach, Appl. Radiat. Isot., 55 (2001) 309.

    Article  CAS  Google Scholar 

  15. M. Mori, K. Tanaka, H. Taoda, M. Ikedo and H. Itabashi, Talanta, 70 (2006) 169.

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Chemical Physics, Faculty of Chemistry, Jagiellonian University, ulica Ingardena 3, 30-060, Kraków, Poland

    Anna Migdał-Mikuli, Elżbieta Szostak, K. Drużbicki & Diana Dołȩga

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  1. Anna Migdał-Mikuli
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  2. Elżbieta Szostak
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  3. K. Drużbicki
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  4. Diana Dołȩga
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Correspondence to Anna Migdał-Mikuli.

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Migdał-Mikuli, A., Szostak, E., Drużbicki, K. et al. Polymorphism and thermal decomposition of [Ni(DMSO)4]I2 . J Therm Anal Calorim 93, 853–856 (2008). https://doi.org/10.1007/s10973-008-9304-8

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  • DOI: https://doi.org/10.1007/s10973-008-9304-8

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