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Reactivity of the oxides in the ternary V2O5-CuO-α-Sb2O4 system in air

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Abstract

In this work it has been established which compounds finally are formed in air in the two-component CuO-V2O5 and CuO-α-Sb2O4 systems. Unknown thermal properties of CuV2O6, Cu2V2O7 and Cu11V6O26 have been established. Reactivity of the oxides and phase relations in the ternary V2O5-CuO-α-Sb2O4 system in air have been studied by using XRD and DTA methods. The results have showed the reaction of V2O5, CuO with α-Sb2O4 does not produce any compound where all the three oxides would be involved. It has been established that the α-Sb2O4 reacts and forms binary phases independently with CuO or V2O5. On the base of these results the investigated system was divided into subsidiary subsystem in which CuSb2O6 remains at equilibrium in the solid state with other phases formed in corresponding binary systems.

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Authors and Affiliations

  1. Department of Inorganic and Analytical Chemistry, Szczecin University of Technology, al. Piastów 42, 71-065, Szczecin, Poland

    Grażyna Dąbrowska & Elżbieta Filipek

Authors
  1. Grażyna Dąbrowska
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  2. Elżbieta Filipek
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Correspondence to Grażyna Dąbrowska.

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Dąbrowska, G., Filipek, E. Reactivity of the oxides in the ternary V2O5-CuO-α-Sb2O4 system in air. J Therm Anal Calorim 93, 839–845 (2008). https://doi.org/10.1007/s10973-008-9301-y

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