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Thermal degradation of iron chelate complexes adsorbed on mesoporous silica and alumina

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Abstract

Nanometric Fe2O3 particles could be inserted inside the internal pore volume of SBA-15 mesoporous silica and mesoporous alumina supports, when Fe(III) chelates (EDTA, gluconate or citrate) were used as impregnating precursors. The oxidative degradation of the chelating anions was followed by combined TG-DTA. Strong chelate-SiOH interactions (case of bulky EDTA), favored by the mesopore curvature, yield sub-nanometric extremely well dispersed Fe2O3 particles preferentially located at the micropore mouths (confinement effect). Fe2O3 even more strongly interacts with alumina walls, generating either (Fe,Al)2O3 mixed phases or Fe-aluminate micro domains. These iron-based mesoporous alumina composites proved very active catalysts in total oxidation of phenol at ambient conditions, with extremely low iron leaching (0.2%).

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Authors and Affiliations

  1. LPI-GSEC, ENSCMu, 3 Rue A. Werner, 68093, Mulhouse Cedex, France

    Z. Gabelica & R. Vataj

  2. Université de Poitiers, ESIP, CNRS-LACCO, UMR 6503, 40 Av. Recteur Pineau, 86022, Poitiers, France

    A. Charmot, J. Barrault & S. Valange

  3. Laboratoire de Catalyse et Synthèse en Chimie Organique (LCSCO), Université A. Belkaid, B.P. 119, Tlemcen, 13000, Algérie

    R. Soulimane

Authors
  1. Z. Gabelica
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  2. A. Charmot
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  3. R. Vataj
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  4. R. Soulimane
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  5. J. Barrault
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  6. S. Valange
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Correspondence to S. Valange.

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Gabelica, Z., Charmot, A., Vataj, R. et al. Thermal degradation of iron chelate complexes adsorbed on mesoporous silica and alumina. J Therm Anal Calorim 95, 445–454 (2009). https://doi.org/10.1007/s10973-008-9256-z

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  • DOI: https://doi.org/10.1007/s10973-008-9256-z

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