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Studies on glass transition of lithium-iron phosphate glasses

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Abstract

Amorphous analogs of lithium-iron phosphates (LFP) were prepared by standard press-quenching method and their thermal stabilities as well as structural properties were studied for the first time. Glass transition temperature T g determined by DTA method was observed at the temperature range 492–523°C, depending on the glass composition. The maxima of crystallization peaks were observed in the 555–579°C range. In products obtained after heating up to 700°C the XRD patterns have revealed the presence of: LiFePO4 (triphylite), FePO4 (heterosite), α-FePO4 (quartz like structure) and Li3Fe2(PO4)3 (Nasicon like structure) phases.

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Authors and Affiliations

  1. Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664, Warsaw, Poland

    I. Gorzkowska

  2. Faculty of Physics, Warsaw University of Technology, Koszykowa 75, 00-662, Warsaw, Poland

    P. Jozwiak, J. E. Garbarczyk & M. Wasiucionek

  3. Institut des Nanosciences de Paris, UMR-CNRS 7588, Université Pierre et Marie Curie, 140 rue de Lourmel, 75015, Paris, France

    C. M. Julien

Authors
  1. I. Gorzkowska
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  2. P. Jozwiak
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  3. J. E. Garbarczyk
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  4. M. Wasiucionek
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  5. C. M. Julien
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Correspondence to I. Gorzkowska.

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Gorzkowska, I., Jozwiak, P., Garbarczyk, J.E. et al. Studies on glass transition of lithium-iron phosphate glasses. J Therm Anal Calorim 93, 759–762 (2008). https://doi.org/10.1007/s10973-008-9141-9

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  • DOI: https://doi.org/10.1007/s10973-008-9141-9

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