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New phase in the system FeVO4-Cd4V2O9

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Abstract

A new phase Cd4Fe7+xV9+xO37+4x, where −0.5<x<1.5, has been obtained in the solid-state in the FeVO4−Cd4V2O9 system. The temperature of incongruent melting and the unit cell volume of this phase decrease with decreasing the content of cadmium. The IR spectrum and SEM image of the new phase are presented.

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Authors and Affiliations

  1. Department of Inorganic and Analytical Chemistry, Szczecin University of Technology, Al. Piastów 42, 71-065, Szczecin, Poland

    Anna Blonska-Tabero

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  1. Anna Blonska-Tabero
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Correspondence to Anna Blonska-Tabero.

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Blonska-Tabero, A. New phase in the system FeVO4-Cd4V2O9 . J Therm Anal Calorim 93, 707–710 (2008). https://doi.org/10.1007/s10973-008-9132-x

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  • DOI: https://doi.org/10.1007/s10973-008-9132-x

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