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The standard enthalpy of formation of silver pivalate

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Abstract

The standard enthalpy of combustion of crystalline silver pivalate, (CH3)3CC(O)OAg (AgPiv), was determined in an isoperibolic calorimeter with a self-sealing steel bomb, Δc H 0 (AgPiv, cr)= −2786.9±5.6 kJ mol−1. The value of standard enthalpy of formation was derived for crystalline state: Δf H 0(AgPiv,cr)= −466.9±5.6 kJ mol−1. Using the enthalpy of sublimation, measured earlier, the enthalpy of formation of gaseous dimer was obtained: Δf H 0(Ag2Piv2,g)= −787±14 kJ mol−1. The enthalpy of reaction (CH3)3CC(O)OAg(cr)=Ag(cr)+(CH3)3CC(O)O.(g) was estimated, Δr H 0=202 kJ mol−1.

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Authors and Affiliations

  1. Chemistry Department, Moscow State University, 119992, Leninskie Gory, Moscow, Russia

    V. A. Lukyanova, T. S. Papina & A. S. Alikhanyan

  2. Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Leninsky Prospect, 31, Moscow, Russia

    K. V. Didenko

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  1. V. A. Lukyanova
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  2. T. S. Papina
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  3. K. V. Didenko
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  4. A. S. Alikhanyan
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Correspondence to V. A. Lukyanova.

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Lukyanova, V.A., Papina, T.S., Didenko, K.V. et al. The standard enthalpy of formation of silver pivalate. J Therm Anal Calorim 92, 743–746 (2008). https://doi.org/10.1007/s10973-008-9019-x

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  • DOI: https://doi.org/10.1007/s10973-008-9019-x

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