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Thermodynamics of ion exchange in a sulfonated polymer based on cis-tetraphenylmetacyclophanoctol

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Abstract

The thermodynamic characteristics of proton exchange in SO3H groups of a sulfonated network polymer based on cis-tetraphenylmetacyclophanoctol for Na+, Cu2+ cations from aqueous solutions were considered for the first time. Microcalorimetric measurements of the heat effects of Na+-H+ and Cu2+-H+ exchanges were performed, equilibrium compositions of polymer and solution were determined. The changes of Gibbs energy, enthalpy and entropy of ion exchange were calculated.

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Authors and Affiliations

  1. Kemerovo Division, Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch of Russian Academy of Sciences, 18 Sovetsky Prosp, Kemerovo, 650099, Russia

    H. N. Al’tshuler, E. V. Ostapova, L. A. Sapozhnikova & O. H. Al’tshuler

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  1. H. N. Al’tshuler
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  2. E. V. Ostapova
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  3. L. A. Sapozhnikova
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  4. O. H. Al’tshuler
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Correspondence to H. N. Al’tshuler.

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Al’tshuler, H.N., Ostapova, E.V., Sapozhnikova, L.A. et al. Thermodynamics of ion exchange in a sulfonated polymer based on cis-tetraphenylmetacyclophanoctol. J Therm Anal Calorim 92, 665–669 (2008). https://doi.org/10.1007/s10973-008-9011-5

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  • DOI: https://doi.org/10.1007/s10973-008-9011-5

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