Skip to main content
SpringerLink
Log in

Thermal studies of Co(II), Ni(II) and Cu(II) complexes of N,N′-bis(3,5-Di-t-butylsalicylidene)ethylenediamine

  • Regular Papers
  • Complexes
  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

The thermal decomposition kinetics of sterically hindered salen type ligand (L) and its metal complexes [M=Co(II), Ni(II), Cu(II)] were investigated by thermogravimetric analysis. A direct insertion probe-mass spectrometer (DIP-MS) was used for the characterization of metal complexes of L and all fragmentations and stable ions were characterized. The thermogravimetry and differential thermogravimetry (TG-DTG) plots of salen type salicylaldimine ligand and complexes showed a single step.

The kinetic analysis of thermogravimetric data was performed by using the invariant kinetic parameter method (IKP). The values of the invariant activation energy, E inv and the invariant pre-exponential factor, A inv, were calculated by using Coats-Redfern (CR) method. The thermal stabilities and activation energies of metal complexes of sterically hindered salen type ligand (L) were found as Co(II)>Cu(II)>Ni(II)>L and E Cu>E Ni>E Co>L. Also, the probabilities of decomposition functions were investigated. The diffusion functions (D n) are most probable for the thermal decomposition of all complexes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. W. Zhang, J. L. Loebach, S. R. Wilson and E. N. Jacobsen, J. Am. Chem. Soc., 112 (1990) 2801.

    Article  CAS  Google Scholar 

  2. T. Matsuura, Tetrahedron, 33 (1977) 2869.

    Article  CAS  Google Scholar 

  3. J. L. Serrano and L. Oriol, Adv. Mater., 7 (1995) 365.

    Google Scholar 

  4. L. Mao, K. Yamamato, W. Zhou and L. Jin, Electroanalysis, 12 (2000) 72.

    Article  CAS  Google Scholar 

  5. J. F. Larrow, E. N. Jacobsen, Y. Gao, Y. Hong, X. Nie and C. M. Zepp, J. Org. Chem., 59 (1994) 1939.

    Article  CAS  Google Scholar 

  6. J. Madarász, G. Pokol and S. Gál, J. Thermal Anal., 42 (1994) 539.

    Article  Google Scholar 

  7. I. L. Lapides, J. Thermal Anal., 50 (1997) 269.

    Article  CAS  Google Scholar 

  8. F. Carrasco, Thermochim. Acta, 213 (1993) 115.

    Article  CAS  Google Scholar 

  9. M. V. Kök and N. Acar, J. Therm. Anal. Cal., 83 (2006) 445.

    Article  CAS  Google Scholar 

  10. M. V. Kök, J. Therm. Anal. Cal., 88 (2007) 663.

    Article  Google Scholar 

  11. M. V. Kök and A. G. Iscan, J. Therm. Anal. Cal., 88 (2007) 657.

    Article  Google Scholar 

  12. J. Zsakó, J. Thermal Anal., 46 (1996) 1854.

    Google Scholar 

  13. A. A. Soliman, S. M. El-Medani and O. A. M. Ali, J. Therm. Anal. Cal., 83 (2006) 385.

    Article  CAS  Google Scholar 

  14. S. Durmuş, Ü. Ergün, J. C. Jaud, K. C Emregül, H. Fues and O Atakol, J. Therm. Anal. Cal., 86 (2006) 337.

    Article  CAS  Google Scholar 

  15. O. Z. Yeşilel, H. Ölmez and H. İçbudak, J. Therm. Anal. Cal., OnlineFirst DOI: 10.1007/s10973-005-7479-9.

  16. G. G. Mohamed and H. Z. El-Wahab, J. Therm. Anal. Cal., 73 (2003) 347.

    Article  CAS  Google Scholar 

  17. F. Doğan, S. Gülcemal, M. Yürekli and B. Çetinkaya, J. Therm. Anal. Cal., 91 (2008) 395.

    Article  CAS  Google Scholar 

  18. V. T. Kasumov and F. Koksal, Spectrochim. Acta, Part A, 61A(1–2) (2004) 225.

    Google Scholar 

  19. V. T. Kasumov, S. O.-Yaman and E. Tas, Spectrochim. Acta, Part A, 62A(1–3) (2005) 716.

    CAS  Google Scholar 

  20. S. V Levchik, G. F. Levchik and A. L. Lesnikovich, Thermochim. Acta, 92 (1985) 157.

    Article  CAS  Google Scholar 

  21. M. Arshad, Saeed-ur-Rehman, S. Ali Khan, K. Masud, N. Arshad and A. Ghani, Thermochim. Acta, 364 (2002) 143.

    Article  Google Scholar 

  22. G. G. Mohamed, F. A. Nour-El Dien and E. A. El-Gamel, J. Therm. Anal. Cal., 67 (2002) 135.

    Article  CAS  Google Scholar 

  23. F. Doğan, M. Ulusoy, Ö. F. Öztürk, I. Kaya and B. Salih, J. Therm. Anal. Cal., (2009), in print.

  24. V. Mamleev, S. Bourbigot, M. Le Bras, S. Duquesne and J. Sešták, Phys. Chem. Chem. Phys., 2 (2000) 4708.

    Article  CAS  Google Scholar 

  25. A. J. Lesnickovick and S. V Levchick, J. Thermal Anal., 30 (1985) 667.

    Google Scholar 

  26. A. W. Coats and J. P. Redfern, Nature, 201 (1964) 68.

    Article  CAS  Google Scholar 

  27. A. J. Lesnickovick and S. V Levchick, J. Thermal Anal., 27 (1983) 83.

    Google Scholar 

  28. S. Bourbigot, R. Delobel, M. Le Bras and D. Normand, J. Chim. Phys., 90 (1993) 1909.

    CAS  Google Scholar 

  29. S. Bourbigot, X. Flambard and S. Duquesne, Polym. Int., 50 (2001) 157.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Arts and Science, Chemistry Department, Çanakkale Onsekiz Mart University, Çanakkale, Turkey

    F. Doğan, Ö. F. Öztürk & İ. Kaya

  2. Faculty of Science, Chemistry Department, Ege University, İzmir, Turkey

    M. Ulusoy

  3. Faculty of Science, Chemistry Department, Hacettepe University, Ankara, Turkey

    Ö. F. Öztürk & B. Salih

Authors
  1. F. Doğan
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. Ulusoy
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ö. F. Öztürk
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. İ. Kaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. B. Salih
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to F. Doğan.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Doğan, F., Ulusoy, M., Öztürk, Ö.F. et al. Thermal studies of Co(II), Ni(II) and Cu(II) complexes of N,N′-bis(3,5-Di-t-butylsalicylidene)ethylenediamine. J Therm Anal Calorim 96, 267–276 (2009). https://doi.org/10.1007/s10973-008-8980-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-008-8980-8

Keywords

Search

Navigation