Skip to main content
SpringerLink
Log in

Preparation, characterization and thermal decomposition of phenylenediammonium sulfate salts Part. XVI

  • Regular Papers
  • Organics/Polymers
  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

Three phenylenediammonium sulfate (PDAS) salts were prepared under solvent free conditions and characterized by gravimetric, spectroscopic and elemental analyses. Thermal decomposition studies of the salts have been investigated using TG (static air), TG/DTG and DSC (inert atmosphere). The thermal decomposition pathways have also been suggested and it has been found that PDAS salts on heating under vacuum in solid state give diaminobenzene sulfonic acids (DABSA) via proton transfer.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. L. Erdey and S. Gal, Talanta, 10 (1963) 23.

    Article  CAS  Google Scholar 

  2. L. Erdey, S. Gal and G. Liptay, Talanta, 11 (1964) 913.

    Article  CAS  Google Scholar 

  3. L. Erdey, Periodica Polytech., 1 (1957) 91.

    CAS  Google Scholar 

  4. G. Singh, C. P. Singh and R. Frohlich, J. Therm. Anal. Cal., 85 (2006) 425.

    Article  CAS  Google Scholar 

  5. G. Singh, B. P. Barnawal, I. P. S. Kapoor D. Kumar, C. P. Singh and R. Frohlich, J. Therm. Anal. Cal., (2007) in press.

  6. G. Singh, C. P. Singh and S. M. Mannan, Thermochim. Acta, 437 (2005) 21.

    Article  CAS  Google Scholar 

  7. G. Singh and I. P. S. Kapoor, Combust. Flame, 92 (1993) 283.

    Article  CAS  Google Scholar 

  8. G. Singh, I. P. S. Kapoor, S. M. Mannan and J. P. Agrawal, Combust. Flame, 97 (1994) 355.

    Article  CAS  Google Scholar 

  9. G. Singh, I. P. S. Kapoor and S. M. Mannan, Thermochim. Acta, 262 (1995) 117.

    Article  CAS  Google Scholar 

  10. I. P. S. Kapoor, P. Srivastava and G. Singh, J. Hazard. Mater., (2007) in press.

  11. G. Singh and I. P. S. Kapoor, J. Phys. Chem., 96 (1992) 215.

    Google Scholar 

  12. G. Singh, I. P. S. Kapoor and S. M. Mannan, J. Thermal Anal., 46 (1996) 1751.

    Article  CAS  Google Scholar 

  13. G. Singh, I. P. S. Kapoor and S. M. Mannan, J. Energ. Mater., 13 (1995) 141.

    Article  CAS  Google Scholar 

  14. G. Singh, I. P. S. Kapoor and J. Kaur, Indian J. Chem., Sec. B, 56 (1999) 3813.

    Google Scholar 

  15. G. Singh, I. P. S. Kapoor and J. Kaur, Thermochim. Acta, 45 (1999) 338.

    Google Scholar 

  16. I. P. S. Kapoor, P. Srivastava, G. Singh and R. Frohlich, Indian J. Chem. Sec. A, 46A (2007) 1277.

    CAS  Google Scholar 

  17. G. Singh, I. P. S. Kapoor and J. Kaur, J. Therm. Anal. Cal., 62 (2000) 305.

    Article  CAS  Google Scholar 

  18. G. Singh, P. Srivastava and J. Srivastava, J. Therm. Anal. Cal., 89 (2007)181.

    Article  CAS  Google Scholar 

  19. G. Singh, I. P. S. Kapoor and J. Kaur, Indian J. Eng. Mater. Sci., 7 (2000) 229.

    CAS  Google Scholar 

  20. G. Singh and I. P. S. Kapoor, J. Chem. Soc. Perkin Trans., 2 (1989) 2155.

    Google Scholar 

  21. G. Singh, I. P. S. Kapoor and M. Jain, J. Chem. Soc. Perkin Trans., 2 (1993) 1521.

    Google Scholar 

  22. G. Singh, I. P. S. Kapoor and M. Jain, Indian J. Chem., 35B (1996) 369.

    CAS  Google Scholar 

  23. G. Singh, I. P. S. Kapoor and M. Jain, Thermochim. Acta, 1 (1997) 3166.

    Google Scholar 

  24. G. Singh, I. P. S. Kapoor and J. Singh, Indian J. Eng. Mater. Sci., 5 (1998) 300.

    Google Scholar 

  25. H. A. Lubs, The Chemistry of Synthetic Dyes and Pigments, R. E. Krieger, Ed., Publ. Malaban, Florida 1982.

    Google Scholar 

  26. M. Ralph, B. Jacobh and S. Robert, US Patent 4681710 (1987).

  27. G. Singh, I. P. S. Kapoor and M. Jain, Thermochim. Acta, 292 (1997) 135.

    Article  CAS  Google Scholar 

  28. G. Singh, I. P. S. Kapoor and J. Singh, Thermochim. Acta, 335 (1999) 11.

    Article  CAS  Google Scholar 

  29. G. Singh, I. P. S. Kapoor, J. Srivastava and J. Kaur, J. Therm. Anal. Cal., 69 (2002) 681.

    Article  CAS  Google Scholar 

  30. G. Singh, I. P. S. Kapoor and M. Jain, Indian J. Chem., 35B (1996) 369.

    CAS  Google Scholar 

  31. G. Singh and R. R. Singh, Res. Ind., 23 (1978) 92.

    CAS  Google Scholar 

  32. I. P. S. Kapoor, P. Srivastava, G. Singh and R. Frohlich, Indian J. Chem., 45A (2006) 1820.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Chemistry Department, DDU Gorakhpur University, Gorakhpur, 273009, India

    I. P. S. Kapoor, P. Srivastava & G. Singh

Authors
  1. I. P. S. Kapoor
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. P. Srivastava
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. Singh
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to G. Singh.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kapoor, I.P.S., Srivastava, P. & Singh, G. Preparation, characterization and thermal decomposition of phenylenediammonium sulfate salts Part. XVI. J Therm Anal Calorim 92, 553–557 (2008). https://doi.org/10.1007/s10973-007-8786-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-007-8786-0

Keywords

Search

Navigation