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Coordination chain polymeric assemblies of trivalent lanthanides with multidentate Schiff base synthetic, spectral investigation and thermal aspects

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Abstract

The coordination chain polymers of La(III), Ce(III), Pr(III), Nd(III) and Sm(III) with N,N’-di(o-thiophenyl)terephthalaldehydediimine have been prepared and characterized by elemental analysis, 1H NMR, 13C NMR, magnetic measurements, infrared spectra, reflectance spectra and thermogravimetric analysis. A coordination number of seven around the metal ion is suggested. The thermal decompositions of the coordination polymers have been studied. The kinetic parameters have been calculated using Freeman-Carroll method. The thermodynamic activation parameters such as entropy (S*), preexponential factor (A), enthalpy (H*) and free energy of the decomposition (G*) have been evaluated.

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Authors and Affiliations

  1. Department of Chemistry, Sardar Patel University, Vallabh Vidyanagar, 388 120, Gujarat, India

    S. H. Patel, P. B. Pansuriya, M. R. Chhasatia, H. M. Parekh & M. N. Patel

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  1. S. H. Patel
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  2. P. B. Pansuriya
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  3. M. R. Chhasatia
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  4. H. M. Parekh
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Patel, S.H., Pansuriya, P.B., Chhasatia, M.R. et al. Coordination chain polymeric assemblies of trivalent lanthanides with multidentate Schiff base synthetic, spectral investigation and thermal aspects. J Therm Anal Calorim 91, 413–418 (2008). https://doi.org/10.1007/s10973-007-8542-5

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  • DOI: https://doi.org/10.1007/s10973-007-8542-5

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