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Thermophysical properties in medium temperature range of several thio and dithiocarbamates

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Abstract

The present study reports a DSC study of the thio-and dithiocarbamates: 3H-benzoxazole-2-thione (2-mercaptobenzoxazole), 3H-benzothiazole-2-thione (2-mercaptobenzothiazole), thiazolidine-2-thione (2-mercapto-2-thiazoline), oxazolidine-2-thione (2-mercapto-2-oxazoline) and tetrahydro-1,3-oxazine-2-thione (5,6-dihydro-4H-1,3-oxazine-2-thiol) in the temperature interval T=268 K and the melting temperatures. Temperatures, enthalpies and entropies of fusion are reported. No solid-solid phase transitions were observed for the compounds in the temperature interval studied. The heat capacity of the compounds as a function of temperature was measured.

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Authors and Affiliations

  1. Instituto de Química Física ‘Rocasolano’, CSIC, Serrano 119, 28006, Madrid, Spain

    Manuel Temprado & Maria Victoria Roux

  2. Department of Chemistry and Biochemistry, University of Missouri-St. Louis, One University Boulevard, St. Louis, MO, 63121-4499, USA

    Archana R. Parameswar, Alexei V. Demchenko & James S. Chickos

  3. Department of Chemistry and Biochemistry, University of Maryland, Baltimore County, Baltimore, MD, 21250, USA

    Joel F. Liebman

Authors
  1. Manuel Temprado
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  2. Maria Victoria Roux
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  3. Archana R. Parameswar
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  4. Alexei V. Demchenko
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  5. James S. Chickos
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  6. Joel F. Liebman
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Correspondence to Maria Victoria Roux.

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Temprado, M., Roux, M.V., Parameswar, A.R. et al. Thermophysical properties in medium temperature range of several thio and dithiocarbamates. J Therm Anal Calorim 91, 471–475 (2008). https://doi.org/10.1007/s10973-007-8345-8

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  • DOI: https://doi.org/10.1007/s10973-007-8345-8

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