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Obtaining of chromium(III) phosphates(V) in the solid-state and their thermal stability

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Abstract

As a result of solid-state reactions four chromium(III) phosphates(V) have been obtained, i.e. Cr(PO3)3, Cr4(P2O7)3, Cr2P4O13 and CrPO4. Cr2P4O13 has been obtained as a result of a solid-state reaction between Cr2O3 and (NH4)2HPO4 as well as between CrPO4 and Cr(PO3)3 mixed at a molar ratio of 1:1 or between Cr4(P2O7)3 and Cr(PO3)3 mixed at a molar ratio of 1:2. Melting temperatures and the products of thermal decomposition have been determined for the obtained chromium(III) phosphates(V).

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  1. Department of Inorganic and Analytical Chemistry, Szczecin University of Technology, Szczecin, Poland, 71-065, al. Piastów 42

    Monika Bosacka, P. Jakubus & I. Rychłowska-Himmel

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  1. Monika Bosacka
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  2. P. Jakubus
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  3. I. Rychłowska-Himmel
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Correspondence to Monika Bosacka.

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Bosacka, M., Jakubus, P. & Rychłowska-Himmel, I. Obtaining of chromium(III) phosphates(V) in the solid-state and their thermal stability. J Therm Anal Calorim 88, 133–137 (2007). https://doi.org/10.1007/s10973-006-8050-z

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  • DOI: https://doi.org/10.1007/s10973-006-8050-z

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