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The interaction between TEOS and some polyols

Thermal analysis and FTIR

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Abstract

Hybrid organic-inorganic materials, silica – polyols (ethylene-glycol – EG; 1,2 propane diol – 1,2PG; 1,3 propane diol – 1,3PG and glycerol – GL), were prepared by a sol-gel process starting from tetraethylorthosilicate (TEOS) and polyols, in acid catalysis. The resulting materials were studied by thermal analysis (in air and nitrogen), FTIR and solid state 29Si-NMR spectroscopy. These techniques evidenced the presence of polyols in the silica matrix both hydrogen bounded and chemically bounded in the silica network. The thermal analysis proves to be the most appropriate technique to evidence the organic chains linked in the matrix network and to follow the thermal evolution of the gels to the SiO2 matrix.

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References

  1. T Higuchi K Kuramada S Nagamine AW Lothongkum M Tanigaki (2000) J. Mater. Sci. 35 3237 Occurrence Handle10.1023/A:1004811019300 Occurrence Handle1:CAS:528:DC%2BD3cXltFCqtbg%3D

    Article  CAS  Google Scholar 

  2. O Shilova EV Tarasyuc VV Shevchenko NS Klimenko TG Movchan SV Hashkovsky VV Shilov (2003) Glass Phys. Chem. 29 378 Occurrence Handle10.1023/A:1025125010618 Occurrence Handle1:CAS:528:DC%2BD3sXmtFGhurk%3D

    Article  CAS  Google Scholar 

  3. D Sternik P Staszczuk J Pekalska G Grodzicka B Gawdzik J Ospiuk-Tomasik P Witer (2006) J. Therm. Anal. Cal. 86 85 Occurrence Handle10.1007/s10973-006-7581-7 Occurrence Handle1:CAS:528:DC%2BD28XhtVWnsbnI

    Article  CAS  Google Scholar 

  4. NN Khimich (2004) Glass Phys. Chem. 30 430 Occurrence Handle10.1023/B:GPAC.0000045925.84139.eb Occurrence Handle1:CAS:528:DC%2BD2cXovFaltbg%3D

    Article  CAS  Google Scholar 

  5. V Castelvetro Cinzia De Vita (2004) Adv. Colloid Interface Sci. 108–109 167 Occurrence Handle10.1016/j.cis.2003.10.017

    Article  Google Scholar 

  6. M Zaharescu A Jitianu A Braileanu J Madarász Cs Novák G Pokol (2003) J. Therm. Anal. Cal. 71 421 Occurrence Handle10.1023/A:1022883221776 Occurrence Handle1:CAS:528:DC%2BD3sXitVygur0%3D

    Article  CAS  Google Scholar 

  7. M Zaharescu A Jitianu A Braileanu J Madarász G Pokol (2001) J. Therm. Anal. Cal. 64 689 Occurrence Handle10.1023/A:1011536209930 Occurrence Handle1:CAS:528:DC%2BD3MXkslWlur8%3D

    Article  CAS  Google Scholar 

  8. CL Beaudry LC Klein RA McCauley (1996) J. Thermal Anal. 46 55 Occurrence Handle10.1007/BF01979947 Occurrence Handle1:CAS:528:DyaK28Xhs1Wku70%3D

    Article  CAS  Google Scholar 

  9. RFS Lenza WL Wasconcelos (2001) Mater. Res. 4 175 Occurrence Handle1:CAS:528:DC%2BD3MXmvV2mtLw%3D

    CAS  Google Scholar 

  10. VK Parashar V Raman OP Bahl (1996) J. Mater. Sci. Lett. 15 1403 Occurrence Handle10.1007/BF00275289 Occurrence Handle1:CAS:528:DyaK28Xls1GhsLk%3D

    Article  CAS  Google Scholar 

  11. N Uchida N Ishiyama Z Kato K Uematsu (1994) J. Mater. Sci. Lett. 29 5188 Occurrence Handle1:CAS:528:DyaK2cXmtlKrsLo%3D

    CAS  Google Scholar 

  12. CP Higginbotham RF Browner JD Jenkins JK Rice (2003) Mater. Lett. 57 3970 Occurrence Handle10.1016/S0167-577X(03)00249-0 Occurrence Handle1:CAS:528:DC%2BD3sXmtVSrurc%3D

    Article  CAS  Google Scholar 

  13. M Laridjani E Lafontaine JP Bayyl P Judeinstein (1999) J. Mater. Sci. 34 5945 Occurrence Handle10.1023/A:1004711709642 Occurrence Handle1:CAS:528:DC%2BD3cXlt1Gisw%3D%3D

    Article  CAS  Google Scholar 

  14. P Ågren JB Rosenhohn (1998) J. Colloid Interface Sci. 204 45 Occurrence Handle10.1006/jcis.1998.5523

    Article  Google Scholar 

  15. AV Rao MM Kulkarni (2003) Mater. Chem. Phys. 77 819 Occurrence Handle10.1016/S0254-0584(02)00207-9 Occurrence Handle1:CAS:528:DC%2BD38XmvVCgtbk%3D

    Article  CAS  Google Scholar 

  16. GM Neves RFS Lenza WL Vasconcelos (2002) Mater. Res. 5 447 Occurrence Handle1:CAS:528:DC%2BD3sXnsV2g

    CAS  Google Scholar 

  17. D Ravanie A Seminel Y Charbouillot MA Vincens (1986) J. Non-Cryst. Solids 82 210 Occurrence Handle10.1016/0022-3093(86)90133-X

    Article  Google Scholar 

  18. M. Ştefănescu, M. Stoia and O. Ştefănescu, J. Sol-Gel Sci. Technol., (2006) in press.

  19. M Ştefănescu C Caizer M Stoia O Ştefănescu (2006) Acta Mater. 54 1249 Occurrence Handle10.1016/j.actamat.2005.10.051

    Article  Google Scholar 

  20. M Ştefănescu C Caizer M Stoia O Ştefănescu (2005) J. Optoelectron. Adv. Mater. 7 607

    Google Scholar 

  21. CJ Brinker GV Scherer et al. (1990) Sol-gel Science Academic Press San Diego 501

    Google Scholar 

  22. F Touati N Gharbi H Zarrouk (1997) J. Sol-Gel Sci. Technol. 8 595 Occurrence Handle1:CAS:528:DyaK2sXitlKqt7s%3D

    CAS  Google Scholar 

  23. CJ Brinker GV Scherer et al. (1990) Sol-gel Science Academic Press San Diego 552

    Google Scholar 

  24. V Jitchum S Chivin S Wongkasemjit H Ishida (2001) Tetrahedron 57 3997 Occurrence Handle10.1016/S0040-4020(01)00275-7 Occurrence Handle1:CAS:528:DC%2BD3MXjt1Whu7g%3D

    Article  CAS  Google Scholar 

  25. RFS Lenza WL Vasconcelos (2003) J. Non-Cryst. Solids 330 216 Occurrence Handle10.1016/j.jnoncrysol.2003.07.001 Occurrence Handle1:CAS:528:DC%2BD3sXos1ansrg%3D

    Article  CAS  Google Scholar 

  26. RFS Lenza WL Vasconcelos (2001) Mater. Res. 4 189 Occurrence Handle1:CAS:528:DC%2BD3MXmvV2mtLo%3D

    CAS  Google Scholar 

  27. Ch Voulgaris E Amanatide D Mataras DE Rapakoulies (2005) J. Phys.: Conference Series 10 206 Occurrence Handle10.1088/1742-6596/10/1/051 Occurrence Handle1:CAS:528:DC%2BD2MXhtVahsLrM

    Article  CAS  Google Scholar 

  28. GM Neves RFS Lenza WL Vasconcelos (2002) Mater. Res. 5 447 Occurrence Handle1:CAS:528:DC%2BD3sXnsV2g

    CAS  Google Scholar 

  29. VA Maroni SJ Epperson (2001) Vibr. Sperctrosc. 27 43 Occurrence Handle10.1016/S0924-2031(01)00122-9 Occurrence Handle1:CAS:528:DC%2BD3MXotVantLc%3D

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Faculty of Industrial Chemistry and Environmental Engineering, University ‘Politehnica’ of Timişoara, Timişoara, Romania, 300006, P-ta Victoriei nr. 2.

    M. Ştefănescu, M. Stoia, O. Ştefănescu & M. Simon

  2. Institute of Chemistry Timişoara, Romanian Academy, Timişoara, Romania, 1900, Bd. Mihai Viteazul, No.24

    A. Popa & C. Ionescu

Authors
  1. M. Ştefănescu
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  2. M. Stoia
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  3. O. Ştefănescu
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  4. A. Popa
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  5. M. Simon
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  6. C. Ionescu
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Correspondence to M. Ştefănescu.

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Ştefănescu, M., Stoia, M., Ştefănescu, O. et al. The interaction between TEOS and some polyols. J Therm Anal Calorim 88, 19–26 (2007). https://doi.org/10.1007/s10973-006-8002-7

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  • DOI: https://doi.org/10.1007/s10973-006-8002-7

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