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Thermochemistry of copper complex of 6-benzylaminopurine

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Abstract

The copper(II) complex of 6-benzylaminopurine (6-BAP) has been prepared with dihydrated cupric chloride and 6-benzylaminopurine. Infrared spectrum and thermal stabilities of the solid complex have been discussed. The constant-volume combustion energy, Δc U, has been determined as −12566.92±6.44 kJ mol−1 by a precise rotating-bomb calorimeter at 298.15 K. From the results and other auxiliary quantities, the standard molar enthalpy of combustion, Δc H m θ, and the standard molar of formation of the complex, Δf H m θ, were calculated as −12558.24±6.44 and −842.50±6.47 kJ mol−1, respectively.

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Authors and Affiliations

  1. Shaanxi Key Laboratory of Phsico-Inorganic Chemistry, Department of Chemistry, Northwest University, Xi’an, 710069, Shaanxi, China

    Y. Xu-Wu, Z. Hang-Guo, W. Xiao-Yan & G. Sheng-Li

  2. College of Chemistry and Environment Science, Shaanxi University of Technology, Hanzhong, 723001, Shaanxi, China

    S. Wu-Juan

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  1. Y. Xu-Wu
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  2. Z. Hang-Guo
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  3. S. Wu-Juan
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  4. W. Xiao-Yan
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  5. G. Sheng-Li
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Correspondence to Y. Xu-Wu.

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Xu-Wu, Y., Hang-Guo, Z., Wu-Juan, S. et al. Thermochemistry of copper complex of 6-benzylaminopurine. J Therm Anal Calorim 92, 961–965 (2008). https://doi.org/10.1007/s10973-006-7946-y

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  • DOI: https://doi.org/10.1007/s10973-006-7946-y

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