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Thermal decomposition and structural study of lanthanide complexes with trans-1,3-dithiane-1,3-dioxide

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Abstract

Lanthanide picrates with 1,3-dithiane-1,3-dioxide ligand were synthesized and characterized. Thermal decomposition of these compounds by TG/DTG and DSC and structural studies were performed. It was found that the compounds are comprised in a single isomorphous series and their thermal decomposition occurs as exothermic events. The final products were found to be lanthanide dioxysulfates.

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Authors and Affiliations

  1. Faculdade de Engenharia, Centro Universitário, Fundação Santo André, Brazil, SP

    P. Miranda Jr

  2. Centro de Metrologia das Radiações, CMR, IPEN-CNEN, Brazil, SP

    M. F. Máduar

  3. Departamento de Química, Universidade Federal de São Carlos, São Carlos, Brazil, SP

    J. Zukerman-Schpector

  4. Departamento de Química Fundamental, LATIG, IQ, Universidade de São Paulo, São Paulo, Brazil, SP

    J. R. Matos

Authors
  1. P. Miranda Jr
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  2. M. F. Máduar
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  3. J. Zukerman-Schpector
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  4. J. R. Matos
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Correspondence to P. Miranda Jr.

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Miranda Jr, P., Máduar, M.F., Zukerman-Schpector, J. et al. Thermal decomposition and structural study of lanthanide complexes with trans-1,3-dithiane-1,3-dioxide. J Therm Anal Calorim 87, 793–795 (2007). https://doi.org/10.1007/s10973-006-7864-z

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  • DOI: https://doi.org/10.1007/s10973-006-7864-z

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