Abstract
Zinc coatings on ferrous substrates are possible to be applied with thermal spraying. In the present work the corrosion behavior of zinc thermal sprayed coatings deposited on low carbon steel St-37 was examined in a simulated marine atmosphere (salt spray chamber-SSC) and in a dry atmosphere at elevated temperature (400°C). The corrosion progress was examined by means of optical microscopy, scanning electron microscopy, X-ray diffraction and thermogravimetric analysis. From this investigation it was deduced that in the SSC the coating is uniformly corroded, while the main corrosion products are hydrated zinc oxides and chlorides. By contrast at 400°C only a thin, compact and continuous film of ZnO is formed on top of the coating, which remains adherent to the ferrous substrate.
Similar content being viewed by others
References
F. Habashi, Discovering the 8th metal-A history of zinc, IZA.
XG Zhang et al. (1996) Corrosion and Electrochemistry of Zinc Plenum Press New York
AR Marder (2000) Prog. Mater. Sci. 45 191 Occurrence Handle10.1016/S0079-6425(98)00006-1 Occurrence Handle1:CAS:528:DC%2BD3cXisVaqsLY%3D
N Pistofidis G Vourlias D Chaliampalias E Pavlidou K Chrissafis G Stergioudis EK Polychroniadis D Tsipas (2006) J. Therm. Anal. Cal. 84 191 Occurrence Handle10.1007/s10973-005-7196-4 Occurrence Handle1:CAS:528:DC%2BD28XjsVOmsrw%3D
N Pistofidis G Vourlias E Pavlidou K Chrissafis G Stergioudis EK Polychroniadis D Tsipas (2006) J. Therm. Anal. Cal. 86 417 Occurrence Handle10.1007/s10973-005-7195-5 Occurrence Handle1:CAS:528:DC%2BD28XhtVygs7bI
InstitutionalAuthorNameAmerican Galvanizing Association et al. (2000) Zinc coatings American Galvanizing Association Englewood, Colorado
R. C. Tucker, Thermal Spray Coatings, in Vol. 5, Surface Engineering, American Society of Metals, ASM International, 1996.
Engineering and Design-Thermal Spraying: New Construction and Maintenance, CECW-ET, Engineer Manual 1110-2-3401, Department of the Army, U.S. Army Corps of Engineers, Washington 1999.
D. Chaliampalias, G. Vourlias, N. Pistofidis, I. Tsiaoussis, E. Pavlidou and E. K. Polychroniadis, on the Effect of Nanocrystalline ZnO Particles on the Anticorrosive Behaviour of Flame Sprayed Zinc Coatings, IMC 2006, Sapporo, Japan.
G Vourlias N Pistofidis G Stergioudis EK Polychroniadis (2006) J. Alloys Compd. 416 183 Occurrence Handle10.1016/j.jallcom.2005.09.007 Occurrence Handle1:CAS:528:DC%2BD28XkvF2htbY%3D
G Vourlias N Pistofidis P Patsalas E Pavlidou G Stergioudis EK Polychroniadis (2005) High Temp. Mater. Processes 9 243
M. J. Mitchell, Developments in Coatings for High Temperature Corrosion Protection, Proceedings of the SSPC 2002 Technical Presentations, Tampa, Florida, November 3–6, 2002, pp. 88–96.
D. R. Lide (Ed.), CRC Handbook of Chemistry and Physics, 80th Ed., CRC Press, London 1999–2000. 14 M. Fontana, Corrosion Engineering, McGraw-Hill, 3rd Ed., New York 1986.
Dun Chen (2006) J. Therm. Anal. Cal. 85 13 Occurrence Handle10.1007/s10973-005-7330-3 Occurrence Handle1:CAS:528:DC%2BD28XnsFOqtbc%3D
SG Lee SG Kang (1997) J. Mater. Sci. Lett. 16 902 Occurrence Handle10.1023/A:1018584004364 Occurrence Handle1:CAS:528:DyaK2sXktVCit7o%3D
S Oesch M Faller (1997) Corr. Sci. 39 1505 Occurrence Handle10.1016/S0010-938X(97)00047-4 Occurrence Handle1:CAS:528:DyaK2sXmsFals78%3D
V Ligier M Wery JY Hihn J Faucheu M Tachez (1999) Corros. Sci. 41 1139 Occurrence Handle10.1016/S0010-938X(98)00176-0 Occurrence Handle1:CAS:528:DyaK1MXjt1Whtr8%3D
AR Mendoza F Corvo (2000) Corros. Sci. 42 1123 Occurrence Handle10.1016/S0010-938X(99)00135-3 Occurrence Handle1:CAS:528:DC%2BD3cXjsVynurs%3D
E Almeida M Morcillo B Rosales (2000) Br. Corros. J. 35 284 Occurrence Handle10.1179/000705900101501353 Occurrence Handle1:CAS:528:DC%2BD3MXisVClu7k%3D
E Almeida M Morcillo B Rosales (2000) Br. Corros. J. 35 289 Occurrence Handle10.1179/000705900101501362 Occurrence Handle1:CAS:528:DC%2BD3MXisVClu7Y%3D
G Vourlias N Pistofidis D Chaliampalias E Pavlidou P Patsalas G Stergioudis D Tsipas EK Polychroniadis (2006) Surf. Coat. Technol. 200 6594 Occurrence Handle10.1016/j.surfcoat.2005.11.039 Occurrence Handle1:CAS:528:DC%2BD28XksVCmt78%3D
PC Powder Diffraction Files, JCPDS-ICDD, 2000.
G Vourlias N Pistofidis G Stergioudis EK Polychroniadis (2005) Sol. St. Sci. 7 465 Occurrence Handle10.1016/j.solidstatesciences.2004.11.001 Occurrence Handle1:CAS:528:DC%2BD2MXjsVemtrY%3D
E Mattson et al. (1996) Basic Corrosion Technology for Scientists and Engineers, 2nd Ed. IOM Communications London
T Brylewski J Dabek K Przybylski (2004) J. Therm. Anal. Cal. 77 207 Occurrence Handle10.1023/B:JTAN.0000033205.69427.8e Occurrence Handle1:CAS:528:DC%2BD2cXlt1ynsbo%3D
InstitutionalAuthorNameAmerican Galvanizers Association et al. (2000) Hot dip galvanizing for corrosion protection of steel products American Galvanizers Association Englewood, Colorado
G Reumont JB Vogt A Iost J Foct (2001) Surf. Coat. Technol. 139 265 Occurrence Handle10.1016/S0257-8972(01)01017-9 Occurrence Handle1:CAS:528:DC%2BD3MXisVWhtro%3D
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Vourlias, G., Pistofidis, N., Chaliambalias, D. et al. Resistance of zinc thermal sprayed coatings on different corrosive environments. J Therm Anal Calorim 87, 401–409 (2007). https://doi.org/10.1007/s10973-006-7798-5
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10973-006-7798-5