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Non-debye nature in thermal relaxation and thermal properties of lithium borate glasses studied by modulated DSC

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Abstract

Complex heat capacity, C p *=C p '–iC p '', of lithium borate glasses xLi2O·(1–x)B2O3 (molar fraction x=0.00–0.30) has been investigated by Modulated DSC. We have analyzed the shape of C p * by the Cole-Cole plot, performed fitting by the Havriliak-Negami equation, and then determined the parameters related to the non-Debye nature of thermal relaxation. Moreover, the concentration dependence of the thermal properties has been investigated. Glass transition temperatures become higher with the increase of molar fraction of Li2O and shows the board peak around x=0.26. Temperature ranges of glass transitions become narrower with the increase of Li2O concentration.

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Authors and Affiliations

  1. Graduate School of Pure and Applied Sciences, University of Tsukuba, Ibaraki, Japan, 305-8571, Tsukuba

    Matsuda Y., Ike Y. & Kojima S.

  2. College of Engineering Sciences, University of Tsukuba, Ibaraki, Japan, 305-8573, Tsukuba

    Matsui C.

  3. Department of Applied Chemistry, Sojo University, Kumamoto, Japan, 860-0082

    Kodama M.

Authors
  1. Matsuda Y.
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  2. Matsui C.
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  3. Ike Y.
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  4. Kodama M.
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  5. Kojima S.
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Correspondence to Matsuda Y..

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Matsuda, Y., Matsui, C., Ike, Y. et al. Non-debye nature in thermal relaxation and thermal properties of lithium borate glasses studied by modulated DSC. J Therm Anal Calorim 85, 725–730 (2006). https://doi.org/10.1007/s10973-006-7652-9

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  • DOI: https://doi.org/10.1007/s10973-006-7652-9

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