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New developments and applications in titration calorimetry and reaction calorimetry

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Abstract

Isothermal titration calorimetry (ITC) and reaction calorimetry (RC) have been used to construct the solid-liquid equilibrium line in ternary systems containing the solute to precipitate and an aqueous mixed solvent, and to study polymerization reactions under real process conditions, respectively. Phase diagrams have been established over the whole concentration range for some benzene substituted derivatives, including o-anisaldehyde, 1,3,5-trimethoxybenzene and vanillin, in {water + alcohol}mixtures at different temperatures. Acrylamide polymerization in aqueous solution using potassium permanganate/acid oxalic redox system as initiator was investigated on a homemade calorimeter, which works according to the isoperibolic mode. A Calvet type differential RC was used to illustrate the applicability of temperature oscillation calorimetry (TOC) for the evaluation of the heat transfer coefficient during the course of reaction.

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Authors and Affiliations

  1. Department of Macromolecular Chemistry, Gh.Asachi Technical University, Iasi, Romania, 700050, 71 Mangeron Ave.

    Dan F.

  2. Mechanical Engineering Department, K.N. Toosi University of Technology, Tehran, Iran, East Vafadar Ave.

    Hamedi M. H.

  3. Laboratory of Thermodynamics of Solutions and Polymers, University Blaise Pascal, Aubière, France, 63177, 24 des Landais Ave.

    Grolier J-P. E.

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  1. Dan F.
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  2. Hamedi M. H.
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  3. Grolier J-P. E.
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Correspondence to Grolier J-P. E..

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Dan, F., Hamedi, M.H. & Grolier, JP.E. New developments and applications in titration calorimetry and reaction calorimetry. J Therm Anal Calorim 85, 531–540 (2006). https://doi.org/10.1007/s10973-006-7639-6

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  • DOI: https://doi.org/10.1007/s10973-006-7639-6

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