Skip to main content
SpringerLink
Log in

Studies of physico-chemical properties of mixed adsorbent in the zeolite/SiO2 system

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

The paper presents physico-chemical properties of mixed adsorbents in the clinoptylolite (mordenite)/SiO2 system containing 30, 50, 80 mass% zeolite. Adsorption capacity towards polar (water, butanol) and non-polar (n-octane) substances as well as total surface heterogeneity (energetic and geometrical) were determined. Desorption energy distribution functions as well as fractal dimensions were also determined and compared with the low-temperature nitrogen adsorption data. Irregular shapes of the curves q=f(E d) as well as large values of volumetric fractal dimensions (D f~2.6) revealed heterogeneous properties of the zeolite/SiO2 system surfaces. Addition of zeolite increases total heterogeneity of the material.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. U Mayer WF Hoelderich (1999) J. Mol. Catal. A: Chem. 142 213 Occurrence Handle10.1016/S1381-1169(98)00289-1

    Article  Google Scholar 

  2. GK Chuah XXuP Zhan S Joenicke (2002) J. Mol. Catal. A: Chem. 181 25 Occurrence Handle1:CAS:528:DC%2BD38XhvFOnu7c%3D Occurrence Handle10.1016/S1381-1169(01)00349-1

    Article  CAS  Google Scholar 

  3. L Bartea HW Kouwanhoven R Prins (1995) Appl. Catal. A 129 229 Occurrence Handle10.1016/0926-860X(95)00105-0

    Article  Google Scholar 

  4. D. Dominé and C. Häy, Molecular Sieves (Soc. Chem. Ind.), London 1968, p. 204.

  5. H Xiubin H Zhanbin (2001) Resources Conservation and Recycling 34 45 Occurrence Handle10.1016/S0921-3449(01)00094-5

    Article  Google Scholar 

  6. A Gladysz-Plaska M Kowalska-Ternes M Majdan (2000) Przem. Chem. 79 298 Occurrence Handle1:CAS:528:DC%2BD3cXntlCgs78%3D

    CAS  Google Scholar 

  7. M Kowalska M Majdan (1999) Przem. Chem. 78 257 Occurrence Handle1:CAS:528:DyaK1MXlslalsr8%3D

    CAS  Google Scholar 

  8. FA Mumpton RH Fishman (1997) J. Anim. Sci. 45 1188

    Google Scholar 

  9. TM Lai DD Eberl (1986) Zeolites 6 129 Occurrence Handle1:CAS:528:DyaL28XhvVGns7s%3D Occurrence Handle10.1016/S0144-2449(86)80010-0

    Article  CAS  Google Scholar 

  10. JE Garcia Hernandez JS Notario del Pino IJ Arteaga-Padron MM Gonzalez-Martin (1992) Agrochimica 32 1

    Google Scholar 

  11. FE Trigueiro DFJ Monteiro FMZ Zotin E Falabella S Aguiar (2002) J. Alloys Compd. 344 337 Occurrence Handle1:CAS:528:DC%2BD38Xns1alsbw%3D Occurrence Handle10.1016/S0925-8388(02)00381-X

    Article  CAS  Google Scholar 

  12. BW Mercer LL Ames Jr. RW Smith (1970) Nucl. Appl. Technol. ECL. 152 62

    Google Scholar 

  13. A Dyer D Keir (1984) Zeolites 4 215 Occurrence Handle1:CAS:528:DyaL2cXlsF2rtLo%3D Occurrence Handle10.1016/0144-2449(84)90026-5

    Article  CAS  Google Scholar 

  14. S. M. Robinson, W. D. Arnold and C. H. Byers, Multicomponent Ion-Exchange Equilibria in Chabazite Zeolite, in: ACS Symposium Series 468, D. W. Tedder and F. G. Pohland (Eds), ACS. Washington. D.C. 1991, pp. 133–152.

  15. P Rajec L Matel J Orechovska J Sucha (1996) J. Radioanal. Nucl. Chem. 208 477 Occurrence Handle1:CAS:528:DyaK28XntF2gtLs%3D Occurrence Handle10.1007/BF02040065

    Article  CAS  Google Scholar 

  16. S Amini A Dyer (1994) J. Radioanal. Nucl. Chem. 178 273 Occurrence Handle1:CAS:528:DyaK2cXkvFakt7c%3D Occurrence Handle10.1007/BF02039721

    Article  CAS  Google Scholar 

  17. FA Nour El-Dien MM Ali MA Zayed (1997) Thermochim. Acta 307 65 Occurrence Handle10.1016/S0040-6031(97)00316-X

    Article  Google Scholar 

  18. E Malliou M Malamis PO Sakellarides (1992) Water Sci. Technol. 25 133

    Google Scholar 

  19. E Malliou M Loizidou N Spyrellis (1994) Sci. Total Environ. 149 139 Occurrence Handle1:CAS:528:DyaK2cXltFOitro%3D Occurrence Handle10.1016/0048-9697(94)90174-0

    Article  CAS  Google Scholar 

  20. Z Li RS Bowman (1997) Environ. Sci. Technol. 31 2407 Occurrence Handle1:CAS:528:DyaK2sXjvFCgtrc%3D Occurrence Handle10.1021/es9610693

    Article  CAS  Google Scholar 

  21. Z Li SJ Roy Y Zou RS Bowman (1998) Environ. Sci. Technol. 32 2628 Occurrence Handle1:CAS:528:DyaK1cXkvVKjsL4%3D Occurrence Handle10.1021/es970841e

    Article  CAS  Google Scholar 

  22. TD Hinsly EK Redborg EL Ziegler JD Alexander (1981) J. Am. Soil Sci. Soc. 46 1009

    Google Scholar 

  23. H Nishita RM Haug (1972) Soil Sci. 114 149 Occurrence Handle1:CAS:528:DyaE38Xlt1ensrc%3D Occurrence Handle10.1097/00010694-197208000-00011

    Article  CAS  Google Scholar 

  24. P Staszczuk D Sternik VV Kutarov (2002) J. Therm. Anal. Cal. 69 23 Occurrence Handle1:CAS:528:DC%2BD38Xms1elt7Y%3D Occurrence Handle10.1023/A:1019973303894

    Article  CAS  Google Scholar 

  25. P Staszczuk VV Kutarov M Płanda (2003) J. Therm. Anal. Cal. 71 445 Occurrence Handle1:CAS:528:DC%2BD3sXitVygurc%3D Occurrence Handle10.1023/A:1022839406755

    Article  CAS  Google Scholar 

  26. D Sternik P Staszczuk G Grodzicka J Pekalska K Skrzypiec (2004) J. Therm. Anal. Cal. 77 171 Occurrence Handle1:CAS:528:DC%2BD2cXlt1yntrw%3D Occurrence Handle10.1023/B:JTAN.0000033201.86803.fa

    Article  CAS  Google Scholar 

  27. AB Kisielev et al. (1958) The Structure and Properties of Porous Materials Butterworths London 195

    Google Scholar 

  28. P Pfeifer D Avnir (1983) J. Chem. Phys. 79 4573

    Google Scholar 

  29. P Pfeifer et al. (1986) Fractals in Physics North-Holland Amsterdam 72

    Google Scholar 

  30. P Staszczuk D Sternik GW Chadzyński VV Kutarov (2004) J. Alloys Compd. 367 277 Occurrence Handle1:CAS:528:DC%2BD2cXhs12ltbk%3D Occurrence Handle10.1016/j.jallcom.2003.08.054

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Physicochemistry of Solid Surface, Chemistry Faculty, Maria Curie-Skłodowska University, Lublin, Poland, 20-031, M. Curie-Skłodowska Sq. 3

    D. Sternik, P. Staszczuk, E. Dąbrowska & K. Bigda

  2. Department of Inorganic Chemistry, Chemistry Faculty, Maria Curie-Skłodowska University, Lublin, Poland, 20-031, M. Curie-Skłodowska Sq. 3

    M. Majdan & A. Gładysz-Płaska

Authors
  1. D. Sternik
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. P. Staszczuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. Majdan
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. Gładysz-Płaska
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. E. Dąbrowska
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. K. Bigda
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to P. Staszczuk.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sternik, D., Staszczuk, P., Majdan, M. et al. Studies of physico-chemical properties of mixed adsorbent in the zeolite/SiO2 system. J Therm Anal Calorim 86, 69–75 (2006). https://doi.org/10.1007/s10973-006-7590-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-006-7590-6

Keywords

Search

Navigation