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Catalytic synthesis of carbon nanotubes over ordered mesoporous matrices

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Abstract

Pyrolytic decomposition of acetylene over the surface of nickel-, cobalt- and iron-containing ordered mesoporous MCM-41 silicas has been studied. Catalytically active matrices have been prepared by chemisorption of volatile metal acetylacetonate complexes on the silica surface. Reduction of the supported metal-containing compounds was carried out in hydrogen or acetylene atmosphere. Acetylene is used not only as a source of carbon in synthesis of the nanostructures but also as a reagent capable of reducing metal ions in the surface chemical compounds. Formation of carbon nanotubes and nanofibers is shown to depend on the pyrolysis conditions.

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Authors and Affiliations

  1. Institute of Surface Chemistry, National Academy of Sciences of Ukraine, Kyiv, Ukraine, 03164, 17 General Naumov Str.

    K. V. Katok, V. A. Tertykh, S. Ya. Brichka & G. P. Prikhod’ko

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  1. K. V. Katok
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  2. V. A. Tertykh
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  3. S. Ya. Brichka
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  4. G. P. Prikhod’ko
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Correspondence to K. V. Katok.

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Katok, K.V., Tertykh, V.A., Brichka, S.Y. et al. Catalytic synthesis of carbon nanotubes over ordered mesoporous matrices. J Therm Anal Calorim 86, 109–114 (2006). https://doi.org/10.1007/s10973-006-7584-4

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  • DOI: https://doi.org/10.1007/s10973-006-7584-4

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