Abstract
This paper presents possible applications of thermal analysis, sorptometry and porosimetry to study physico-chemical properties of Na- and La-montmorillonite samples, especially for determination of total surface heterogeneity. The quasi-isothermal thermogravimetric (Q-TG) mass loss and its first derivative (Q-DTG) curves with respect to temperature and time obtained during programmed liquid thermodesorption under quasi-isothermal conditions have been used to study adsorbed layers and heterogeneous properties of the Na- and La-montmorillonites. Calculations of the desorption energy distribution functions by analytical procedure using mass loss Q-TG and differential mass loss Q-DTG curves of thermodesorption under quasi-isothermal conditions of polar and non-polar liquid vapours preadsorbed on a material surface are presented. Parameters relating to porosity of samples were determined by sorptometry, mercury porosimetry and atomic force microscopy (AFM). From nitrogen sorption isotherms from sorptometry and porosimetry methods, the fractal dimensions of montmorillonites have been calculated. Moreover, a new approach is proposed to calculate fractal dimensions of materials obtained from Q-TG curve; this is compared with values obtained by the above methods. The total heterogeneous properties (energy distribution function and pore-size distribution functions) of samples studied were estimated. The radius and pore volume of the tested samples calculated on the basis of thermogravimetry, sorptometry and porosimetry techniques were compared and good correlations obtained.
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References
SL Swartzen-Allen E Matijevic (1974) Chem. Rev. 74 385 Occurrence Handle1:CAS:528:DyaE2cXktFKqt7w%3D Occurrence Handle10.1021/cr60289a004
L Stoch et al. (1974) Minerały ilaste (Clays minerals) Wyd. Geologiczne Warsaw
E Chibowski P Staszczuk (1988) Clays Clay Miner. 36 455 Occurrence Handle1:CAS:528:DyaL1cXmtlChurg%3D Occurrence Handle10.1346/CCMN.1988.0360511
M Gay-Duchosal DH Powell RE Lechne B Ruffle (2000) Physica B 276–278 234 Occurrence Handle10.1016/S0921-4526(99)01421-0
PX Wu ZW Liau HF Zhang JG Guo (2001) Environment International 26 401 Occurrence Handle1:CAS:528:DC%2BD3MXkslOjur0%3D Occurrence Handle10.1016/S0160-4120(01)00019-8
A Negron-Mendoza S Ramos-Bernal G Albarran J Reyes-Gasga (1997) Nanostruct. Mater. 9 209 Occurrence Handle1:CAS:528:DyaK2sXnt1SrsLc%3D Occurrence Handle10.1016/S0965-9773(97)00055-X
S Sivakumar AD Damodaran KGK Warrier FJ Berry L Smart (1995) Polyhedron 15 2201 Occurrence Handle10.1016/0277-5387(95)00005-D
S Narayanana K Deshpande (2000) Appl. Catal., A 193 17 Occurrence Handle10.1016/S0926-860X(99)00402-0
HP He JG Guo XD Xie JL Peng (2001) Environment International 26 347 Occurrence Handle1:CAS:528:DC%2BD3MXkslOjtLY%3D Occurrence Handle10.1016/S0160-4120(01)00011-3
F Rey-Bueno A Garcia-Rodriquez A Mata-Arjona FJ Rey-Perez-Caballero E Villafranca-Sanchez (1997) Appl. Surf. Sci. 120 340 Occurrence Handle10.1016/S0169-4332(97)00381-4
Y Fan H Wu (1997) Solid State Ionics 93 347 Occurrence Handle1:CAS:528:DyaK2sXhtlynu74%3D Occurrence Handle10.1016/S0167-2738(96)00446-8
FM Etzler (1983) J. Colloid Interface Sci. 92 43 Occurrence Handle1:CAS:528:DyaL3sXhtFCgsbg%3D Occurrence Handle10.1016/0021-9797(83)90115-7
FM Etzler JJ Conners (1990) Langmuir 6 1250 Occurrence Handle1:CAS:528:DyaK3cXksVOisb8%3D Occurrence Handle10.1021/la00097a010
JL Harden D Andelman (1992) Langmuir 8 2547 Occurrence Handle1:CAS:528:DyaK38Xlsl2jsLg%3D Occurrence Handle10.1021/la00046a031
P Staszczuk (1995) Colloids Surf., A 94 213 Occurrence Handle1:CAS:528:DyaK2MXjtl2rtrw%3D Occurrence Handle10.1016/0927-7757(95)03000-X
Y Laureiro A Jerez F Rouquerol J Rouquerol (1996) Thermochim. Acta 278 165 Occurrence Handle1:CAS:528:DyaK28Xjs1ams7k%3D Occurrence Handle10.1016/0040-6031(95)02330-5
S Sivakumar AD Damodaran KGK Warrier FJ Berry L Smart (1995) Polyhedron 15 2201 Occurrence Handle10.1016/0277-5387(95)00005-D
E Iwamatsu E Hayashi Y Sanda S Ahmed SA Ali AKK Lee H Hamid T Yoneda (1999) Appl. Catal., A 179 139 Occurrence Handle1:CAS:528:DyaK1MXhsVegur4%3D Occurrence Handle10.1016/S0926-860X(98)00305-6
SJ Gregg KSW Sing et al. (1982) Adsorption, Surface Area and Porosity Academic Press London
P Staszczuk (1998) J. Thermal Anal. 53 597 Occurrence Handle1:CAS:528:DyaK1cXns1Ggt7w%3D Occurrence Handle10.1023/A:1010166131014
VI Bogillo P Staszczuk (1999) J. Therm. Anal. Cal. 55 493 Occurrence Handle1:CAS:528:DyaK1MXivFWqsr8%3D Occurrence Handle10.1023/A:1010145919510
P Staszczuk (1984) J. Thermal Anal. 29 217 Occurrence Handle1:CAS:528:DyaL2cXmtFKrurY%3D
M Matyjewicz P Staszczuk JC Bazan NJ Garcia (2003) Annals Pol. Chem. Soc. 2 659
F Paulik et al. (1995) Special Trends in Thermal Analysis J. Wiley & Sons Chichester
P Staszczuk (1994) Thermochim. Acta 247 169 Occurrence Handle1:CAS:528:DyaK2MXivVOrs7o%3D Occurrence Handle10.1016/0040-6031(94)80119-3
P Staszczuk GW Chądzyński D Sternik (2000) J. Therm. Anal. Cal. 62 451 Occurrence Handle1:CAS:528:DC%2BD3MXptleq Occurrence Handle10.1023/A:1010102618100
P Staszczuk (1996) Am. Lab. 28 21 Occurrence Handle1:CAS:528:DyaK28XlsVansL0%3D
V Dondur D Vucelic (1983) Thermochim. Acta 68 91 Occurrence Handle1:CAS:528:DyaL3sXls1Cntrs%3D Occurrence Handle10.1016/0040-6031(83)80383-9
V Dondur D Vucelic (1983) Thermochim. Acta 68 101 Occurrence Handle1:CAS:528:DyaL3sXls1Cntrg%3D Occurrence Handle10.1016/0040-6031(83)80384-0
V Dondur D Vucelic (1983) Thermochim. Acta 68 103
P Staszczuk D Sternik VV Kutarov (2002) J. Therm. Anal. Cal. 69 23 Occurrence Handle1:CAS:528:DC%2BD38Xms1elt7Y%3D Occurrence Handle10.1023/A:1019973303894
WI Frisen WG Laidlaw (1993) J. Colloid Interface Sci. 160 226 Occurrence Handle10.1006/jcis.1993.1388
SP Rigby RS Fletcher SN Riley (2001) J. Colloid Interface Sci. 240 190 Occurrence Handle1:CAS:528:DC%2BD3MXkvFyjtr4%3D Occurrence Handle10.1006/jcis.2001.7636
BM Kats VV Kutarov (1996) Langmuir 12 2762 Occurrence Handle1:CAS:528:DyaK28XivVCgu7g%3D Occurrence Handle10.1021/la9403441
AV Kiselev et al. (1958) The Structure and Properties of Porous Materials Butterworths London 195
P Pfeifer M Obert et al. (1989) The Fractal Approach to Heterogeneous Chemistry Wiley Chichester
D-P Tao (1999) Thermochim. Acta 338 125 Occurrence Handle1:CAS:528:DyaK1MXmvFCrsb0%3D Occurrence Handle10.1016/S0040-6031(99)00215-4
P Staszczuk D Sternik GW Chądzyński (2003) J. Therm. Anal. Cal. 71 173 Occurrence Handle1:CAS:528:DC%2BD3sXptFyhtw%3D%3D Occurrence Handle10.1023/A:1022278520075
WI Frisen RJ Mikula (1987) J. Colloid Interface Sci. 120 263 Occurrence Handle10.1016/0021-9797(87)90348-1
P Staszczuk (2005) J. Therm. Anal. Cal. 79 545 Occurrence Handle1:CAS:528:DC%2BD2MXisFynsb4%3D Occurrence Handle10.1007/s10973-005-0577-x
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Staszczuk, P., Bazan, J.C., Błachnio, M. et al. Studies of surface properties of Na- and La-montmorillonites. J Therm Anal Calorim 86, 57–68 (2006). https://doi.org/10.1007/s10973-006-7577-3
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DOI: https://doi.org/10.1007/s10973-006-7577-3