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Enthalpies of dilution and homotactic enthalpic interaction coefficients of THF and 1,4-dioxane at 298.15 k

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Abstract

Enthalpies of dilution at 298.15 K of aqueous solutions of THF and 1,4-dioxane have been determined using flow microcalorimetry. The results obtained were used to determine the homotactic enthalpic interaction coefficients that characterize pair interactions of THF and 1,4-dioxane in aqueous solution. These are briefly discussed from the point of view of intermolecular interaction between the hydrated solute species.

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Authors and Affiliations

  1. Key Lab for Colloid and Interface Chemistry of Shandong University, Ministry of Education, Jinan, 250100, P.R. China

    Y. Li, G. Fei & L. Zhen

  2. Department of Chemistry, Zhejiang University, Hangzhou, 310027, P.R. China

    Y. Li & L. Ruisen

  3. Department of Chemistry, Wenzhou Normal College, Wenzhou, 325000, P.R. China

    H. Xingen

Authors
  1. Y. Li
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  2. G. Fei
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  3. H. Xingen
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  4. L. Ruisen
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  5. L. Zhen
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Correspondence to Y. Li.

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Li, Y., Fei, G., Xingen, H. et al. Enthalpies of dilution and homotactic enthalpic interaction coefficients of THF and 1,4-dioxane at 298.15 k. J Therm Anal Calorim 92, 771–774 (2008). https://doi.org/10.1007/s10973-006-7450-4

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  • DOI: https://doi.org/10.1007/s10973-006-7450-4

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