Skip to main content
SpringerLink
Log in

Transition metal complexes of heterocyclic Schiff base

Biological activity, spectroscopic and thermal characterization

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

Metal complexes of Schiff base derived from 2-furancarboxaldehyde and 2-aminobenzoic acid (HL) are reported and characterized based on elemental analyses, IR, 1H NMR, UV-Vis, solid reflectance, magnetic moment, molar conductance and thermal analysis. The ligand dissociation as well as the metal-ligand stability constants have been calculated pH-metrically at 25°C and ionic strength μ=0.1 (1 M NaCl). The complexes are found to have the formulae [M(HL)2](X)n·yH2O (where M=Fe(III) (X=Cl, n=3, y=4), Co(II) (X=Cl, n=y=2), Ni(II) (X=Cl, n=y=2), Cu(II) (X=Cl, n=y=2) and Zn(II) (X=AcO, n=y=2)) and [UO2(L)2]·2H2O. The thermal behaviour of these chelates is studied and the activation thermodynamic parameters are calculated using Coats-Redfern method. The ligand and its metal complexes show a biological activity against some bacterial species.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. HA El-Boraey (2005) J. Therm. Anal. Cal. 81 339 Occurrence Handle1:CAS:528:DC%2BD2MXnslyqs74%3D Occurrence Handle10.1007/s10973-005-0789-0

    Article  CAS  Google Scholar 

  2. ASM Al-Shiri HM Abdel-Fattah (2003) J. Therm. Anal. Cal. 71 643 Occurrence Handle10.1023/A:1022880615841

    Article  Google Scholar 

  3. J Estrela dos Santos ER Dockal ETG Cavalheiro (2003) J. Therm. Anal. Cal. 79 243 Occurrence Handle10.1007/s10973-005-0042-x

    Article  Google Scholar 

  4. W Scott H Furman et al. (1962) Standard Methods of Chemical Analysis Von Nostrand New York

    Google Scholar 

  5. CE Housecroft AG Sharpe et al. (2001) Inorganic Chemistry, 1st edn. Pearson Education Limited Harlow, England

    Google Scholar 

  6. R Sarin KN Munshi (1972) J. Inorg. Nucl. Chem. 34 581 Occurrence Handle1:CAS:528:DyaE38XhtVClurs%3D Occurrence Handle10.1016/0022-1902(72)80438-X

    Article  CAS  Google Scholar 

  7. N Sari S Arslan E Logoglu I Sakiyan (2003) J. Sci. 16 283

    Google Scholar 

  8. H Irving HS Rossotti (1954) J. Chem. Soc. 1 2904 Occurrence Handle10.1039/jr9540002904

    Article  Google Scholar 

  9. J Bjerrum et al. (1941) Kgl. ‘Metal Amine Formation in Aqueous Solution’ Haase Kopenhagen

    Google Scholar 

  10. H Irving HS Rossotti (1953) J. Chem. Soc. 1 3397 Occurrence Handle10.1039/jr9530003397

    Article  Google Scholar 

  11. H Irving RJP Williams (1948) Nature 162 746 Occurrence Handle1:CAS:528:DyaH1MXislSjsQ%3D%3D

    CAS  Google Scholar 

  12. H Irving RJP Williams (1953) J. Chem. Soc. 1 3192 Occurrence Handle10.1039/jr9530003192

    Article  Google Scholar 

  13. GG Mohamed ZH Abd El Wahwb (2003) J. Therm. Anal. Cal. 73 347 Occurrence Handle1:CAS:528:DC%2BD3sXmt1emtLw%3D Occurrence Handle10.1023/A:1025126801265

    Article  CAS  Google Scholar 

  14. MA Zayed FA Nour El-Dien GG Mohamed Nadia EA El-Gamel (2004) Spectrochim. Acta, Part A 60 2843 Occurrence Handle1:STN:280:DC%2BD2cvksVaqtw%3D%3D Occurrence Handle10.1016/j.saa.2003.12.051

    Article  CAS  Google Scholar 

  15. AP Mishra (1999) J. Indian Chem. Soc. 76 35 Occurrence Handle1:CAS:528:DyaK1MXjvF2kt70%3D

    CAS  Google Scholar 

  16. A Kriza M Voiculescu A Nicolae (2002) Analele Universitatii Bucuresti. Chimie 11 197 Occurrence Handle1:CAS:528:DC%2BD38XpsVGlu74%3D

    CAS  Google Scholar 

  17. FA Cotton G Wilkinson CA Murillo M Bochmann et al. (1999) Advanced Inorganic Chemistry, 6th edn. Wiley New York

    Google Scholar 

  18. J Kohout M Hvastijova J Kozisek JG Diaz M Valko L Jager I Svoboda (1999) Inorg. Chim. Acta 287 186 Occurrence Handle1:CAS:528:DyaK1MXjt1SjtL8%3D Occurrence Handle10.1016/S0020-1693(99)00013-4

    Article  CAS  Google Scholar 

  19. J Sanmartin MR Bermejo AMG Deibe M Maneiro C Lage AJC Filho (2002) Polyhedron 19 185 Occurrence Handle10.1016/S0277-5387(99)00341-1

    Article  Google Scholar 

  20. VP Krzyminiewska H Litkowska WR Paryzek (1999) Monatsh. Chem. 130 243

    Google Scholar 

  21. K Bertoncello GD Fallon KS Murray ERT Tiekink (1991) Inorg. Chem. 30 3562 Occurrence Handle1:CAS:528:DyaK3MXlt1GmsLs%3D Occurrence Handle10.1021/ic00018a033

    Article  CAS  Google Scholar 

  22. M Badea A Emandi D Marinescu E Cristarean R Olar A Braileanu P Budrugeac E Segal (2003) J. Therm. Anal. Cal. 72 525 Occurrence Handle1:CAS:528:DC%2BD3sXltVWhsrc%3D Occurrence Handle10.1023/A:1024517430630

    Article  CAS  Google Scholar 

  23. AW Coats JP Redfern (1964) Nature 20 68 Occurrence Handle10.1038/201068a0

    Article  Google Scholar 

  24. MM Omar (2003) J. Therm. Anal. Cal. 68 1003 Occurrence Handle10.1023/A:1016159010160

    Article  Google Scholar 

  25. DC Shanson et al. (1982) Microbiology in Clinical Practice Wright PSG Bristol, London, Boston

    Google Scholar 

  26. E Jawetz JL Melnick EA Adelberg et al. (1979) Review of Medical Microbiology, 16th edn. Lang Medical Publications Los Angeles, California

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Chemistry Department, Faculty of Science, Cairo University, Giza, Egypt

    M. M. Omar, G. G. Mohamed & A. M. M. Hindy

Authors
  1. M. M. Omar
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. G. Mohamed
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. M. M. Hindy
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Omar, M.M., Mohamed, G.G. & Hindy, A.M.M. Transition metal complexes of heterocyclic Schiff base. J Therm Anal Calorim 86, 315–325 (2006). https://doi.org/10.1007/s10973-006-7095-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-006-7095-3

Keywords

Search

Navigation