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Comparison of different -nucleators for isotactic polypropylene, characterisation by DSC and temperature-modulated DSC (TMDSC) measurements

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Abstract

The nucleating efficiency and selectivity of different β-nucleating agents was characterised and compared by differential scanning calorimetry, (DSC) and temperature-modulated DSC (TMDSC). The nucleating agents were the calcium salts of pimelic and suberic acid (Ca-pim and Ca-sub), linear trans-γ-quinacridone (LTQ), a commercial nucleator NJ Star (NJS) and an experimental product (CGX-220). The efficiency and the selectivity of Ca-sub and Ca-pim are extremely high. NJS is efficient above a critical concentration, which is connected with its partial dissolution in polypropylene melt. LTQ and CGX-220 possess strong overall nucleating ability and moderate selectivity. Using TMDSC, we found that three consecutive processes take place during the heating of β-nucleated samples cooled down to room temperature: reversible partial melting of the β-form, irreversible βα-recrystallisation, and the melting of the α-modification formed during βα-recrystallisation or being present in samples prepared with non-selective β-nucleators. Melting of the α-phase contains both reversible and irreversible components.

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References

  1. B Lotz JC Wittmann AJ Lovinger (1996) Polymer 37 4979 Occurrence Handle1:CAS:528:DyaK28Xms1ynsrk%3D Occurrence Handle10.1016/0032-3861(96)00370-9

    Article  CAS  Google Scholar 

  2. J Varga (2002) J. Macromol. Sci. Part-B Phys. 41 1121 Occurrence Handle10.1081/MB-120013089

    Article  Google Scholar 

  3. HJ Leugering (1967) Makromol. Chem. 109 204 Occurrence Handle1:CAS:528:DyaF1cXjt1Or Occurrence Handle10.1002/macp.1967.021090118

    Article  CAS  Google Scholar 

  4. J Varga I Mudra GW Ehrenstein (1999) J. Therm. Anal. Cal. 56 1047 Occurrence Handle1:CAS:528:DyaK1MXnt1Wntbo%3D Occurrence Handle10.1023/A:1010132306934

    Article  CAS  Google Scholar 

  5. G Shi X Zhang Z Qui (1992) Makromol. Chem. 193 583 Occurrence Handle1:CAS:528:DyaK38XitFGhtb0%3D Occurrence Handle10.1002/macp.1992.021930303

    Article  CAS  Google Scholar 

  6. N. Ikeda, T. Kobayashi and L. Killough, Polypropylene’96. World Congress, Zurich, Switzerland, 18–20th Sept., 1996

  7. M Varma-Nair PK Agarwal (2000) J. Therm. Anal. Cal. 59 483 Occurrence Handle1:CAS:528:DC%2BD3cXivFKrtLk%3D Occurrence Handle10.1023/A:1010145625770

    Article  CAS  Google Scholar 

  8. C Marco MA Gomez G Ellis JM Arribas (2002) J. Appl. Polym. Sci. 86 531 Occurrence Handle1:CAS:528:DC%2BD38Xmtl2ns7Y%3D Occurrence Handle10.1002/app.10811

    Article  CAS  Google Scholar 

  9. J Kotek M Raab J Baldrian W Grellmann (2002) J. Appl. Polym. Sci. 85 1174 Occurrence Handle1:CAS:528:DC%2BD38Xks12gtbg%3D Occurrence Handle10.1002/app.10701

    Article  CAS  Google Scholar 

  10. A Romankiewitz T Sterzynski W Brostow (2004) Polymer Int. 53 2086 Occurrence Handle10.1002/pi.1632

    Article  Google Scholar 

  11. M. Obadal, R. Cermak, R. Cabla and K. Stoklasa, ANTEC, (2004) 3045.

  12. M Obadal R Cermak N Baran K Stoklasa I Simonik (2004) Int. Polymer Proc. 19 35 Occurrence Handle1:CAS:528:DC%2BD2cXks1yhsrg%3D Occurrence Handle10.3139/217.1802

    Article  CAS  Google Scholar 

  13. J Varga (1986) J. Thermal Anal. 31 165 Occurrence Handle1:CAS:528:DyaL28Xks1Whsb4%3D Occurrence Handle10.1007/BF01913897

    Article  CAS  Google Scholar 

  14. J Varga (1995) Crystallization, Melting and Supermolecular Structure of Isotactic Polypropylene, In: ‘Polypropylene: Structure Blends and Composites’ Vol. 1 Chapman and Hill London 56 Occurrence Handle10.1007/978-94-011-0567-5_3

    Book  Google Scholar 

  15. P Forgács BP Tolochko MA Sheromov (1981) Polymer Bull. 6 127 Occurrence Handle10.1007/BF00256515

    Article  Google Scholar 

  16. J Garbarczyk T Sterzynski D Paukszta (1989) Polymer Comm. 30 153 Occurrence Handle1:CAS:528:DyaL1MXksFylsLg%3D

    CAS  Google Scholar 

  17. S Vleeshouwers (38) Polymer 1997 3213

    Google Scholar 

  18. K Cho DN Saheb J Choi H Yang (2002) Polymer 43 1407 Occurrence Handle1:CAS:528:DC%2BD3MXpt1Wqsb8%3D Occurrence Handle10.1016/S0032-3861(01)00729-7

    Article  CAS  Google Scholar 

  19. K Cho DN Saheb H Yang BI Kang J Kim (2003) Polymer 44 4053 Occurrence Handle1:CAS:528:DC%2BD3sXkt1Wltr4%3D Occurrence Handle10.1016/S0032-3861(03)00305-7

    Article  CAS  Google Scholar 

  20. A Turner Jones JM Aizlewood DR Beckett (1964) Makromol. Chem. 75 134 Occurrence Handle1:CAS:528:DyaF2cXksVyhtro%3D Occurrence Handle10.1002/macp.1964.020750113

    Article  CAS  Google Scholar 

  21. J Karger-Kocsis PP Shang (1998) J. Therm. Anal. Cal. 51 237 Occurrence Handle1:CAS:528:DyaK1cXns1agt78%3D Occurrence Handle10.1007/BF02719025

    Article  CAS  Google Scholar 

  22. I MacDonald S Clarke R Pillar M Ginic-Markovic J Matisons (2005) J. Therm. Anal. Cal. 80 781 Occurrence Handle1:CAS:528:DC%2BD2MXks1Cjt7o%3D Occurrence Handle10.1007/s10973-005-0729-z

    Article  CAS  Google Scholar 

  23. A Genovese RA Shanks (2004) J. Therm. Anal. Cal. 75 233 Occurrence Handle1:CAS:528:DC%2BD2cXhsFaisrY%3D Occurrence Handle10.1023/B:JTAN.0000017345.31134.8d

    Article  CAS  Google Scholar 

  24. AA Duswalt WW Cox (1971) Polymer Characterization, Interdisciplinary Approaches Plenum Press New York, London 147 Occurrence Handle10.1007/978-1-4684-1929-0_9

    Book  Google Scholar 

  25. T Sterzynski P Calo M Lambla M Thomas (1997) Polymer Eng. Sci. 37 1917 Occurrence Handle1:CAS:528:DyaK1cXhtVWksg%3D%3D Occurrence Handle10.1002/pen.11842

    Article  CAS  Google Scholar 

  26. M Fujiyama (1996) Intern. Polymer Proc. 11 271 Occurrence Handle1:CAS:528:DyaK28XmtlKrsbc%3D Occurrence Handle10.3139/217.960271

    Article  CAS  Google Scholar 

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  1. Budapest University of Technology and Economics, Department of Plastic and Rubber Technology, Budapest, Hungary, P.O. Box 92, 1521

    Menyhárd A., Varga J. & Molnár G.

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  1. Menyhárd A.
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  2. Varga J.
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  3. Molnár G.
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Menyhárd, A., Varga, J. & Molnár, G. Comparison of different -nucleators for isotactic polypropylene, characterisation by DSC and temperature-modulated DSC (TMDSC) measurements. J Therm Anal Calorim 83, 625–630 (2006). https://doi.org/10.1007/s10973-005-7498-6

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