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Thermal decomposition kinetics of some aromatic azomonoethers

Part 1. Decomposition of 4-[(4-chlorobenzyl)oxy]-4’-nitro-azobenzene

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Abstract

The non-isothermal kinetic parameters corresponding to the decomposition of 4-[(4-chlorobenzyl)oxy]-4’-nitro-azobenzene were evaluated. The kinetic analysis was performed by means of different multi-heating rates methods: isoconversional (‘model-free’) methods (Flynn–Wall–Ozawa) and invariant kinetic parameters method (IKP) associated with the criterion of the independence of activation parameters on the heating rate. The values of the obtained non-isothermal kinetic parameters are in satisfactory agreement.

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Authors and Affiliations

  1. Department of Physical Chemistry, Faculty of Chemistry, University of Bucharest, Bucharest, Romania, Bvd. Regina Elisabeta Nr. 4-12

    A. Rotaru, I. Sălăgeanu & E. Segal

  2. Department of Organic Chemistry, Faculty of Chemistry, University of Craiova, Craiova, Romania, Str. Calea Bucuresti, Nr. 107 I

    Anca Moanta

  3. ICPE-CA Advanced Research Institute for Electrical Engineering, Bucharest, Romania, 74204, Splaiul Unirii 313

    P. Budrugeac

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  1. A. Rotaru
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  2. Anca Moanta
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  3. I. Sălăgeanu
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  4. P. Budrugeac
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  5. E. Segal
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Correspondence to E. Segal.

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Rotaru, A., Moanta, A., Sălăgeanu, I. et al. Thermal decomposition kinetics of some aromatic azomonoethers. J Therm Anal Calorim 87, 395–400 (2007). https://doi.org/10.1007/s10973-005-7435-8

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  • DOI: https://doi.org/10.1007/s10973-005-7435-8

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