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A kinetic study of the thermal degradation of 3-methylaminopropylamine inside AlPO4-21

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Abstract

Kinetics of the thermal decomposition of 3-methylaminopropylamine which was used as a structure-directing agent in the synthesis of AlPO4-21 has been studied under isothermal and non-isothermal conditions. The decomposition is a single-step reaction occurring in the 573–663 K range. It is a phase-boundary-controlled process, described by the ‘F2/3, R3’ kinetic model. The activation energy values obtained under the non-isothermal and isothermal conditions lie in the 173–151 kJ mol–1 range.

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References

  1. N. Rajic and V. Kaucic, Molecular sieves: Aluminophosphates, in Encyclopedia of Catalysis, Vol. 5, Ed. I. T. Horvath, John Wiley & Sons, Inc., Hoboken 2003, p. 188.

  2. AF Ojo LB McCusker (1991) Zeolites 11 460 Occurrence Handle10.1016/S0144-2449(05)80118-6 Occurrence Handle1:CAS:528:DyaK3MXltVejur8%3D

    Article  CAS  Google Scholar 

  3. AK Sinha S Sainkar S Sivasanker (1999) Microporous Mesoporous Mater. 31 321 Occurrence Handle10.1016/S1387-1811(99)00081-5 Occurrence Handle1:CAS:528:DyaK1MXmtVyhtL8%3D

    Article  CAS  Google Scholar 

  4. JB Parise CS Day (1985) Acta Cryst. C41 515 Occurrence Handle1:CAS:528:DyaL2MXhvFGls7g%3D

    CAS  Google Scholar 

  5. JM Bennett JM Cohen G Artioli JJ Pluth JV Smith (1985) Inorg. Chem. 24 188 Occurrence Handle10.1021/ic00196a014 Occurrence Handle1:CAS:528:DyaL2MXosl2mtw%3D%3D

    Article  CAS  Google Scholar 

  6. Z Liu W Xu G Yang R Xu (1998) Microporous Mesoporous Mater. 22 33 Occurrence Handle10.1016/S1387-1811(98)00105-X Occurrence Handle1:CAS:528:DyaK1cXls12mt7c%3D

    Article  CAS  Google Scholar 

  7. R Jelinek BF Chmelka Y Wu PJ Grandinetti A Pines PJ Barrie K Klinowski (1991) J. Am. Chem. Soc. 113 4097 Occurrence Handle10.1021/ja00011a007 Occurrence Handle1:CAS:528:DyaK3MXitl2itrk%3D

    Article  CAS  Google Scholar 

  8. JJM Orfao FG Martins (2002) Thermochim. Acta 390 195 Occurrence Handle10.1016/S0040-6031(02)00133-8 Occurrence Handle1:CAS:528:DC%2BD38XkslCrtr8%3D

    Article  CAS  Google Scholar 

  9. RM Mahfouz MAS Monshi NM Abd El-Salam (2002) Thermochim. Acta 383 95 Occurrence Handle10.1016/S0040-6031(01)00682-7 Occurrence Handle1:CAS:528:DC%2BD38XktlOluw%3D%3D

    Article  CAS  Google Scholar 

  10. T Vlase G Vlase A Chiriac N Doca (2005) J. Therm. Anal. Cal. 80 87 Occurrence Handle10.1007/s10973-005-0618-5 Occurrence Handle1:CAS:528:DC%2BD2MXktl2ksL8%3D

    Article  CAS  Google Scholar 

  11. T Vlase G Vlase N Doca (2005) J. Therm. Anal. Cal. 80 207 Occurrence Handle10.1007/s10973-005-0637-2 Occurrence Handle1:CAS:528:DC%2BD2MXktl2ksrw%3D

    Article  CAS  Google Scholar 

  12. T Vlase G Vlase N Doca C Bolcu (2005) J. Therm. Anal. Cal. 80 59 Occurrence Handle10.1007/s10973-005-0613-x Occurrence Handle1:CAS:528:DC%2BD2MXktl2ksLg%3D

    Article  CAS  Google Scholar 

  13. P Budrugeac C Popescu E Segal (2001) J. Therm. Anal. Cal. 64 821 Occurrence Handle10.1023/A:1011521201269 Occurrence Handle1:CAS:528:DC%2BD3MXkslWlu7Y%3D

    Article  CAS  Google Scholar 

  14. G Pokol G Várhegyi (1988) CRC Critical Reviews in Analytical Chemistry 19 65 Occurrence Handle1:CAS:528:DyaL1MXhs1SqsL4%3D

    CAS  Google Scholar 

  15. A Corma FL Copis IB Monton S Waller (1993) J. Catal. 142 97 Occurrence Handle10.1006/jcat.1993.1192 Occurrence Handle1:CAS:528:DyaK3sXlsVOns70%3D

    Article  CAS  Google Scholar 

  16. P Budrugeac (2005) Polym. Degrad. Stab. 89 265 Occurrence Handle10.1016/j.polymdegradstab.2004.09.014 Occurrence Handle1:CAS:528:DC%2BD2MXktFajtrc%3D

    Article  CAS  Google Scholar 

  17. T Vlase G Vlase N Doca (2005) J. Therm. Anal. Cal. 80 425 Occurrence Handle10.1007/s10973-005-0671-0 Occurrence Handle1:CAS:528:DC%2BD2MXjvVCmsb8%3D

    Article  CAS  Google Scholar 

  18. P Budrugeac D Homentcovschi E Segal (2001) J. Therm. Anal. Cal. 63 457 Occurrence Handle10.1023/A:1010148611036 Occurrence Handle1:CAS:528:DC%2BD3MXisFWisr0%3D

    Article  CAS  Google Scholar 

  19. ME Brown M Maciejewski S Vyazovkin R Nomen J Sempere A Burnham J Opfermann R Strey HL Anderson A Kemmler R Keuleers J Janssens HO Desseyn C-R Li TB Tang B Roduit J Malek T Mitsuhashi (2000) Thermochim. Acta 355 125 Occurrence Handle10.1016/S0040-6031(00)00443-3 Occurrence Handle1:CAS:528:DC%2BD3cXktVSjsr0%3D

    Article  CAS  Google Scholar 

  20. HL Friedman (1965) J. Polym. Sci. 6C 183

    Google Scholar 

  21. J Guo AC Lua (2000) J. Therm. Anal. Cal. 59 763 Occurrence Handle10.1023/A:1010149619877 Occurrence Handle1:CAS:528:DC%2BD3cXjt1Clsb8%3D

    Article  CAS  Google Scholar 

  22. E Tomaszewicz M Kotfica (2004) J. Therm. Anal. Cal. 77 25 Occurrence Handle10.1023/B:JTAN.0000033184.32714.7f Occurrence Handle1:CAS:528:DC%2BD2cXlt1yntbc%3D

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Faculty of Technology and Metallurgy, Belgrade, Serbia and Montenegro, 11000, Karnegijeva 4

    D. Stojakovic, Nevenka Rajic & Sanja Sajic

  2. National Institute of Chemistry, Ljubljana, Slovenia, 1000, Hajdrihova 19

    Natasa Zabukovec Logar & V. Kaucic

Authors
  1. D. Stojakovic
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  2. Nevenka Rajic
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  3. Sanja Sajic
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  4. Natasa Zabukovec Logar
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  5. V. Kaucic
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Correspondence to D. Stojakovic.

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Stojakovic, D., Rajic, N., Sajic, S. et al. A kinetic study of the thermal degradation of 3-methylaminopropylamine inside AlPO4-21. J Therm Anal Calorim 87, 339–343 (2007). https://doi.org/10.1007/s10973-005-7382-4

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  • DOI: https://doi.org/10.1007/s10973-005-7382-4

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