Skip to main content
SpringerLink
Log in

Photoinitiating behavior of macrophotoinitiator containing aminoalkylphenone group

Free-radical polymerization

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

Photoinitiating behaviors of oligo(α-aminoketones) (OAK) macrophotoinitiator containing aminoalkylphenone group on free-radical photopolymerization had been investigated by differential photo-calorimetry (DPC). The macrophotoinitiator showed comparative performance with those commercial photoinitiators with lower molecular mass. The effect of photoinitiator concentrations and UV intensity on the polymerization rate was investigated, and the value of exponential factor was found to be 0.5 at the beginning of polymerization, suggesting that the photopolymerization initiated by OAK followed biradical termination mechanism. Photosensitizer isopropyl thioxanthone (ITX) and oxygen severely restricted the polymerization in these systems. Photoinitiators with lower molecular mass showed higher reactivity than those with higher molecular mass.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. HF Gruber (1992) Progress Polym. Sci. 17 953 Occurrence Handle1:CAS:528:DyaK3sXkt1ylsLk%3D Occurrence Handle10.1016/0079-6700(92)90006-K

    Article  CAS  Google Scholar 

  2. R Stephen Davidson (1993) J. Photochem. Photobiol. A,69 263. Occurrence Handle10.1016/1010-6030(93)85092-M

    Article  Google Scholar 

  3. JP Fouassier D Ruhlmann B Graff F Wieder (1995) Progress in Organic Coatings 25 169 Occurrence Handle10.1016/0300-9440(94)00508-X

    Article  Google Scholar 

  4. K Dietliker (1991) In Chemistry and Technology of UV and EB Formulation for Coating, Inks and Paints, Oldring PKT, Ed.; SITA Technology London 151

    Google Scholar 

  5. GD Ye JW Yang ZH Zeng YL Chen (2006) J. Appl. Polym. Sci., 99 3417. Occurrence Handle10.1002/app.22956

    Article  Google Scholar 

  6. JE Moore (1978 ) In: S. P. Pappas, UV Curing: Science and Technology Vol.1, Technology Marketing Corp. Norwalk. Conn. p. 85.

    Google Scholar 

  7. GA Brady JW Halloran (1998) J. Mater. Sci., 33 4551. Occurrence Handle10.1023/A:1004416705140

    Article  Google Scholar 

  8. R Sastre M Conde JL Mateo (1988) J. Photochem. Photobiol. A, 44 111 Occurrence Handle10.1016/1010-6030(88)85010-X

    Article  Google Scholar 

  9. CSB Ruiz LDB Machado JE Volponi ES Pino (2004) J. Therm. Anal. Cal. 75 507 Occurrence Handle1:CAS:528:DC%2BD2cXisVKjsrg%3D Occurrence Handle10.1023/B:JTAN.0000027140.27560.d1

    Article  CAS  Google Scholar 

  10. G Rist A Borer K Dietliker V Desobry JP Fouassier D Ruhlmann (1992) Macromolecules 25 4182 Occurrence Handle1:CAS:528:DyaK38XksFSku7o%3D Occurrence Handle10.1021/ma00042a020

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, People’s Republic of China, 510275

    J. W. Yang, Z. H. Zeng & Y. L. Chen

  2. Department of Chemistry, Guangzhou Medical College, Guangzhou, People’s Republic of China, 510182

    G. D. Ye

  3. Obstetrics and Gynecology Research Institute of the NO. 2 Municipal People’s Hospital, Guangzhou Medical College, Guangzhou, People’s Republic of China, 510150

    H. Zhou

Authors
  1. G. D. Ye
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. H. Zhou
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. J. W. Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Z. H. Zeng
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Y. L. Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Z. H. Zeng.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ye, G., Zhou, H., Yang, J. et al. Photoinitiating behavior of macrophotoinitiator containing aminoalkylphenone group. J Therm Anal Calorim 85, 771–777 (2006). https://doi.org/10.1007/s10973-005-7271-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-005-7271-x

Keywords

Search

Navigation