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Spectrothermal studies of 1,10-phenanthroline complexes of Co(II), NI(II), Cu(II) and Cd(II) orotates

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Abstract

The 1,10-phenanthroline (phen) complexes of Co(II), Ni(II), Cu(II) and Cd(II) orotates were synthesized and characterized by elemental analysis, magnetic susceptibility, spectral methods (UV-vis and FTIR) and thermal analysis techniques (TG, DTG and DTA). The Co(II), Ni(II), Cu(II) and Cd(II) ions in diaquabis(1,10-phenanthroline)metal(II) diorotate octahedral complexes [M(H2O)2(phen)2](H2Or)2·nH2O (M=Co(II), n=2.25; Ni(II), n=3; Cu(II) and Cd(II), n=2) are coordinated by two aqua ligands and two moles of phen molecules as chelating ligands through their two nitrogen atoms. The monoanionic orotate behaves as a counter ion in the complexes. On the basis of the first DTGmax, the thermal stability of the hydrated complexes follows the order: Cd(II), 68°C 68°C

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Arts and Sciences, Eskişehir, Osmangazi University, Eskişehir, Turkey, 26480

    O. Z. Yeşilel

  2. Department of Chemistry, Faculty of Arts and Sciences, Ondokuz Mayıs University, Kurupelit, Samsun, Turkey, 55139

    H. Ölmez

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  1. O. Z. Yeşilel
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  2. H. Ölmez
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Yeşilel, O.Z., Ölmez, H. Spectrothermal studies of 1,10-phenanthroline complexes of Co(II), NI(II), Cu(II) and Cd(II) orotates. J Therm Anal Calorim 86, 211–216 (2006). https://doi.org/10.1007/s10973-005-7137-2

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