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Thermal properties of multiblock thermoplastic elastomerswith oligoamide soft blocks derived from dimerized fatty acid

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Abstract

Two series of multiblock copolymers, poly(ester-block-amide)s (PEA) and poly(amide-block-amide)s (PAA), with the same type of oligoamide soft block were obtained. Oligoamide soft block was prepared from dimerized fatty acid and 1,6-hexamethylenediamine. Oligo(butylene terephthalate) (PBT) was used as oligoester hard block in the first series and oligolaurolactam (PA12) was oligoamide hard block in the second one. The thermal and mechanical properties of these copolymers have been investigated as functions of temperature and the hard/soft block ratio. DSC and DMTA revealed that the copolymers behaved as thermoplastic elastomers.

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Authors and Affiliations

  1. Szczecin University of Technology, Polymer Institute, Szczecin, , Poland, 70-322 , Pulaskiego 10 St.

    Kozlowska A , Ukielski R  & Piatek M

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  1. Kozlowska A
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  2. Ukielski R
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  3. Piatek M
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Correspondence to Kozlowska A .

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Kozlowska, A., Ukielski, R. & Piatek, M. Thermal properties of multiblock thermoplastic elastomerswith oligoamide soft blocks derived from dimerized fatty acid . J Therm Anal Calorim 83, 349–353 (2006). https://doi.org/10.1007/s10973-005-6948-5

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  • DOI: https://doi.org/10.1007/s10973-005-6948-5

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