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The enthalpies of dilution of pyridine and methylpyridine at 298.15 K

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Abstract

The enthalpies of dilution of aqueous solutions for pyridine and methylpyridine isomers have been determined with a 2277-Thermal Activity Monitor at 298.15 K. The results have been treated using the excess function concept and homotactic interaction coefficients have been obtained. The homotactic enthalpic pairwise interaction coefficients are discussed qualitatively in terms of substitution effects of methyl group introduced into the pyridine ring.

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Authors and Affiliations

  1. Key Lab for Colloid and Interface Chemistry of Shandong University, Ministry of Education, Jinan, PR China, 250100

    Li Y & Guiying X

  2. Department of Chemistry, Zhejiang University, Hangzhou, PR China, 310027

    Ruisen L

  3. Department of Chemistry, Wenzhou Normal College, Wenzhou, PR China, 325000

    Xingen H

Authors
  1. Li Y
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  2. Xingen H
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  3. Ruisen L
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  4. Guiying X
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Correspondence to Li Y.

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Li, Y., Xingen, H., Ruisen, L. et al. The enthalpies of dilution of pyridine and methylpyridine at 298.15 K . J Therm Anal Calorim 83, 269–272 (2006). https://doi.org/10.1007/s10973-005-6829-y

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  • DOI: https://doi.org/10.1007/s10973-005-6829-y

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