Skip to main content
SpringerLink
Log in

Calorimetric and thermal decomposition kinetic study of Tb(Tyr)(Gly)3Cl3·3H2O

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

The solid-state ternary complex of terbium chloride with L-tyrosine and glycine, [Tb(Tyr)(Gly)3Cl3·3H2O], was synthesized and characterized. Using a solution-reaction isoperibol calorimeter, the enthalpy of reaction for the following reaction, TbCl3·6H2O(s)+Tyr(s)+3Gly(s)=Tb(Tyr)(Gly)3Cl3·3H2O(s)+3H2O(l), was determined to be (5.1±0.6) kJ mol-1. The standard enthalpy of formation of Tb(Tyr)(Gly)3Cl3-3H2O at T=298.15 K has been derived as -(4267.3±2.3) kJ mol-1. The thermal decomposition kinetics of the complex was studied by non-isothermal thermogravimetry in the temperature range of 325-675 K. Two main mass loss stages existed in the process of the decomposition of the complex, the kinetic parameters for the second stage were analyzed by means of differential and integral methods, respectively. Comparing the results of differential and integral methods, mechanism functions of the thermal decomposition reaction for its second stage were proposed. The kinetic equation can be expressed as: dα/dt=Aexp(-E/RT)(1-α)2. The average values of the apparent activation energy E and pre-exponential factor A were 213.18 kJ mol-1 and 2.51·1020 s-1, respectively.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. L. J. Anghileri, Arzneim.-Forsch. (Drug Res.), 25 (1975) 793.

    Google Scholar 

  2. J. G. Wu, R. W. Deng, L. F. Wang and M. Yu, J. Lanzhou Univ. (Nat. Sci. Edn.), 20 (1984) 69.

    Google Scholar 

  3. B. P. Liu, Z. C. Tan, Z. D. Nan, P. Liu, L. X. Sun, F. Xu and X. Z. Lan, J. Therm. Anal. Cal., 71 (2003) 623.

    Article  Google Scholar 

  4. J. X. Liu, L. M. Duan and Y. H. Sun, Chem. J. Chin. Univ., 13 (1992) 300.

    Google Scholar 

  5. M. Ji, J. Liu, S. L. Gao, R. Hu and Q. Shi, J. Therm. Anal. Cal., 58 (1999) 331.

    Article  Google Scholar 

  6. T. S. Sun, Y. M. Xiao, D. Q. Wang, F. L. Wang and Y. T. Zhao, J. Therm. Anal. Cal., 53 (1998) 285.

    Article  Google Scholar 

  7. Q. G. Li, S. S. Qu, C. P. Zhou and Y. Liu, Chem. J. Chin. Univ., 21 (2000) 791.

    Google Scholar 

  8. W. S. Chen, Y. Liu, C. P. Zhou and S. S. Qu, J. Therm. Anal. Cal., 66 (2001) 463.

    Article  Google Scholar 

  9. W. S. Chen, Y. Liu, C. P. Zhou, Q. G. Li and S. S. Qu, J. Therm. Anal. Cal., 73 (2003) 285.

    Article  Google Scholar 

  10. H. G. Yu, Y. Liu, Z. C. Tan, J. X. Dong, T. J. Zou, X. M. Huang and S. S. Qu, Thermochim. Acta, 401 (2003) 217.

    Article  Google Scholar 

  11. R. Rychly and V. Pekarek, J. Chem. Thermodyn., 9 (1977) 391.

    Article  Google Scholar 

  12. R. L. Montgomery, R. A. Melau, C. C. Lau, G. H. Meier, H. H. Chan and F. D. Rossini, J. Chem. Thermodyn., 9 (1977) 915.

    Google Scholar 

  13. R. C. Weast, CRC Handbook of Chemistry and Physics, 69th Ed., CRC Press, Florida 1988-1989.

    Google Scholar 

  14. J. B. Pedley, R. D. Muylor and S. P. Kirby, Thermochemical Data of Organic Compounds, 2nd Ed.; Chapman and Hall, London 1992.

    Google Scholar 

  15. F. Rodante, Thermochim. Acta, 200 (1992) 47.

    Article  Google Scholar 

  16. F. Rodante and G. Marrosu, Thermochim. Acta, 171 (1990) 15.

    Article  Google Scholar 

  17. F. Rodante, G. Marrosu and G. Catalani, Thermochim. Acta, 194 (1992) 197.

    Article  Google Scholar 

  18. K. Biemann, J. Seibl and F. Gapp, J. Am. Chem. Soc., 83 (1961) 3795.

    Google Scholar 

  19. B. N. Achar, G. W. Brindley and J. H. Sharp, Proc. Int. Clay Conf. Jerusalem, 1 (1966) 67.

    Google Scholar 

  20. J. H. Sharp and S. A. Wendworth, Anal. Chem., 41 (1969) 2060.

    Google Scholar 

  21. A. W. Coats and J. P. Redfern, Nature, 201 (1964) 68.

    Google Scholar 

  22. Y. Z. Li, Thermal Analysis, Tsinghua University Press, Beijing 1987, pp. 94-96.

    Google Scholar 

  23. R. Z. Hu and Q. Z. Shi, Thermal Analysis Kinetics, Science Press, Beijing 2001.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Wuhan University Wuhan, 430072, P. R. China

    Z. H. Zhang, H. R. Li, Y. Liu & S. S. Qu

  2. Department of Chemistry, Xiaogan University Xiaogan, 432100, P. R. China

    Z. J. Ku

Authors
  1. Z. H. Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Z. J. Ku
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. H. R. Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Y. Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. S. S. Qu
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zhang, Z.H., Ku, Z.J., Li, H.R. et al. Calorimetric and thermal decomposition kinetic study of Tb(Tyr)(Gly)3Cl3·3H2O. J Therm Anal Calorim 79, 169–173 (2005). https://doi.org/10.1007/s10973-004-0580-7

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-004-0580-7

Search

Navigation