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Comparative thermodynamic investigation of binary Ga-Bi system; Experimental determination of enthalpies of mixing and activity estimation for liquid Ga-Bi alloys

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Abstract

The results of experimental and analytical thermodynamic investigation of binary Ga-Bi system are presented in this paper. Integral molar enthalpies of mixing for liquid Ga-Bi alloys were obtained using quantitative differential thermal analysis. Activities of bismuth in the entire composition range and temperature interval 573-1073 K, were calculated by Zhang-Chou’s method for binary systems having two liquid or solid coexisting phases in combination with other Chou’s method developed for simple eutectic systems. Activities of gallium were derived from Gibbs-Duhem equation. Comparison between experimental, calculated values and existing literature data shows good agreement.

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Authors and Affiliations

  1. University of Belgrade, Technical Faculty, VJ 12, 19210, Bor, Serbia and Montenegro

    D. Živković, D. Manasijević & Ž. Živkoviş

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  1. D. Živković
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  2. D. Manasijević
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  3. Ž. Živkoviş
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Correspondence to D. Živković.

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Živković, D., Manasijević, D. & Živkoviş, Ž. Comparative thermodynamic investigation of binary Ga-Bi system; Experimental determination of enthalpies of mixing and activity estimation for liquid Ga-Bi alloys. J Therm Anal Calorim 79, 71–77 (2005). https://doi.org/10.1007/s10973-004-0564-7

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  • DOI: https://doi.org/10.1007/s10973-004-0564-7

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