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Magnetocaloric and induction heating characteristics of La0.71Sr0.29Mn0.95Fe0.05O3 nanoparticles

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Abstract

In this study, we synthesized nanosized ferromagnetic La0.71Sr0.29Mn0.95Fe0.05O3 (LSMFO) manganites using a modified sol-gel method, followed by annealing at 750 °C. We investigated their magnetic properties, with a specific focus on magnetocaloric properties, as well as their potential application in hyperthermia treatments. Notably, the sample exhibited a second-order magnetic transition, demonstrating significant magnetocaloric properties and a distinct table-like feature over a temperature range of ∼30 K. This behavior was characterized by remarkable relative cooling power (RCP) and refrigerant capacity (RC). To assess the magnetic heating characteristics, we measured the response of the samples in alternating magnetic fields of 30 mT at various frequencies. Additionally, we evaluated the sample’s potential for hyperthermia by determining the Specific Absorption Rate (SAR) and Intrinsic Loss Power (ILP) parameters across different frequencies. The results highlighted the sample’s effective heat generation capabilities at various frequencies. These findings support the suitability and applicability of the synthesized nanosized LSMFO manganites for both magnetic refrigeration and hyperthermia applications.

Graphical Abstract

Highlights

  • Nanosized of La0.71Sr0.29Mn0.95Fe0.05O3 (LSMFO) manganites synthesized via modified sol-gel method.

  • LSMFO shows promising magnetocaloric properties (table-like response, high RCP & RC) for magnetic refrigeration.

  • Effective heat generation in LSMFO suggests potential for hyperthermia applications (supported by SAR & ILP).

  • LSMFO nanoparticles hold promise for both magnetic refrigeration and hyperthermia.

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Data availability

The data that support the findings of this study are available from the corresponding author on request.

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Acknowledgements

This study is supported by the Tunisian Ministry of Higher Education and Scientific Research and the Neel Institute.

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Authors and Affiliations

  1. LT2S Lab, Digital Research Centre of Sfax, Sfax Technopark, BP 275, 3021, Sakiet-Ezzit, Tunisia

    N. Rmili & W. Cheikhrouhou-Koubaa

  2. Functional Materials, Institute of Materials Science, Technical University of Darmstadt, Alarich-Weiss-Straße 16, 64287, Darmstadt, Germany

    K. Riahi

  3. Unité de Recherche Matériaux Avancés et Nanotechnologies (URMAN), Institut Supérieur des Sciences Appliquées et de Technologie de Kasserine, Kairouan University, BP 471, Kasserine, 1200, Tunisia

    R. M’nassri

  4. Photovoltaic Laboratory Research and Technology Center of Energy, Borj-Cedria Science and Technology Park, BP 95, 2050, Hammam-Lif, Tunisia

    B. Ouertani

  5. Institut NEEL, B.P.166, 38042, Grenoble Cedex 09, France

    E. K. Hlil

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NR, KR, BO, and RM: sample preparation, formal analysis, data curation, writing- original draft preparation. RM, WC-K, and EKH: supervision, conceptualization, methodology, formal analysis, writing - original draft, software, validation, writing- review & editing.

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Rmili, N., Riahi, K., M’nassri, R. et al. Magnetocaloric and induction heating characteristics of La0.71Sr0.29Mn0.95Fe0.05O3 nanoparticles. J Sol-Gel Sci Technol (2024). https://doi.org/10.1007/s10971-024-06361-5

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