Skip to main content
Log in

Twenty years of aerogel research at an undergraduate institution

Journal of Sol-Gel Science and Technology Aims and scope Submit manuscript

Cite this article

Abstract

This paper celebrating the 30th Anniversary of the Journal of Sol-Gel Science and Technology, presents a retrospective of twenty years of aerogel research at Union College, a baccalaureate-granting institution. Development of a rapid supercritical extraction method for aerogel fabrication and subsequent contributions to the sol-gel literature in the areas of aerogel windows for sustainable buildings, hydrophobic aerogels for a variety of applications including drag reduction, and catalytic aerogels for automotive pollution mitigation are highlighted. Engaging in multidisciplinary research on remarkable materials that can contribute to addressing global challenges is inherently motivating for students early in their academic careers as well as for faculty members. Opportunities and challenges associated with establishing and maintaining a productive academic research program when most students are available to participate only in shorter-term projects are discussed.

Graphical Abstract

Photograph of Union College Aerogel Team: faculty (bottom row) and students, February 2020.

Highlights

  • A retrospective of 20 years of research in aerogel materials is presented.

  • An overview of the Union College rapid supercritical extraction method is provided.

  • Contributions in the areas of aerogel windows, hydrophobic materials and catalysis are described.

  • Opportunities and challenges of research at an undergraduate institution are emphasized.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

References

  1. US Bureau of Labor Statistics. Accessed 6 November 2022. https://www.blsgov/opub/ted/2022/61-8-percent-of-recent-high-school-graduates-enrolled-in-college-in-october-2021htm

  2. Carnegie Commission on Higher Education. Accessed 6 November 2022. https://carnegieclassifications.acenet.edu/classification_descriptions/basic.php

  3. NASA/JPL, Public domain, via Wikimedia Commons, Accessed 12 November 2022.

  4. Leventis N, Elder IA, Rolison DR, Anderson ML, Merzbacher CI (1999) Durable modification of silica aerogel monoliths with fluorescent 2,7-diazapyrenium moieties Sensing oxygen near the speed of open-air diffusion. Chem Mater 11 10:2837–2845

    Article  Google Scholar 

  5. Poco JF, Coronado PR, Pekala RW, Hrubesh LW (1996) A rapid supercritical extraction process for the production of silica aerogels. MRS Online Proceedings Library (OPL), 431

  6. Gross J, Coronado PR, Hrubesh LW (1998) Elastic properties of silica aerogels from a new rapid supercritical extraction process. J Non-crystalline Solids 225:282–286

    Article  CAS  Google Scholar 

  7. Scherer GW, Gross J, Hrubesh LW, Coronado PR (2002) Optimization of the rapid supercritical extraction process for aerogels. J Non-crystalline solids 311(3):259–272

    Article  CAS  Google Scholar 

  8. Gauthier BM, Bakrania SD, Anderson AM, Carroll MK (2004) A fast supercritical extraction technique for aerogel fabrication. J Non-crystalline Solids 350:238–243

    Article  CAS  Google Scholar 

  9. Gauthier BM, Anderson AM, Bakrania S, Mahony MK, Bucinell RB (2008) US Patent No 7, 384, 988 Washington, DC, US Patent and Trademark Office

  10. Gauthier BM, Anderson AM, Bakrania S, Mahony MK, Bucinell RB (2011) US Patent No 8, 080, 591 Washington, DC, US Patent and Trademark Office

  11. Carroll MK, Anderson AM, Gorka CA (2014) Preparing silica aerogel monoliths via a rapid supercritical extraction method. JoVE (J Vis Exp) 84:e51421

    Google Scholar 

  12. Anderson AM, Wattley CW, Carroll MK (2009) Silica aerogels prepared via rapid supercritical extraction: effect of process variables on aerogel properties. J Non-Crystalline Solids 355(2):101–108

    Article  CAS  Google Scholar 

  13. Anderson AM, Bakrania SD, Konecny J, Gauthier BM, Carroll MK (2004) Detecting sol–gel transition using light transmission. J non-crystalline solids 350:259–265

    Article  CAS  Google Scholar 

  14. Roth TB, Anderson AM, Carroll MK (2008) Analysis of a rapid supercritical extraction aerogel fabrication process: Prediction of thermodynamic conditions during processing. J Non-crystalline Solids 354(31):3685–3693

    Article  CAS  Google Scholar 

  15. Plata DL, Briones YJ, Wolfe RL, Carroll MK, Bakrania SD, Mandel SG, Anderson AM (2004) Aerogel-platform optical sensors for oxygen gas. J Non-crystalline Solids 350:326–335

    Article  CAS  Google Scholar 

  16. Anderson AM, Donlon EA, Forti AA, Silva VP, Bruno BA, Carroll MK (2017) Synthesis and characterization of copper-nanoparticle-containing silica aerogel prepared via rapid supercritical extraction for applications in three-way catalysis. MRS Adv 2(57):3485–3490

    Article  CAS  Google Scholar 

  17. Anderson AM, Bruno BA, Santos J, Barry PJ, Carroll MK (2022). PGM nanoparticle-based alumina aerogels for three-way catalyst applications. Catal Commun, 106547

  18. Rubin M, Lampert CM (1983) Transparent silica aerogels for window insulation. Solar Energy. Materials 7(4):393–400

    CAS  Google Scholar 

  19. Jensen KI, Schultz JM, Kristiansen FH (2004) Development of windows based on highly insulating aerogel glazings. J Non-Crystalline Solids 350:351–357

    Article  CAS  Google Scholar 

  20. Schultz JM, Jensen KI (2008) Evacuated aerogel glazings. Vacuum 82(7):723–729

    Article  CAS  Google Scholar 

  21. Buratti C, Moretti E (2012) Experimental performance evaluation of aerogel glazing systems. Appl Energy 97:430–437

    Article  CAS  Google Scholar 

  22. Buratti C, Moretti E (2012) Glazing systems with silica aerogel for energy savings in buildings. Appl Energy 98:396–403

    Article  CAS  Google Scholar 

  23. Cotana F, Pisello AL, Moretti E, Buratti C (2014) Multipurpose characterization of glazing systems with silica aerogel:in-field experimental analysis of thermal-energy, lighting and acoustic performance. Build Environ 81:92–102

    Article  Google Scholar 

  24. Gao T, Jelle BP, Ihara T, Gustavsen A (2014) Insulating glazing units with silica aerogel granules: the impact of particle size. Appl Energy 128:27–34

    Article  CAS  Google Scholar 

  25. Berardi U (2015) The development of a monolithic aerogel glazed window for an energy retrofitting project. Appl Energy 154:603–615

    Article  Google Scholar 

  26. Ihara T, Gao T, Grynning S, Jelle BJ, Gustavsen A (2015) Aerogel granulate glazing facades and their application potential from an energy saving perspective. Appl Energy 142:179–191

    Article  Google Scholar 

  27. Bhuiya MMH, Anderson AM, Carroll MK, Bruno BA, Ventrella JL, Silberman B, Keramati B (2016) Preparation of monolithic silica aerogel for fenestration applications: scaling up, reducing cycle time, and improving performance. Ind Eng Chem Res 55(25):6971–6981

    Article  CAS  Google Scholar 

  28. Estok SK, Hughes TA, Carroll MK, Anderson AM (2014) Fabrication and characterization of TEOS-based silica aerogels prepared using rapid supercritical extraction. J Sol-gel Sci Technol 70(3):371–377

    Article  CAS  Google Scholar 

  29. Carroll MK, Anderson AM, Mangu ST, Hajjaj Z, Capron M (2022) Aesthetic aerogel window design for sustainable buildings. Sustainability 14(5):2887

    Article  CAS  Google Scholar 

  30. Merli F, Anderson AM, Carroll MK, Buratti C (2018) Acoustic measurements on monolithic aerogel samples and application of the selected solutions to standard window systems. Appl Acoust 142:123–131

    Article  Google Scholar 

  31. Zinzi M, Rossi G, Anderson AM, Carroll MK, Moretti E, Buratti C (2019) Optical and visual experimental characterization of a glazing system with monolithic silica aerogel. Sol Energy 183:30–39

    Article  CAS  Google Scholar 

  32. Fiorini CV, Merli F, Belloni E, Anderson AM, Carroll MK, Buratti C (2023) Optical and color rendering long-term performance of monolithic aerogel after laboratory accelerated aging: development of a method and preliminary experimental results. Solar Energy, in press

  33. SunThru LLC. Accessed 13 November 2022. https://www.sunthru.biz/

  34. Carroll MK, & Anderson AM. (2011) Aerogels as platforms for chemical sensors. In Aerogels Handbook Springer, New York, NY.

  35. Michaloudis I, Carroll MK, Kupiec S, Cook K, Anderson AM (2018) Facile method for surface etching of silica aerogel monoliths. J Sol-Gel Sci Technol 87(1):22–26

    Article  Google Scholar 

  36. Stanec AM, Hajjaj Z, Carroll MK, Anderson AM (2021) Aesthetically enhanced silica aerogel via incorporation of laser etching and dyes. JoVE (J Visualized Exp) 169:e61986

    Google Scholar 

  37. Anderson AM, Carroll MK (2011) Hydrophobic silica aerogels: review of synthesis, properties and applications. Aerogels Handbook. Springer, New York, NY, p 47–77

    Chapter  Google Scholar 

  38. Anderson AM, Carroll MK, Green EC, Melville JT, Bono MS (2010) Hydrophobic silica aerogels prepared via rapid supercritical extraction. J Sol-gel Sci Technol 53(2):199–207

    Article  CAS  Google Scholar 

  39. Rodriguez JE, Anderson AM, Carroll MK (2014) Hydrophobicity and drag reduction properties of surfaces coated with silica aerogels and xerogels. J Sol-gel Sci Technol 71(3):490–500

    Article  CAS  Google Scholar 

  40. Karatum O, Bhuiya MMH, Carroll MK, Anderson AM, Plata DL (2018) Life cycle assessment of aerogel manufacture on small and large scales: weighing the use of advanced materials in oil spill remediation. J Ind Ecol 22(6):1365–1377

    Article  CAS  Google Scholar 

  41. Aerogel Particles. Accessed 10 November 2022. https://www.cabotcorpcom/solutions/products-plus/aerogel/particles

  42. Bono MS, Anderson AM, Carroll MK (2010) Alumina aerogels prepared via rapid supercritical extraction. J Sol-gel Sci Technol 53(2):216–226

    Article  CAS  Google Scholar 

  43. Brown LB, Anderson AM, Carroll MK (2012) Fabrication of titania and titania–silica aerogels using rapid supercritical extraction. J Sol-gel Sci Technol 62(3):404–413

    Article  CAS  Google Scholar 

  44. Armor JN, Carlson EJ (1987) Variables in the synthesis of unusually high pore volume aluminas. J Mater Sci 22(7):2549–2556

    Article  CAS  Google Scholar 

  45. Baumann TF, Gash AE, Chinn SC, Sawvel AM, Maxwell RS, Satcher Jr JH (2005) ChemMater 17:395–401

    CAS  Google Scholar 

  46. Juhl SJ, Dunn NJ, Carroll MK, Anderson AM, Bruno BA, Madero JE, Bono Jr MS (2015) Epoxide-assisted alumina aerogels by rapid supercritical extraction. J Non-Crystalline Solids 426:141–149

    Article  CAS  Google Scholar 

  47. Dunn NJ, Carroll MK, Anderson AM (2011) Characterization of alumina and nickel-alumina aerogels prepared via rapid supercritical extraction. Polym Prepr 52(1):250–251

    Google Scholar 

  48. Bruno, BA, Anderson, AM, Carroll, M, Swanton, T, Brockmann, P, Palace, T, & Ramphal, IA. (2016) Benchtop scale testing of aerogel catalysts: preliminary results. (No. 2016-01-0920) SAE Technical Paper.

  49. Anderson AM, Bruno BA, Donlon EA, Posada LF, Carroll MK (2018) Fabrication and testing of catalytic aerogels prepared via rapid supercritical extraction. JoVE (J Vis Exp) 138:e57075

    Google Scholar 

  50. Tobin ZM, Posada LF, Bechu AM, Carroll MK, Bouck RM, Anderson AM, Bruno BA (2017) Preparation and characterization of copper-containing alumina and silica aerogels for catalytic applications. J Sol-Gel Sci Technol 84(3):432–445

    Article  CAS  Google Scholar 

  51. Bouck RM, Anderson AM, Prasad C, Hagerman ME, Carroll MK (2016) Cobalt-alumina sol-gels: Effects of heat treatment on structure and catalytic ability. J Non-Crystalline Solids 453:94–102

    Article  CAS  Google Scholar 

  52. Posada LF, Carroll MK, Anderson AM, Bruno BA (2019) Inclusion of ceria in alumina-and silica-based aerogels for catalytic applications. J Supercrit Fluids 152:104536

    Article  CAS  Google Scholar 

  53. Smith LC, Anderson AM, Carroll MK (2016) Preparation of vanadia-containing aerogels by rapid supercritical extraction for applications in catalysis. J Sol-Gel Sci Technol 77(1):160–171

    Article  CAS  Google Scholar 

  54. Dunn, NJ, Brown, LB, Juhl, SJ, Anderson, AM, Bruno, BA, & Mahony, MK (2016) Catalyst, catalytic converter, and method for the production thereof. US Patent No. 9,358,534 Washington, DC US Patent and Trademark Office

  55. Anderson AM, Bruno BA, Dilone F, LaRosa MT, Andre TF, Avanessian C, Carroll MK (2020) Effect of copper loading in copper-alumina aerogels on three-way catalytic performance. Emiss Control Sci Technol 6(3):324–335

    Article  CAS  Google Scholar 

  56. Anderson AM, Bruno BA, Santos J, Avanessian C, Carroll MK (2022) Effect of slurry processing on the properties of catalytically active copper-alumina aerogel material for applications in three-way catalysis. J Sol-Gel Sci Technol 102(2):422–436

    Article  CAS  Google Scholar 

  57. Burpo FJ, Nagelli EA, Morris LA, McClure JP, Ryu MY, Palmer JL (2017) Direct solution-based reduction synthesis of Au, Pd, and Pt aerogels. J Mater Res 32(22):4153–4165

    Article  CAS  Google Scholar 

  58. Mitropoulos AN, Burpo FJ, Nguyen CK, Nagelli EA, Ryu MY, Wang J, Wickiser JK (2019) Noble metal composite porous silk fibroin aerogel fibers. Materials 12(6):894

    Article  CAS  Google Scholar 

  59. Burpo FJ, Mitropoulos AN, Nagelli EA, Palmer JL, Morris LA, Ryu MY, Wickiser JK (2018) Cellulose nanofiber biotemplated palladium composite aerogels. Molecules 23(6):1405

    Article  Google Scholar 

  60. Burpo FJ, Mitropoulos AN, Nagelli EA, Ryu MY, Palmer JL (2018) Gelatin biotemplated platinum aerogels. MRS Adv 3 47:2875–2880

    Article  Google Scholar 

  61. Harper-Leatherman AS, Iftikhar M, Ndoi A, Scappaticci SJ, Lisi GP, Buzard KL, Garvey EM (2012) Simplified procedure for encapsulating cytochrome c in silica aerogel nanoarchitectures while retaining gas-phase bioactivity. Langmuir 28(41):14756–14765

    Article  CAS  Google Scholar 

  62. Harper-Leatherman AS, Wallace JM, Rolison DR (2017) Cytochrome c Stabilization and Immobilization in Aerogels. In Enzyme Stabilization and Immobilization pp149–163. Humana Press, New York, NY

    Google Scholar 

  63. 100 Inspiring Women in STEM Awards. Accessed 13 November 2022. https://www.insightintodiversity.com/100-inspiring-women-in-stem-awards/

Download references

Acknowledgements

The Union College Aerogel Lab has received external funding from the US National Science Foundation (Grant nos. CTS-0216153, CHE-0514527, CMMI-0722842, CHE-0847901, DMR-1206631, CBET-1228851, IIP-1332456, DMR-1828144, and IIP-1918217) and the ACS Petroleum Research Fund (Grant No. 39796-B10), as well as subawards from grants to SunThru LLC from the NSF (Grant nos. IIP-1415359 and IIP-2025800) and the New York State Energy Research & Development Authority (Grant No. NYSERDA-87381). We are grateful for the contributions of our students, postbaccalaureate researchers, and colleagues to the work reviewed herein. We acknowledge support of that work from Union College through the Faculty Research Fund, Student Research Grants, Student Summer Research Fellowships, and the Chemistry Department’s Kane Fund.

Author Contributions

Both authors contributed to writing and editing the manuscript. Both authors read and approved the final manuscript.

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Mary K. Carroll or Ann M. Anderson.

Ethics declarations

Conflict of interest

The authors declare no competing interests.

Additional information

Publisher’s note Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and Permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Carroll, M.K., Anderson, A.M. Twenty years of aerogel research at an undergraduate institution. J Sol-Gel Sci Technol (2023). https://doi.org/10.1007/s10971-022-06034-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s10971-022-06034-1

Keywords

Navigation