MoS2 microspheres/MOF-derived In2S3 heterostructures were fabricated through a two-step temperature-raising hydrothermal method. MOF-derived In2S3 porous structures were synthesized via a sulfidation process of MIL-68(In) precursor, and then MoS2 microspheres further in situ grew on the surface of In2S3 porous structures at the increased temperature. The as-obtained samples were characterized by XRD, SEM, XPS, UV-Vis DRS, and PL. Compared with pure In2S3, MoS2/In2S3 heterostructures exhibited a higher photocatalytic activity towards methyl orange degradation under visible light irradiation, which should be attributed to the stronger visible light absorption as well as the effective separation of photo-generated electrons and holes.
MIL-68(In) is used as the morphological template and the indium precursor.
One-pot synthesis involving a two-step temperature-raising hydrothermal process.
Strong visible light absorption and effective separation of photo-generated carries.
MoS2/In2S3 heterostructures exhibit excellent visible-light photocatalytic activity.
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Vasei HV, Masoudpanah SM, Adeli M, Aboutalebi MR (2019) Facile synthesis of ZnO nanosheets as ultraviolet photocatalyst. J Sol-Gel Sci Technol 89(2):594–601
Li MH, Liu YB, Dong LM, Shen CS, Li F, Huang MH, Ma CY, Yang B, An XQ, Sand W (2019) Recent advances on photocatalytic fuel cell for environmental applications-The marriage of photocatalysis and fuel cells. Sci Total Environ 668:966–978
Saini A, Sharma JL, Sharma RK, Chaudhary A, Sharma D, Dhayal V (2019) Zinc oxide derived from zinc(II)/acetoxime system: formation pathway and solar-driven photocatalytic and antimicrobial applications. J Sol-Gel Sci Technol 91(3):644–653
Lu XY, Che WJ, Hu XF, Wang Y, Zhang AT, Deng F, Luo SL, Dionysiou DD (2019) The facile fabrication of novel visible-light-driven Z-scheme CuInS2/Bi2WO6 heterojunction with intimate interface contact by in situ hydrothermal growth strategy for extraordinary photocatalytic performance. Chem Eng J 356:819–829
Shafei A, Salarpour ME, Sheibani S (2019) Effect of intermediate ball milling on the synthesis of Cu-doped TiO2 nano-photocatalyst by sol-gel method. J Sol-Gel Sci Technol 92(1):173–185
Li H, Yuan ZH, Li W, Chen MF, Snyders R, Li WJ, Bittencourt C (2019) Novel synthesis of porous beta-In2S3 ultrathin nanosheets with large lateral size. Mater Lett 252:15–18
Zeng TY, Wang LW, Feng L, Xu HL, Cheng QR, Pan ZQ (2019) Two novel organic phosphorous-based MOFs: synthesis, characterization and photocatalytic properties. Dalton Trans 48(2):523–534
Liu N, Jing CW, Li ZM, Huang WY, Gao B, You F, Zhang XD (2019) Effect of synthesis conditions on the photocatalytic degradation of Rhodamine B of MIL-53(Fe). Mater Lett 237:92–95
Xiao JD, Jiang HL (2019) Metal-organic frameworks for photocatalysis and photothermal catalysis. Acc Chem Res 52(2):356–366
Zhang Y, Zhou JB, Chen X, Feng QQ, Cai WQ (2019) MOF-derived C-doped ZnO composites for enhanced photocatalytic performance under visible light. J Alloy Compd 777:109–118
Yang MF, Zhang C, Fan YH, Lin TJ, Chen XQ, Lu YW, Wang H, Zhong LS, Sun YH (2018) ZIF-67-derived Co3O4 micro/nano composite structures for efficient photocatalytic degradation. Mater Lett 222:92–95
Liang RW, Shen LJ, Jing FF, Wu WM, Qin N, Lin R, Wu L (2015) NH2-mediated indium metal-organic framework as a novel visible-light-driven photocatalyst for reduction of the aqueous Cr(VI). Appl Catal B-Environ 162:245–251
Liu YS, Liu XP, Wang YB, Wang R, Zhang T (2019) Metal-organic-framework-derived In2O3 microcolumnar structures embedded with Pt nanoparticles for NO2 detection near room temperature. Ceram Int 45(8):9820–9828
Feng YX, Yan T, Wu TT, Zhang N, Yang QQ, Sun M, Yan LG, Du B, Wei Q (2019) A label-free photoelectrochemical aptasensing platform base on plasmon Au coupling with MOF-derived In2O3@g-C3N4 nanoarchitectures for tetracycline detection. Sensor Actuat B-Chem 298:126817
Adhikari S, Mandal S, Kim DH (2019) Z-scheme 2D/1D MoS2 nanosheet-decorated Ag2Mo2O7 microrods for efficient catalytic oxidation of levofloxacin. Chem Eng J 373:31–43
Selvaraj R, Kalimuthu KR, Kalimuthu V (2019) A type-II MoS2/ZnO heterostructure with enhanced photocatalytic activity. Mater Lett 243:183–186
Fang Y, Zhu SR, Wu MK, Zhao WN, Han L (2018) MOF-derived In2S3 nanorods for photocatalytic removal of dye and antibiotics. J Solid State Chem 266:205–209
Han L, Zhang X, Wu D (2019) Construction and characterization of BiOI/NH2-MIL-125(Ti) heterostructures with excellent visible-light photocatalytic activity. J Mater Sci Mater El 30:3773–3781
Pi YH, Jin S, Li XY, Tu S, Li Z, Xiao J (2019) Encapsulated MWCNT@MOF-derived In2S3 tubular heterostructures for boosted visible-light-driven degradation of tetracycline. Appl Catal B-Environ 256:117882
Zhang XL, Zhang N, Gan CX, Liu YF, Chen L, Zhang C, Fang YZ (2019) Synthesis of In2S3/UiO-66 hybrid with enhanced photocatalytic activity towards methyl orange and tetracycline hydrochloride degradation under visible-light irradiation. Mater Sci Semicond Process 91:212–221
Sun BL, Shan F, Jiang XX, Ji J, Wang F (2018) One-pot synthesis of MoS2/In2S3 ultrathin nanoflakes with mesh-shaped structure on indium tin oxide as photocathode for enhanced photo-and electrochemical hydrogen evolution reaction. Appl Surf Sci 435:822–831
Wang H, Yuan XZ, Wu Y, Zeng GM, Dong HR, Chen XH, Leng LJ, Wu ZB, Peng LJ (2016) In situ synthesis of In2S3@MIL-125(Ti) core-shell microparticle for the removal of tetracycline from wastewater by integrated adsorption and visible-light-driven photocatalysis. Appl Catal B-Environ 186:19–29
Wu DY, Han L (2019) Solvothermal synthesis and characterization of visible-light-active MoO3/MoS2 heterostructure. J Sol-Gel Sci Technol 91(3):441–445
Liu FY, Jiang Y, Yang J, Hao MM, Tong ZF, Jiang LX, Wu ZZ (2016) MoS2 nanodot decorated In2S3 nanoplates: a novel heterojunction with enhanced photoelectrochemical performance. Chem Commun 52(9):1867–1870
He TT, Wu DY, Tan YB (2016) Fabrication of BiOI/BiVO4 heterojunction with efficient visible-light-induced photocatalytic activity. Mater Lett 165:227–230
Wu D, Long M (2011) Realizing visible-light-induced self-cleaning property of cotton through coating N-TiO2 film and loading AgI particles. ACS Appl Mat Interfaces 3(12):4770–4774
Moongraksathum B, Chen YW (2017) CeO2-TiO2 mixed oxide thin films with enhanced photocatalytic degradation of organic pollutants. J Sol-Gel Sci Technol 82(3):772–782
Yuan XZ, Jiang LB, Liang J, Pan Y, Zhang J, Wang H, Leng LJ, Wu ZB, Guan RP, Zeng GM (2019) In-situ synthesis of 3D microsphere-like In2S3/InVO4 heterojunction with efficient photocatalytic activity for tetracycline degradation under visible light irradiation. Chem Eng J 356:371–381
Wang D, Zhang J, Luo Q, Li X, Duan Y, An J (2009) Characterization and photocatalytic activity of poly(3-hexylthiophene)-modified TiO2 for degradation of methyl orange under visible light. J Hazard Mater 169(1):546–550
Zhan C, Chen F, Yang J, Dai D, Cao X, Zhong M (2014) Visible light responsive sulfated rare earth doped TiO2@fumed SiO2 composites with mesoporosity: Enhanced photocatalytic activity for methyl orange degradation. J Hazard Mater 267:88–97
This work was supported by the National Natural Science Foundation of China (21767009). WDY also gratefully acknowledges the support from China Scholarship Council.
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Wu, D., Wu, C. MoS2 microspheres/MOF-derived In2S3 heterostructures with enhanced visible-light photocatalytic activity. J Sol-Gel Sci Technol 94, 251–256 (2020). https://doi.org/10.1007/s10971-020-05232-z
- Metal-organic frameworks
- Visible light