Abstract
The present investigation had made to synthesis of silica nanoparticle (SiNp) from Bambusa vulgaris leaves (BVL) ash by using sol-gel technique and it was utilized for the removal of Cadmium (Cd) and Congo red (CR) in aqueous solutions. Further, the synthesized adsorbent was characterized using instrumental techniques such as XRD, FTIR, FESEM–EDS mapping, TEM, BET, and Zeta potential. In addition, the batch mode technique (such as pH, adsorbent dose, and contact time) was carried out for optimization of Cd and CR removal. The adsorption behavior and capacity was calculated using different isotherms and kinetics. The obtained results of Cd and CR removal were optimized with following parameters such as pH 7, adsorbent dose (100 mg), and equilibrium time (30 min). Also, the adsorbent behavior was found suitable in Langmuir and Freundlich isotherm model and its maximum adsorbent capacity was 133 and 172 mg/g. The kinetic data were better fitted into the pseudo-second order model. The results concluded that the synthesized SiNp was the best adsorbent for the removal of metals, dyes and also economically sound techniques for disposal of agricultural waste.
Highlights
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Silica nanoparticles were synthesized from Bambusa vulgaris leaves by sol-gel method.
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Silica nanoparticles were characterized using XRD, FTIR, FESEM–EDS mapping, TEM, BET, and Zeta potential.
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Cadmium and Congo red were removed using synthesized silica nanoparticles in batch mode.
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Maximum adsorption capacity (Qo) of Cd and Congo red were 133, 172 mg/g, respectively.
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Acknowledgements
K. Durairaj is thankful to Council of Scientific and Industrial Research, New Delhi, for providing him financial assistance (Award No: 09/810/0025/2018 EMR-I) in the form of Senior Research Fellowship (SRF) and all the authors gratefully acknowledge Prof. N. Radhakrishnan, Department of Library and Information science, Periyar University for making language correction of the manuscript.
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Durairaj, K., Senthilkumar, P., Velmurugan, P. et al. Sol-gel mediated synthesis of silica nanoparticle from Bambusa vulgaris leaves and its environmental applications: kinetics and isotherms studies. J Sol-Gel Sci Technol 90, 653–664 (2019). https://doi.org/10.1007/s10971-019-04922-7
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DOI: https://doi.org/10.1007/s10971-019-04922-7