Abstract
In this work, we demonstrated the anti-icing properties of a transparent and superhydrophobic coating surface based on the octadecyltrichlorosilane-modified silica nanoparticles. The surface was prepared via a simple condensation polymerization followed by a spray-coating process. The surface exhibited a high contact angle of 157.5° and a low sliding angle of 6.5° at ambient temperature. The icing behavior of the surface was investigated by successively dropping the 0 °C of water droplets onto the superhydrophobic coating surface at various low temperatures, i.e., –5, –10 and –15 °C with the help of wind action. The surface displayed excellent anti-icing properties at –5 and –10 °C. Water droplets bounced off or slid away the surface before freezing under wind action at the above temperatures. The icing delay time is larger than 2500 s at –10 °C and 5 m/s of wind blow. While at even lower temperature of –15 °C, water froze on the surface quickly. The icing and/or anti-icing mechanisms of the superhydrophobic surface at different temperatures were interpreted by the variation of the surface wettabilities with decreasing temperatures. Specifically, the humidity in air condensed and consequently formed a layer of frost covering the superhydrophobic surface, which has significant influence on the moving abilities of the surface water droplets. As a result, the anti-icing properties of the coating surface changed with the decreasing of temperatures.
Graphical Abstract
Similar content being viewed by others
References
Bhushan B, Jung YC (2011) Prog Mater Sci 56:1–108
Ganesh VA, Raut HK, Nair AS, Ramakrishna SJ (2011) Mater Chem 21:16304–16322
Sun TL, Qing GY, Su BL, Jiang L (2011) Chem Soc Rev 40:2909–2921
Neinhuis C, Koch K, Barthlott W (2011) Planta 213:427–434
Wang YY, Xue J, Wang QJ, Chen QM, Ding JF (2013) ACS Appl Mater Interfaces 5:3370–3381
Wen XF, Wang K, Pi PH, Yang JX, Cai ZQ, Zhang LJ, Qian Y, Yang ZR, Zheng DF, Cheng J (2011) Appl Surf Sci 258:991–998
Davis A, Yeong YH, Steele A, Bayer IS, Loth E (2014) ACS Appl Mater Interfaces 6:9272–9279
Bahadur V, Mishchenko L, Hatton B, Taylor JA, Aizenberg J, Krupenkin T (2011) Langmuir 27:14143–14150
Jin CF, Yan RS, Huang JG (2011) J Mater Chem 21:17519–17525
Jin CF, Jiang YF, Niu T, Huang JG (2012) J Mater Chem 22:12562–12576
Li SJ, Wei YQ, Huang JG (2010) Chem Lett 39:20–21
Mishchenko L, Hatton B, Bahadur V, Taylor JA, Krupenkin T, Aizenberg J (2010) ACS Nano 4:7699–7707
Guo P, Wen MX, Wang L, Zheng YM (2014) Nanoscale 6:3917–3920
Oberli L, Caruso D, Hall C, Fabretto M, Murphy PJ, Evans DC (2014) Adv Colloid Interface Sci 210:47–57
Lee YW, Yu KY, Lee JK (2010) Langmuir 26:14110–14130
Wang FJ, Lei S, Xue MS, Ou JF, Li CQ, Li W (2014) J Phys Chem C 118:6344–6351
Cao LL, Jones AK, Sikka VK, Wu JZ, Gao D (2009) Langmuir 25:12444–12448
Wen MX, Lei L, Zhang MQ, Jiang L, Zheng YM (2014) ACS Appl. Mater. Interfaces 6:3963–3968
Yang J, Li W (2013) J Alloy Compd 576:215–219
Zhang YF, Yu XQ, Wu H, Wu J (2012) Appl Surf Sci 2012(258):8253–8257
Boinovich L, Emelyanenko AM, Korolev VV, Pashinin AS (2014) Langmuir 30:1659–1668
Kulinich SA, Farzaneh M (2011) Cold Reg Sci Technol 65:60–64
Kulinich SA, Farzaneh M (2009) Appl Surf Sci 255:8153–8157
Li XY, Yang BB, Zhang YQ, Gu GT, Li MM, Mao LQ (2014) J Sol-Gel Sci Technol 69:441–447
Zhang ZJ, Jiang XH, Sun CX, Hu JL, Huang HZ (2012) IEEE Trans Dielectr Electr Insul 19:1070–9878
Tarquini S, Antonini C, Amirfazli A, Marengo M, Palacios J (2014) Cold Reg Sci Technol 100:50–58
Li J, Wan HQ, Ye YP, Zhou HD, Chen JM (2012) Appl Surf Sci 261:470–472
Wang SD, Luo SS (2012) Appl Surf Sci 258:5443–5450
Mahadik SA, Mahadik DB, Kavale MS, Parale VG, Wagh PB, Barshilia HC, Gupta SC, Hegde ND, Rao AV (2012) J Sol-Gel Sci Technol 63:580–586
Hou WX, Wang QH (2009) J Colloid Interf Sci 333:400–403
Isimjan TT, Wang TY, Rohani S (2012) Chem Eng J 210:182–187
Xu L, Karunakaran RG, Guo J, Yang S (2012) ACS Appl Mater Interfaces 4:1118–1125
Yang H, Zhang XJ, Cai ZQ, Pi PH, Zheng DF, Wen XF, Cheng J, Yang ZR (2011) Surf Coat Tech 205:5387–5393
Yang HW, Cheng YR, Xiao F (2011) Appl Surf Sci 258:1572–1580
Rykaczewski K, Anand S, Subramanyam SB, Varanasi KK (2013) Langmuir 29:5230–5238
Kulinich SA, Farhadi S, Nose K, Du XW (2011) Langmuir 27:25–29
Feng J, Qin ZQ, Yao SH (2012) Langmuir 28:6067–6075
Boreyko JB, Chen CH (2009) Phys Rev Lett 103:184501-1–184501-4
Acknowledgments
The authors acknowledge the financial support by the National Natural Science Foundation of China (Grant No. 51263018), International S&T Cooperation Program of China (Grant No. 2012DFA51200), Science and Technology Supporting Plan of Jiangxi Province, Social Development Field (Grant Nos. 20122BBG70165) and Industrial Field (20133BBE50007), and the Key Laboratory for Microstructural Control of Metallic Materials of Jiangxi Province (Grant No. JW201423002).
Author information
Authors and Affiliations
Corresponding author
Electronic supplementary material
Below is the link to the electronic supplementary material.
Preparation of transparent and superhydrophobic coating surface on a glass bottle surface via a simple spray-coating method. (AVI 1982 kb)
Movie S2
Water droplets impinging on the superhydrophobic coating surface at different temperature under wind action. (AVI 3570 kb)
Rights and permissions
About this article
Cite this article
Wang, F., Yu, S., Ou, J. et al. Anti-icing performance of transparent and superhydrophobic surface under wind action. J Sol-Gel Sci Technol 75, 625–634 (2015). https://doi.org/10.1007/s10971-015-3733-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10971-015-3733-1