Abstract
Different citrate precursor powders of lanthanum chromite doped with copper LaCr1−xCuxO3 (0 ≤ x ≤ 0.4) have been synthesized by sol–gel method. After calcination, its structural and surface characteristics have been examined by X-ray diffraction to confirm the formation of the pure perovskite phase. Fourier transform infrared, differential thermal analysis and thermogravimetric analysis results indicate that the pure orthorhombic phase was obtained at temperature above 800 °C. The structure and morphology of the samples are characterized by SEM measurements indicating that the particles have nearly spherical shapes and are agglomerated. The study of electrochemical behavior shows that the electrode with large copper content has a better electrocatalytical activity.
Graphical Abstract
Similar content being viewed by others
References
Ponce S, Peña MA, Fierro JLG (2000) Appl Catal B 24:193–205
Leanza R, Rossetti I, Fabbrini L, Oliva C, Forni L (2000) Appl Catal B 28(1):55–64
Russo N, Fino D, Saracco G, Specchia V (2005) J Catal 229:459–469
Peña MA, Fierro JLG (2001) Chem Rev 101:1981–2018
Saracco G, Scibilia G, Iannibello A, Baldi G (1996) Appl Catal B 8:229–244
Hilpert K, Steinbrech RW, Borromand F, Teller O (2003) J Eur Ceram Soc 23:3009–3020
Tien-Thao N, Alamdari H, Zahedi-Niaki MH, Kaliaguine S (2006) Appl Catal A 311:204–212
Toniolo FS, Magalhaes RNSH, Perez CAC, Schmal M (2012) Appl Catal B 117–118:156–166
Zhang R, Villanueva A, Alamdari H, Kaliaguine S (2006) Appl Catal A 307:85–97
Jia L, Gao J, Fang W, Li Q (2009) Catal Commun 10:2000–2003
Nithya VD, Immanuel RJ, Senthilkumar ST, Sanjeeviraja C, Perelshtein I, Zitoun D, Selvan RK (2012) Mater Res Bull 47:1861–1868
Jitaru I, Berger D, Fruth V, Novac A, Stanica N, Rusu F (2000) Ceram Inter 26:193–196
Marcos Z, David L (2000) Chem Mater 12(9):2763–2769
Rida K, Benabbas A, Bouremmad F, Pena MA, Sastre E, Martinez-Arias A (2007) Appl Catal A 327(2):173–179
Taguchi H, Yamada S, Nagao M, Ichikawa Y, Tabata K (2002) Mater Res Bull 37(1):69–76
Tascon JMD, Tejuca LG (1981) J Chem Soc, Faraday Trans 1(77):591–602
Mali A, Ataie A (2005) Scripta Mater 53:1065–1070
Chakrabarti N, Maiti HS (1997) Mater Lett 30:169–173
Cullity BD (1978) Elements of X-ray diffractions. Addition Wesley, Reading 102
Diafi M, Omari M (2012) Bol Soc Esp Ceram Vidr 51(6):337–342
Hsiang HI, Yen FS, Chang YH (1996) J Mater Sci 31:2417–2424
Jung GB, Huang TJ, Huang MH, Chang CL (2001) J Mater Sci 36:5839–5844
Zhang R, Villanueva A, Alamdari H, Kaliaguine S (2006) J Mol Catal A Chem 258:22–34
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Adaika, K., Omari, M. Synthesis and physicochemical characterization of LaCr1−xCuxO3 . J Sol-Gel Sci Technol 75, 298–304 (2015). https://doi.org/10.1007/s10971-015-3699-z
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10971-015-3699-z