Abstract
Multiferroic (1−x)BiFeO3(BFO)–xNiFe2O4(NFO) (x = 0, 0.1, 0.2, 0.3) nanocomposite thin films were prepared by sol–gel technique and their structural, electrical and magnetic properties were studied. X-ray diffraction and transmission electron microscopy examinations confirmed that NFO nanoparticles were well distributed in BFO matrix. The magnetic and dielectric properties were significantly improved by incorporation of NFO nanoparticle in matrix of BFO. The saturation magnetization (M s ) and remnant magnetization (M r ) increased as high as ~34 and ~7 emu/cm3 respectively for x = 0.1. The dielectric constant of the films increased from 160 (for x = 0) to 280 (for x = 0.3). However, the values of ferroelectric polarization were decreased with increasing x. Importantly, the sample with (x = 0.1), the best sample in our study demonstrates improved ferroelectric as well as magnetic properties and thus provides a great opportunities for many passive electronic devices for future potential applications.
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Eerenstein W, Mathur ND, Scott JF (2006) Nature 442:759–765
Ramesh R, Spaldin NA (2007) Nat Mater 6:21–29
Nan CW, Bichurin MI, Dong S, Viehland D, Srinivasan G (2008) J Appl Phys 103:031101
Palkar VR, Kundaliya C, Malik SK, Bhattacharya S (2004) Phys Rev B 69:212102-1–212102-3
Ma J, Hu J, Li Z, Nan CW (2011) Adv Mater 23:1062–1087
Chen YJ, Hsieh YH, Liao SC, Hu Z, Huang MJ, Kuo WC, Chin YY, Uen TM, Juang JY, Lai CH, Lin HJ, Chen CT, Chu YH (2013) Nanoscale 5:4449
Yan F, Chen G, Lu L, Finkel P, Spanier EJ (2013) Appl Phys Lett 103:042906
Hsieh YH, Kuo HH, Liao SC, Liu HJ, Chen YJ, Lin HJ, Chen CT, Lai CH, Zhan Q, Chueh Y, Chu YH (2013) Nanoscale 5:6219
Sone K, Sekiguchi S, Naganuma H, Miyazaki T, Nakajima T (2012) J Appl Phys 111:124101-1–124101-5
Sarkar B, Dalal B, Vishal DA, Kaushik C, Amitava M, De SK (2014) J Appl Phys 115:123908
Guo R, Cross LE, Park SE, Noheda B, Cox DE, Shirane G (2000) Phys Rev Lett 84:5423
Zheng RY, Gao XS, Zhou ZH, Wang J (2007) J Appl Phys 101:054104-1–054104-5
Wang J, Neaton JB, Zheng H, Nagarajan V, Ogale SB, Liu B, Viehland D, Vaithyanathan V, Schlom DG, Waghmare UV, Spaldin NA, Rabe KM, Wuttig M, Ramesh R (2003) Science 299:1719–1722
Naganuma H, Inoue Y, Okamura S (2008) IEEE Trans Ultrason Ferroelectr Freq Control 55:1046–1050
Yan L, Xing ZP, Wang ZG, Wang T, Lei GY, Li JF, Viehland D (2009) Appl Phys Lett 94:192902
Crane SP, Bihler C, Brandt MS, Goennenwein STB, Gajek M, Ramesh R (2009) J Magn Magn Mater 321:L5–L9
Benatmane N, Crane SP, Zavaliche F, Ramesh R, Clinton TW (2010) Appl Phys Lett 96:082503
Gu J, Yang S, Yang W, Qi Y, Zhao G, Sun H (2014) J Magn Magn Mater 349:140–143
Tyagi M, Kumari M, Chatterjee R, Sun AC, Sharma P (2014) IEEE Trans Magn 50:2500704
Zhan Q, Yu R, Crane SP, Zheng H, Kisielowski C, Ramesh R (2006) Appl Phys Lett 89:172902
Scott JF (2008) J Phys Condens Matter 20:021001
Upadhyay SK, Reddy VR (2013) J Appl Phys 113:114107
Koops CG (1951) Phys Rev 83:121
Wagner KW (1993) Ann Phys 40:818
Babu SN, Hsu JH, Chen YS, Lin JG (2010) J Appl Phys 107:09D919
Babu SN, Hsu JH, Chen YS, Lin JG (2011) J Appl Phys 109:07D904
Acknowledgments
This work was supported in part by University grant commission (UGC), India, under Grant 40/446/2011 (SR). The authors also would like to acknowledge SQUID, a National facility at IIT Delhi (funded by DST, India) for magnetic measurements.
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Tyagi, M., Chatterjee, R. & Sharma, P. Improved dielectric and magnetic properties of multiferroic BiFeO3–NiFe2O4 nanocomposite thin films. J Sol-Gel Sci Technol 74, 692–697 (2015). https://doi.org/10.1007/s10971-015-3650-3
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DOI: https://doi.org/10.1007/s10971-015-3650-3