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Multifunctional superhydrophobic/oleophobic and flame-retardant cellulose fibres with improved ice-releasing properties and passive antibacterial activity prepared via the sol–gel method

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Abstract

In this research, a two-component sol–gel inorganic–organic hybrid coating was prepared on a cotton fibre surface. An equimolar sol mixture of the precursors 1H,1H,2H,2H-perfluorooctyltriethoxysilane (SiF) and P,P-diphenyl-N-(3-(trimethoxysilyl)propyl) phosphinic amide (SiP) was applied to cotton fabric samples using the pad-dry-cure method. The surfaces of the untreated and coated cotton fibres were characterised using scanning electron microscopy, Fourier transform-infrared spectroscopy, X-ray photoelectron spectroscopy, and time-of-flight-secondary ion mass spectrometry. The functional properties of the coated cotton fabric samples were investigated using static contact angle measurements with water and n-hexadecane, the ice-releasing test, antibacterial testing against Gram-positive Staphylococcus aureus and Gram-negative Escherichia coli, thermogravimetric analysis in an air atmosphere, and vertical flammability tests. The results reveal the formation of a nanocomposite two-component inorganic–organic hybrid polymer network that is homogenously distributed over the cotton fibre surface. The presence of the SiP component in the two-component inorganic–organic hybrid coating did not hinder the functional properties imparted by the presence of the SiF component and vice versa, illustrating their compatibility. The cooperative action of the SiF and SiP components in the two-component coating provided the cotton fabric with exceptional multifunctionality, including simultaneous superhydrophobicity and high oleophobicity, passive antibacterial activity, and improved thermo-oxidative stability.

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Acknowledgments

This work was supported by the Slovenian Research Agency (Programme P2-0213 and a Grant for the Ph.D. student J. V.).

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Authors and Affiliations

  1. Department of Textiles, Faculty of Natural Sciences and Engineering, University of Ljubljana, Aškerčeva 12, 1000, Ljubljana, Slovenia

    Jelena Vasiljević, Brigita Tomšič & Barbara Simončič

  2. National Institute of Chemistry, Hajdrihova 19, 1000, Ljubljana, Slovenia

    Ivan Jerman & Boris Orel

  3. Jožef Stefan Institute, Jamova 39, 1000, Ljubljana, Slovenia

    Gregor Jakša & Janez Kovač

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  1. Jelena Vasiljević
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  2. Brigita Tomšič
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  3. Ivan Jerman
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  4. Boris Orel
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  5. Gregor Jakša
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  6. Janez Kovač
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  7. Barbara Simončič
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Correspondence to Barbara Simončič.

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Vasiljević, J., Tomšič, B., Jerman, I. et al. Multifunctional superhydrophobic/oleophobic and flame-retardant cellulose fibres with improved ice-releasing properties and passive antibacterial activity prepared via the sol–gel method. J Sol-Gel Sci Technol 70, 385–399 (2014). https://doi.org/10.1007/s10971-014-3294-8

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  • DOI: https://doi.org/10.1007/s10971-014-3294-8

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