Skip to main content
Log in

Enhanced photoinduced super-hydrophilicity in sol–gel TiO2 thin films with co-doped Sn/Nb

  • Orginal Paper
  • Published:
Journal of Sol-Gel Science and Technology Aims and scope Submit manuscript

Abstract

In this work, Sn and Nb co-doped TiO2 were coated on glazed porcelain substrates via sol–gel dip coating method. Field emission-scanning electron microscopy, transmission electron microscopy, and UV–vis spectrophotometer were used to evaluate thickness and optical properties of the thin films. Surface chemical state of thin films was examined by atomic X-ray photoelectron spectroscopy. Water contact angle on the film surfaces was measured by a contact angle analyzer under solar light irradiation. The optical results indicated that Sn/Nb dopant in TiO2 thin film changed the absorption edge from ultraviolet to visible light and exhibited excellent photo-catalytic ability for degradation of methylene blue solution under solar irradiation. Wettability results indicated that Sn and Nb dopant ions had significant effect on the hydrophilicity property of thin films.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. Fujishima A, Rao TN, Tryk DA (2000) J Photochem Photobiol C Photochem Rev 1:1–21

    Article  Google Scholar 

  2. Hata S, Kai Y, Yamanaka I, Oosaki H, Hirota K, Yamazaki S (2000) JSAE Rev 21:97–202

    Article  Google Scholar 

  3. Feng Z, Kaiming L, Guoliang W, Hua S, Anmin H (2004) J Cryst Growth 264:297–301

    Article  Google Scholar 

  4. Yu JG, Zhao XJ (2001) Mater Res Bull 36:97–107

    Article  Google Scholar 

  5. Yu JG, Zhao XJ, Zhao QN, Wang G (2001) Mater Chem Phys 68:253–259

    Article  Google Scholar 

  6. Watenabe T, Nakajima A, Wang R, Minabe M, Koizumi S, Fujishima A, Hashimoto K (1999) Thin Solid Films 351:260–263

    Article  Google Scholar 

  7. Liu Z, wang Y, Peng X, Li Y, Liu Z, Liu C, Ya J, Huang Y (2012) J Sci Technol Adv Mater 13: Art No. 025001

  8. Ghasemi S, Rahimnejad S, Setayesh SR, Rohani S, Gholami MR (2009) J Hazard Mater 172:1573–1578

    Article  Google Scholar 

  9. Mardare D, Iacomi F, Cornei N, Girtan M, Luca D (2010) Thin Solid Films 518:4586–4589

    Article  Google Scholar 

  10. Akpan UG, Hameed BH (2010) Appl Catal A 375:1–11

    Article  Google Scholar 

  11. Liu Z, Ya J, Lei E, Xin Y, Zhao W (2010) J Chem Phys 120:277–283

    Google Scholar 

  12. Zorba V, Chen X, Mao S (2010) J Appl Phys Lett 96: Art No. 093702

  13. Koozegar Kaleji B, Sarraf-Mamoory Rasoul, Nakata K, Fujishima A (2011) J Sol–Gel Sci Technol 60:99–107

    Article  Google Scholar 

  14. Koozegar Kaleji B, Sarraf Mamoory Rasoul, Nakata K, Fujishima A (2012) Mater Chem Phys 132:210–215

    Article  Google Scholar 

  15. Koozegar Kaleji B, Hosseinabadi Navid, Fujishima A (2013) J Sol–Gel Sci Technol 65:195–203

    Article  Google Scholar 

  16. Baker RW (2004) Membrane technology and application. Wiley Pub, Chichester

    Book  Google Scholar 

  17. Sharma R, Bhatnagar M (1999) Sens Actuators, B 56:215–219

    Article  Google Scholar 

  18. Fresno F, Coronado JM, Tudela D, Soria (2005) J Appl Catal B Environ 55:159–167

    Article  Google Scholar 

  19. Sanjines R, Tang H, Berger H, Gozzo F, Margaritondo G (1994) J Appl Phys 75:2945–2951

    Article  Google Scholar 

  20. Cao Y, Yang W, Zhang W, Liu G, Yue P (2004) New J Chem 28:218–222

    Article  Google Scholar 

  21. Moulder JF, Stickle WF, Sool PE, Bomben KD (1992) Handbook of X-ray photoelectron spectroscopy. Perkin-Elmer, Eden Prairie

    Google Scholar 

  22. Kamat PV (1993) Chem Rev 93:267–300

    Article  Google Scholar 

  23. Guan K, Lu B, Yin Y (2003) Surf Coat Technol 173:219–223

    Article  Google Scholar 

  24. Miyauchi M, Nakajima A, Fujishima A, Hashimoto K, Watanabe T (2000) Chem Mater 12:3–5

    Article  Google Scholar 

  25. Nakajima A, Koizumi SI, Watanabe T, Hashimoto K (2000) Langmuir 16:7048–7050

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Behzad Koozegar Kaleji.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kaleji, B.K., Hosseinabadi, N. Enhanced photoinduced super-hydrophilicity in sol–gel TiO2 thin films with co-doped Sn/Nb. J Sol-Gel Sci Technol 69, 412–417 (2014). https://doi.org/10.1007/s10971-013-3235-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10971-013-3235-y

Keywords

Navigation