Abstract
In this work, the laser dye PM567 was incorporated into various organically modified silicate gel glasses (ORMOSILs) derived by methyltriethoxysilane (MTES) and vinyltriethoxysilane (VTES) precursors mixed in various ratios. The laser performances of PM567 doped into MTES–VTES-derived ORMOSILs including the laser slope efficiency, threshold and lifetime together with the spectroscopic properties were investigated. Blue-shifts of fluorescent peaks, extended fluorescent lifetime, improved laser efficiency and lifetime of PM567 doped into ORMOSILs derived by mixed precursors of MTES and VTES have been observed, which might related to the microstructures and micro-chemical environment of the dye in ORMOSILs.
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The authors gratefully acknowledge the financial support for this work from the National Natural Science Foundation of China (Nos. 51010002, 51272231 and 51229201), Natural Science Foundation of Zhejiang Province (No. LY12E02004), and the Fundamental Research Funds for the Central Universities.
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Liao, Z., Zhou, Y., Yang, Y. et al. Fluorescent and laser properties of pyrromethene 567 (PM567) doped into multi-precursors derived gel glasses. J Sol-Gel Sci Technol 67, 480–485 (2013). https://doi.org/10.1007/s10971-013-3104-8
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DOI: https://doi.org/10.1007/s10971-013-3104-8