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One pot synthesis of ordered mesoporous organosilica particles bearing propyl-, octyl- and hexadecyl-chains

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Abstract

New hybrid organic–inorganic materials exhibiting ordered mesoporous structures have been synthesized by co-condensation of tetraethoxysilane and various alkyltrimethoxysilanes with increasing length of the hydrocarbon chain (propyl, octyl, hexadecyl), in water–ethanol solution containing ammonia, in the presence of a cationic surfactant (cetyltrimethylammonium bromide) as templating agent. The obtained hybrid materials were characterized by using several physico-chemical techniques, such as X-ray diffraction, N2 adsorption, 29Si MAS NMR, SEM and elemental analysis. It was shown that the direct synthesis procedure allows obtaining ordered hybrid mesoporous silica with various contents of organic functions, from 5 to 20 %. Moreover, increasing the chain length of the organic group, from propyl to octyl and hexadecyl leads to a change of the pore structure from hexagonal p6mm MCM-41 type architecture to cubic Ia3d MCM-48 type mesostructure.

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Acknowledgments

The authors would like to thank L. Mouton for taking SEM pictures (SCMEM, Faculté des Sciences et Technologies, Université de Lorraine), S. Adach for CHNS analyses (SRSMC, Faculté des Sciences et Technologies, Université de Lorraine, service d’analyse élémentaire), and M.C. De Weerd (CP2S, Institut Jean Lamour—UMR 7198, Université de Lorraine).

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Authors and Affiliations

  1. Laboratoire de Chimie Physique et Microbiologie pour l’Environnement, UMR 7564 CNRS, Université de Lorraine, Faculté des Sciences et Technologies, 405, rue de Vandoeuvre, 54600, Villers-lès-Nancy, France

    Natalya A. Vodolazkaya, Christelle Despas & Alain Walcarius

  2. Department of Physical Chemistry, V. N. Karazin Kharkov National University, Svoboda sq. 4, Kharkiv, 61077, Ukraine

    Natalya A. Vodolazkaya

  3. Institut de Science des Matériaux de Mulhouse, équipe Matériaux à Porosité Contrôlée, LRC 7228, CNRS, Ecole Nationale Supérieure de Chimie de Mulhouse, Université de Haute Alsace, 3 rue Alfred Werner, 68093, Mulhouse cedex, France

    Bénédicte Lebeau & Claire Marichal

Authors
  1. Natalya A. Vodolazkaya
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  2. Christelle Despas
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  3. Bénédicte Lebeau
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  4. Claire Marichal
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  5. Alain Walcarius
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Correspondence to Christelle Despas or Bénédicte Lebeau.

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Vodolazkaya, N.A., Despas, C., Lebeau, B. et al. One pot synthesis of ordered mesoporous organosilica particles bearing propyl-, octyl- and hexadecyl-chains. J Sol-Gel Sci Technol 63, 587–594 (2012). https://doi.org/10.1007/s10971-012-2816-5

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