Synthesis of LiCoO₂ by l-apple acid assisted sol–gel method and its electrochemical behavior in aqueous lithium-ion battery

Abstract

The synthesis process of LiCoO₂ prepared by l-apple acid (l-HOOCCH(OH)CH₂COOH) assisted sol–gel method is studied by using Fourier transforms infrared spectroscopy, mass spectroscopy, simultaneous thermogravimetric and differential thermal analysis, X-ray diffraction analysis, and elemental analysis. The results show that lithium and cobalt ions are trapped homogeneously on an atomic scale throughout the precursor. Lithium carbonate and Co₃O₄ are intermediate products during heat treatment of the precursor. Moreover, the kinetics for formation of LiCoO₂ by l-apple acid assisted sol–gel method is faster than the case of the conventional solid-state reaction between lithium carbonate and Co₃O₄. In comparison with the solid-state reaction, the sol–gel method significantly shortens the required reaction time for synthesizing LiCoO₂, and also reduces the particle size. In the electrochemical test, it is found that the specific discharge/charge capacities as well as the coulomb efficiency substantially increase with increasing the calcination temperature. It is considered that LiCoO₂ with a good-layered structure facilitates the insertion and de-insertion of lithium ions in aqueous electrolyte. As a result, the combination of the sol–gel method with proper calcination processes is highly successful in producing LiCoO₂ powders with large specific capacity and good cycle performance in aqueous lithium-ion battery.