Abstract
A tile-like Ta2O5 aerogel monolithic was prepared by sol–gel method. Tantalum ethoxide and tantalum pentachloride were used as precursors, ethanol as the solvent, and propylene oxide as the gelation agent. Field emission scanning electron microscopy (FESEM), high-resolution transmission electron microscopy (HRTEM), and Brunauer–Emmett–Teller (BET) and Barrett–Joyner–Halenda (BJH) methods were used to characterize the as-prepared aerogel. The combined results of these techniques indicated the presence of tantalum pentachloride and propylene oxide leading to the high porosity, high surface area, and low density of the Ta2O5 aerogel monolithic.
Similar content being viewed by others
References
Mccusker LB, Liebau F, Engelhardt G (2001) Nomenclature of structural and compositional characteristics of ordered microporous and mesoporous materials with inorganic hosts. Pure Appl Chem 73(2):381–394
Jenekhe SA, Chen XL (1999) Self-assembly of ordered microporous materials from rod-coil block copolymers. Science 283(5400):372–375
Beyer HK, Mihályi RM, Minchev Ch, Neinska Y, Kanazirev V (1996) Study of the reductive solid-state ion exchange of indium into NH4NaY zeolite. Microporous Mater 7(6):333–341
Reid CR, Thomas KM (1999) Adsorption of gases on a carbon molecular sieve used for air separation: linear adsorptives as probes for kinetic selectivity. Langmuir 15(9):3206–3218
Shu H-T, Li D, Scala AA, Ma YH (1997) Adsorption of small organic pollutants from aqueous streams by aluminosilicate-based microporous materials. Sep Purif Technol 11(1):27–36
Zhang Z, Han Y, Xiao F-S, Qiu S, Zhu L, Wang R, Yu Y, Zhang Z, Zou B, Wang Y, Sun H, Zhao D, Wei Y (2001) Mesoporous aluminosilicates with ordered hexagonal structure, strong acidity, and extraordinary hydrothermal stability at high temperatures. J Am Chem Soc 123(21):5014–5021
Berlini C, Guidotti M, Moretti G, Psaro R, Ravasio N (2000) Catalytic epoxidation of unsaturated alcohols on Ti-MCM-41. Catal Today 60(3–4):219–225
Doadrio AL, Sousa EMB, Doadrio JC, Pérez Pariente J, Izquierdo-Barba I, Vallet-Regi M (2004) Mesoporous SBA-15 HPLC evaluation for controlled gentamicin drug delivery. J Control Release 97(1):125–132
Selvam P, Bhatia SK, Sonwane CG (2001) Recent advances in processing and characterization of periodic mesoporous MCM-41 silicate molecular sieves. Ind Eng Chem Res 40(15):3237–3261
Aricò AS, Bruce P, Scrosati B, Tarascon J-M, van Schalkwijk W (2005) Nanostructured materials for advanced energy conversion and storage devices. Nat Mater 4(5):366–377
Yamada T, Zhou HS, Uchida H, Tomita M, Ueno Y, Honma I, Asai K, Katsube T (2002) Application of a cubic-like mesoporous silica film to a surface photovoltage gas sensing system. Microporous Mesoporous Mater 54(3):269–276
Gao F, Lu Q, Liu I, Yan Y, Zhao D (2001) Controlled synthesis of semiconductor PbS nanocrystals and nanowires inside mesoporous silica SBA-15 phase. Nano Lett 1(12):743–748
Kato H, Kudo A (1998) New tantalate photocatalysts for water decomposition into H2 and O2. Chem Phys Lett 295(5–6):487–492
Kim KY, Ahn WS, Park DW, Oh JH, Lee CM, Tai WP (2004) Microwave synthesis of titanium silicalite-1 using solid phase precursors. Bull Korean Chem Soc 25(5):634–638
Takahara Y, Kondo JN, Takata T, Lu D, Domen K (2001) Mesoporous tantalum oxide. 1. Characterization and photocatalytic activity for the overall water decomposition. Chem Mater 13(4):1194–1199
Miller JE (2007) High-pressure equation-of-state of porous-Ta2O5. University of Rochester, Dissertation
Huo Q, Margolese DI, Ciesla U, Feng P, Gier TE, Sieger P, Leon R, Petroff PM, Schüth F, Stucky GD (1994) Generalized synthesis of periodic surfactant/inorganic composite materials. Nature 368(6469):317–321
Ying JY, Mehnert CP, Wong MS (1999) Synthesis and applications of supramolecular-templated mesoporous materials. Angew Chem Int Ed 38(1–2):56–77
Antonelli DM, Ying JY (1996) Synthesis and characterization of hexagonally packed mesoporous tantalum oxide molecular sieves. Chem Mater 8(4):874–881
Kondo JN, Takahara Y, Lu D, Domen K (2001) Mesoporous Ta oxide. 2. Improvement of the synthetic method and observation of mesostructure formation. Chem Mater 13(4):1200–1206
Droege MW, Coronado PR, Hair LM (1995) Method for making monolithic metal oxide aerogels. US Patent 5,395,805
Rouquerol J, Avnir D, Fairbridge CW, Everett DH, Haynes JH, Pernicone N, Ramsay JDF, Sing KSW, Unger KK (1994) Recommendations for the characterization of porous solids. Pure Appl Chem 66(8):1739–1758
Livage J, Henry M, Sanchez C (1988) Sol–gel chemistry of transition metal oxides. Prog Solid State Chem 18(5):259–341
Duraes L, Costa BFO, Vasques J, Campos J, Portugal A (2005) Phase investigation of as-prepared iron oxide/hydroxide produced by sol–gel synthesis. Mater Lett 59(7):859–863
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Ren, H., Zhang, L., Shang, C. et al. Synthesis of a low-density tantalum oxide tile-like aerogel monolithic. J Sol-Gel Sci Technol 53, 307–311 (2010). https://doi.org/10.1007/s10971-009-2092-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10971-009-2092-1