Skip to main content
SpringerLink
Log in

Synthesis and characterization of ternary hybrid material based on poly-o-methoxyaniline and poly(ethylene oxide) in mesostructured V2O5

  • Original Paper
  • Published:
Journal of Sol-Gel Science and Technology Aims and scope Submit manuscript

Abstract

New hybrid composites based on mesostructured V2O5 containing intercalated poly(ethylene oxide), poly-o-methoxyaniline and poly(ethylene oxide)/poly-o-methoxyaniline were prepared. The results suggest that the polymers were intercalated into the layers of the mesostructured V2O5. Electrochemical studies showed that the presence of both polymers in the mesostructured V2O5 (ternary hybrid) leads to an increase in total charge and stability after several cycles compared with binary hybrid composites. This fact makes this material a potential component as cathode for lithium ion intercalation and further, a promising candidate for applications in batteries.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. Yano K, Usuki A, Okada A, Kurauchi T, Kamigaito O (1991) Polymer Prepr 32:65

    CAS  Google Scholar 

  2. Gomez-Romero P (2001) Adv Mater 13:163. doi:10.1002/1521-4095(200102)13:3<163::AID-ADMA163>3.0.CO;2-U

    Article  CAS  Google Scholar 

  3. Crepaldi EL, Grosso D, Soler-Illia GJAA, Albouy P-A, Amenitsch H, Sanchez C (2002) Chem Mater 14:3316. doi:10.1021/cm021151z

    Article  CAS  Google Scholar 

  4. Guerra EM, Ciuffi KJ, Oliveira HP (2006) J Solid State Chem 179:3814. doi:10.1016/j.jssc.2006.08.018

    Article  ADS  CAS  Google Scholar 

  5. Guerra EM, Brunello CA, Graeff CFO, Oliveira HP (2002) J Solid State Chem 168:134. doi:10.1006/jssc.2002.9700

    Article  ADS  CAS  Google Scholar 

  6. Stein A, Melde BJ, Schroden RC (2000) Adv Mater 12:1403. doi:10.1002/1521-4095(200010)12:19<1403::AID-ADMA1403>3.0.CO;2-X

    Article  CAS  Google Scholar 

  7. Hyodo T, Shimizu Y, Egashira M (2003) Electrochemistry 71:387

    CAS  Google Scholar 

  8. Lu DL, Lee B, Kondo JN, Domen K (2004) Microporous Mesoporous Mater 75:203. doi:10.1016/j.micromeso.2004.07.002

    Article  CAS  Google Scholar 

  9. Wu YY, Cheng GS, Katsov K, Sides SW, Wang JF, Tang J, Fredrickson GH, Moskovits M, Stucky GD (2004) Nat Mater 3:816. doi:10.1038/nmat1230

    Article  PubMed  ADS  CAS  Google Scholar 

  10. Yu JC, Zhang LZ, Yu JG (2002) N J Chem 26:416. doi:10.1039/b109173e

    Article  CAS  Google Scholar 

  11. Ruckenstein E, Chao Z-S (2001) Nano Lett 1:739. doi:10.1021/nl015634y

    Article  CAS  Google Scholar 

  12. Posudievsky OY, Biskulova SA, Pokhodenko VD (2004) J Mater Chem 14:1419. doi:10.1039/b400495g

    Article  CAS  Google Scholar 

  13. Coustier F, Hill J, Owens BB, Passerini S, Smyrl WH (1999) J Electrochem Soc 146:1355. doi:10.1149/1.1391770

    Article  CAS  Google Scholar 

  14. Liu P, Lee SH, Tracy CE, Turner JA, Pitts JR, Deb SK (2003) Solid State Ion 165:223. doi:10.1016/j.ssi.2003.08.044

    Article  CAS  Google Scholar 

  15. Li ZF, Ruckenstein E (2002) Langmuir 18:6956. doi:10.1021/la0203887

    Article  CAS  Google Scholar 

  16. Stine KE (1970) Beckman Infrared Laboratory Manual. Beckman Instruments Inc, Ney York

    Google Scholar 

  17. Gregg SJ, Sing KSW (1982) Adsorption, Surface Area and Porosity. Academic Press, London

    Google Scholar 

  18. Wu Z-G, Zhao YX, Liu DS (2004) Microporous Mesoporous Mater 68:127. doi:10.1016/j.micromeso.2003.12.018

    Article  CAS  Google Scholar 

  19. Sing KSW, Everett DH, Haul RA, Moscou L, Pierotti RA, Rouquérol J, Siemieniewska T (1985) Pure Appl Chem 57:603. doi:10.1351/pac198557040603

    Article  CAS  Google Scholar 

  20. Noh JA, Schwartz JA (1986) J Colloid Interface Sci 27:531

    Google Scholar 

  21. Sing KSW (1968) Chem Ind 44:1520

    Google Scholar 

  22. Gommes CJ, Blacher S, Pirard J-P (2005) Langmuir 21:1703. doi:10.1021/la0471543

    Article  PubMed  CAS  Google Scholar 

  23. Sanchez C, Livage J, Lucazeau G (1982) J Raman Spect 12:68. doi:10.1002/jrs.1250120110

    Article  CAS  Google Scholar 

  24. Balderas-Tapia L, Hernandez-Perez I, Schacht P, Cordova IR, Aguilar-Rıos GG (2005) Catal Today 107–108:371. doi:10.1016/j.cattod.2005.07.025

    Article  Google Scholar 

  25. Silverstein RM, Bassler GC (1974) Spectrometric identification of organic compounds, 5th edn. Wiley, Ney York

  26. Scarmino J, Talledo A, Andersson AA, Passerini S, Decker F (1993) Electrochim Acta 38:1637. doi:10.1016/0013-4686(93)85053-2

    Article  Google Scholar 

Download references

Acknowledgments

The authors gratefully acknowledge the fellowship provided by CAPES. FAPESP and CNPq are also acknowledged for financial support.

Author information

Authors and Affiliations

  1. Departamento de Química, Faculdade de Filosofia, Ciências e Letras de Ribeirão Preto, Universidade de São Paulo, 14040-901, Ribeirão Preto, SP, Brazil

    Elidia M. Guerra & Herenilton P. Oliveira

Authors
  1. Elidia M. Guerra
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Herenilton P. Oliveira
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Elidia M. Guerra.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Guerra, E.M., Oliveira, H.P. Synthesis and characterization of ternary hybrid material based on poly-o-methoxyaniline and poly(ethylene oxide) in mesostructured V2O5 . J Sol-Gel Sci Technol 50, 103–110 (2009). https://doi.org/10.1007/s10971-009-1910-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10971-009-1910-9

Keywords

Search

Navigation