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Preparation and characterization of periodic mesoporous organosilica terminally functionalized with fluorocarbon groups by a direct synthesis

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Abstract

Fluorocarbon groups were used to modify the pore channels of ethane-bridged periodic mesoporous organosilica by the co-condensation of 1,2-Bis(triethoxysilyl)ethane (BTESE) and trifluoropropyltrimethoxysilane (TFPTMS) in the presence of Poly(ethylene glycol)-B-Poly(propylene glycol)-B-Poly(ethylene glycol) (P123) surfactants under acidic conditions. The functionalized materials were investigated in detail by means of XRD, TEM, FT-IR, solid-state NMR, and N2 adsorption. The effect of fluorocarbon groups concentration on the mesoscopic order and pore structure of the functionalized materials was also studied. The results show that bridging groups in the framework do not cleave and fluorocarbon groups are attached covalently to the pore wall of periodic mesoporous organosilica after functionalization. The samples functionalized with 20% TFPTMS remain desired mesoporous architecture, with a narrow pore size distribution centered at 4.1 nm, a large surface of 834 m2/g and a pore volume of 0.91 cm3g−1, without pronounced change compared to the pure periodic mesoporous organosilica. Unfortunately the functionalized materials become structurally disordered with increasing amount of fluorocarbon groups.

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References

  1. Asefa T, MacLachlan MJ, Coombs N, Ozin GA (1999) Nature 402:867

    CAS  Google Scholar 

  2. Melde BJ, Holland BT, Blanford CF, Stein A (1999) Chem Mater 11:3302

    Article  CAS  Google Scholar 

  3. Inagaki S, Guan S, Fukushima Y, Ohsuna T, Terasaki O (1999) J Am Chem Soc 121:9611

    Article  CAS  Google Scholar 

  4. Whitnall W, Asefa T, Ozin GA (2005) Adv Funct Mater 15:259

    Article  Google Scholar 

  5. Olkhovyk O, Jaroniec M (2005) J Am Chem Soc 127:60

    Article  CAS  Google Scholar 

  6. Hatton B, Landskron K, Whitnall W, Perovic D, Ozin GA (2005) Acc Chem Res 38:305

    Article  CAS  Google Scholar 

  7. Landskron K, Hatton BH, Perovic DD, Ozin GA (2003) Science 302:266

    Article  CAS  Google Scholar 

  8. Asefa T, Kruk M, MacLachlan MJ, Coombs N, Grondey H, Jaroniec M, Ozin GA (2001) J Am Chem Soc 123:8520

    Article  CAS  Google Scholar 

  9. Kuroki M, Asefa T, Whitnal W, Kruk M, Ishii CY, Jaroniec M, Ozin GA (2002) J Am Chem Soc 124:13886

    Article  CAS  Google Scholar 

  10. Kresge CT, Leonowicz ME, Roth WJ, Vartuli JC, Beck JS (1992) Nature 359:710

    Article  CAS  Google Scholar 

  11. Zhao DY, Feng JL, Huo QS, Melosh N, Fredrickson GH, Chmelka BF, Stucky GD (1998) Science 279:548

    Article  CAS  Google Scholar 

  12. Tanev PT, Pinnavaia TJ (1995) Science 267:865

    Article  CAS  Google Scholar 

  13. Bagshaw SA, Pinnavaia TJ (1996) Angew Chem Int Ed 35:1102

    Article  CAS  Google Scholar 

  14. Feng X, Frywell GE, wang LQ, Kim AY, Liu J, Kemner KM (1997) Science 276:923

    Article  CAS  Google Scholar 

  15. Frywell GE, Liu J, Hauser TA, Zie Z, Ferris KF, Mattigod S, Gong M, Hallen RT (1999) Chem Mater 11:2148

    Article  Google Scholar 

  16. Brown J, Mercier L, Pinnavaia TJ (1999) Chem Commun 69

  17. Burleigh MC, Markowitz MA, Spector MS, Gaber BP (2001) J Phys Chem B 105:9935

    Article  CAS  Google Scholar 

  18. Hamoudi S, Royer S, Kaliaguine S (2004) Micropor Mesopor Mater 71:17

    Article  CAS  Google Scholar 

  19. Hamoudi S, Kaliaguine S (2003) Micropor Mesopor Mater 59:195

    Article  CAS  Google Scholar 

  20. Corriu R, Mehdi A, Reye C, Thieuleux C (2002) Chem Commun 1382

  21. Wahab MA, Imae I, Kawakami Y, Ha C-S (2005) Chem Mater 17:2165

    Article  CAS  Google Scholar 

  22. Liu Y, Gu Z, Margrave JL, Khabashesku VN (2004) Chem Mater 16:3924

    Article  CAS  Google Scholar 

  23. Sayari A, Hamoudi S, Yang Y, Moudrakovski IL, Ripmeester JR (2000) Chem Mater 12:3857

    Article  CAS  Google Scholar 

  24. Yu DQ, Yang JS, Xie JX (1989) Handbook of analytical chemistry: nuclear magnetic resonance (in Chinese). Chemical Industry Press, Beijing, p 476, 542 & 548

    Google Scholar 

  25. Guo W, Park J-Y, Oh M-O, Jeong H-W, Cho W-J, Kim I, Ha C-S (2003) Chem Mater 15:2295

    Article  CAS  Google Scholar 

  26. Wang Y, Zibrowius B, Yang C-M, Spliethoff B, Schüth F (2004) Chem Commun 46

  27. Zhao DY, Huo QS, Feng JL, Chmelka BF, Stucky GD (1998) J Am Chem Soc 120:6024

    Article  CAS  Google Scholar 

  28. Huh S, Wiench JW, Yoo JC, Pruski M, Lin VSY (2003) Chem Mater 15:4247

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The financial support of National Natural Science Foundation of China (granted No. 50525413 and 50502002), Scientific Research Common Program of Beijing Municipal Commission of Education (granted No. KM200610005016).

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Authors and Affiliations

  1. College of Materials Science & Engineering, Beijing University of Technology, 100 Pingleyuan, Chaoyang District, Beijing, 100022, P. R. China

    Qi Wei, Li Liu, Zuo-Ren Nie, Hui-Qiao Chen & Jing-Xia Zou

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  1. Qi Wei
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  2. Li Liu
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  3. Zuo-Ren Nie
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  4. Hui-Qiao Chen
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  5. Jing-Xia Zou
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Correspondence to Qi Wei.

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Wei, Q., Liu, L., Nie, ZR. et al. Preparation and characterization of periodic mesoporous organosilica terminally functionalized with fluorocarbon groups by a direct synthesis. J Sol-Gel Sci Technol 44, 105–110 (2007). https://doi.org/10.1007/s10971-007-1602-2

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  • DOI: https://doi.org/10.1007/s10971-007-1602-2

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