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Dispersion of silica nano-particles in sol-gel hybrid resins for fabrication of multi-scale hybrid nanocomposite

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Abstract

Multi-scale hybrid nanocomposites containing both ∼15 nm silica colloids and ∼2 nm oligosiloxanes in a methacryl polymer matrix were newly designed and fabricated. Colloidal silica sols were dispersed in methacryl oligosiloxanes nano-hybrid resins synthesized by sol-gel reaction of methacryloxypropylmethoxysilane and diphenylsilanediol. On the basis of TEM and SANS analyses, it was confirmed that the silica colloids were compatibly dispersed and different sizes of colloidal silica and oligosiloxanes co-exist in the solutions. Multi-scale hybrid nanocomposites fabricated by UV and thermal curing with incorporation of silica colloids in the nano-hybrid materials show enhanced mechanical and thermal characteristics.

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References

  1. Schmidt H, Jonschker G, Goedickev S, Mennig M (2000) J Sol-Gel Sci Technol 19:39

    Article  CAS  Google Scholar 

  2. Sanchez C, Julian B, Belleville P, Popall M (2005) J Mater Chem 15:3559; Sanchez C, Lebeau B (2000) MRS Bull 26:377; Judeinstein P, Sanchez C (1996) J Mater Chem 6(4):511; Lecomte M, Viana B, Sanchez C (1991) J Chim Phys 88:39

  3. Haas KH (2000) Adv Eng Mater 2(9):571; Haas KH, Amberg-Schwab S, Rose K (1999) Thin Solid Films 351:198

  4. Gellermann C, Storch W, Wolter H (1997) J Sol-Gel Sci Technol 8:173

    CAS  Google Scholar 

  5. Choi J, Kim SG, Laine RM (2004) Macromol 37:99

    Article  CAS  Google Scholar 

  6. Novak BM (1993) Adv Mater 5(6):422

    Article  CAS  Google Scholar 

  7. Reynaud E, Gauthier C, Perez J (1999) Rev Metall/Cah Inf Tech 96(2):169

    CAS  Google Scholar 

  8. Chung HJ, Ohno K, Fukuda T, Composto RJ (2005) Nano Letters 5(10):1878

    Article  CAS  Google Scholar 

  9. Shaheen SE, Ginley DS, Jabbour GE (2005) MRS Bull 30:10

    CAS  Google Scholar 

  10. Kim WS, Lee JH, Shin SY, Kim YC, Bae BS (2004) IEEE Photon Technol Lett 16(8):1888

    Article  Google Scholar 

  11. Sanchez C, Ribot F (1994) New J Chem 18:1007

    CAS  Google Scholar 

  12. Sanchez C, Soler-Illia GJAA, Ribot F, Grosso D, Chimie CR 6:1131

  13. Schubert U, Husing N, Lorenz A (1995) Chem Mater 7:2010

    Article  CAS  Google Scholar 

  14. Schmidt H (1997) J Sol-Gel Sci Technol 8:557; Bourgeat-Lami E (2002) J Nanosci Nanotech 2:1; Haraguchi K, Usami Y (1997) Chem Lett 51:1997; Jun JB, Hong JK, Park JG, Suh KD (2003) Macromol Chem Phys 18:204

  15. Laine RM, Choi J, Lee I (2001) Adv Mater 13:800; Zhang C, Laine RM (1998) J Am Chem Soc 120:8380

    Article  CAS  Google Scholar 

  16. Eo YJ, Kim JH, Ko JH, Bae BS (2005) J Mater Res 20(2):401; Eo YJ, Lee TH, Kim SY, Kang JK, Han YS, Bae BS (2005) J Polym Sci, Part B: Polym Phys 43:827; Eo YJ, Kim JH, Ko JH, Bae BS (2004) XX ICG’04 Proceedings 20;11–046

    Google Scholar 

  17. Lee TH, Kim JH, Ko JH, Bae BS (2004) Mater Res Soc Symp Proc 847:8.8.1–8.8.6; Lee TH, Kim JH, Bae BS (2006) J Mater Chem 16:1657; Kim WS, Kim KS, Eo YJ, Yoon KB, Bae BS (2005) J Mater Chem 15:465

  18. Hay JN, Raval HM (2001) Chem Mater 3396

  19. Schubert U, Hussing N, Lorenz A (1995) Chem Mater 1010

  20. Yoshitake K, Yokoyama T (2000) US Pat, No 6 025 455

  21. Product information of MEK-ST, see http://www.snowtex.com/

  22. Seong BS, Han YS, Lee CH, Hong KP, Park KN, Kim HJ (2002) Appl Phys A 74(Suppl.):201

    Article  Google Scholar 

  23. NIST SANS homepage, see http://www.ncnr.nist.gov/programs/ sans/

  24. Zhou Z, Wu P, Ma C (1990) Colloids Surfaces 50:177

    Article  CAS  Google Scholar 

  25. Arieh BN (1980) In Hydrophobic interaction, Plenum Press, New York and London, p 15

  26. Kim JH, Thesis MS (2005) Korea advanced institute of science and technology

  27. Oliver WC, Pharr GM (1992) J Mater Res 7:1564

    CAS  Google Scholar 

Download references

Acknowledgments

This study was supported by Korea Institute of Science & Technology Evaluation and Planning (KISTEP) and Ministry of Science & Technology (MOST), Korean government, through its National Nuclear Technology Program.

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Authors and Affiliations

  1. Laboratory of Optical Materials and Coating (LOMC), Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology (KAIST), Daejeon, 305-701, Republic of Korea

    Jeong Hwan Kim, Ji Hoon Ko & Byeong-Soo Bae

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  1. Jeong Hwan Kim
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  2. Ji Hoon Ko
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  3. Byeong-Soo Bae
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Correspondence to Byeong-Soo Bae.

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Kim, J.H., Ko, J.H. & Bae, BS. Dispersion of silica nano-particles in sol-gel hybrid resins for fabrication of multi-scale hybrid nanocomposite. J Sol-Gel Sci Technol 41, 249–255 (2007). https://doi.org/10.1007/s10971-006-9001-7

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  • DOI: https://doi.org/10.1007/s10971-006-9001-7

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