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Spectral characterization of chlorophyll fluorescence in extract of barley leaves embedded in silica xerogel matrix

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Abstract

We have used the sol-gel method to prepare SiO2 based matrix containing barley leaves extracts and studied the spectral characteristics of chlorophyll fluorescence of the glass under structural evolution promoted by heat treatment. One primary effect on the fluorescence for barley leaves embedded in glass is that PSII chlorophyll fluorescence transients are not present. We obtain a higher PSII thermostability for leaves embedded in xerogel matrix than in the green barley leaves. We observed for high temperatures that fluorescing aggregates are formed. The behavior of the PSII fluorescence under heat treatment will be used in subsequent works to study the microstructural evolution during the silica-gel-glass conversion and their optical properties.

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Abbreviations

PSI::

Photosystem I

PSII::

Photosystem II

LHC::

Light Harvesting Complexes

qE::

High-Energy-State Quenching

PPCs::

Pigment-Protein Complexes

References

  1. Levy D, Esquivias L (1995) Adv Mater 7:120

    Article  CAS  Google Scholar 

  2. Qian G, Wang M (1999) J Phys D: Appl Phys 32:2462

    Article  CAS  Google Scholar 

  3. Matsui K, Tominaga M, Arai Y, Satoh H, Kyoto M (1994) J Non-Cryst Solids 169:295

    Article  CAS  Google Scholar 

  4. Qian GD, Wang MQ, Fan XP, Hong ZL (1998) Chinese J Mater Res 12:102

    CAS  Google Scholar 

  5. Winter R, Hua DW, Song X, Mantulin W, Jonas J (1990) J Phys Chem 94:2706

    Article  CAS  Google Scholar 

  6. Malins C, MacCraith BD (1998) Analyst 123:2373

    Article  CAS  Google Scholar 

  7. Dave BC, Soyez H, Miller JM, Dunn B, Valentine JS, Zink JI (1995) Chem Mater 7:1431

    Article  CAS  Google Scholar 

  8. Suratwala T, Gardlund Z, Davidson K, Uhlmann DR (1998) Chem Mater 10:190

    Article  CAS  Google Scholar 

  9. Hinić I, Stanišić G, Popović Z (2003) J Serb Chem Soc 68:953

    Article  Google Scholar 

  10. Mackenzie JD (1994) J Sol-Gel Sci Technol 2:81

    Article  CAS  Google Scholar 

  11. Innocenzi P, Abdirashid MO, Guglielmi M (1994) J Sol-Gel Sci Technol 3:189

    Article  Google Scholar 

  12. Livage J, Coradin T, Roux C (2001) J Phys Condens Matter 13:R673

    Article  CAS  Google Scholar 

  13. Braun S, Rappaport S, Zusman R, Avnir D, Ottolenghi M (1990) Mater Lett 10:1

    Article  CAS  Google Scholar 

  14. Avnir D, Braun S, Lev O, Ottolenghi M (1994) Chem Mater 6:1605

    Article  CAS  Google Scholar 

  15. Zink JI, Valentine JS, Dunn B (1994) New J Chem 18:1109

    CAS  Google Scholar 

  16. Livage J (1996) CR Acad Sci Paris IIb 322:417

    CAS  Google Scholar 

  17. Gill I, Ballesteros A (2000) Trends Biotechnol 18:282; Böttcher H (2000) J Prakt Chem 342:427

  18. Levy D (1996) Pure Appl Opt 5:621

    Article  CAS  Google Scholar 

  19. Cintora-Gonzalez O, Estournès C, Guille JL, Grob JJ, Hönerlage B, Lemoigne J, Lévy R, Lutz T, Merle JC, Muller D, Richard M, Rehspringer JL, Schell J, Viart N (2000) New Trends Mater Sci 28:109

    CAS  Google Scholar 

  20. Pospíšil P, Nauš J (1998) J Theor Biol 193:125

    Article  Google Scholar 

  21. Pospíšil P, Skotnica J, Nauš J (1998) Biochim Biophys Acta 1363:95

    Article  Google Scholar 

  22. Brinker CJ, Scherer GW (1990) Sol-gel science: The Physics and Chemistry of the sol-gel processing. Academic Press, New York

    Google Scholar 

  23. Avnir D, Levy D, Reisfeld R (1984) J Chem Phys 88:5956

    Article  CAS  Google Scholar 

  24. Avnir D, Kaufman VR, Reisfeld R (1985) J Non-Cryst Solids 74:395

    Article  CAS  Google Scholar 

  25. Whitehurst C, Shaw DJ, King TA (1990) SPIE Proc Sol–gel Optics 1328:183

    CAS  Google Scholar 

  26. Salin F, Le Saux G, Georges P, Brun A, Bagnall C, Zarzycki J (1989) Opt Lett 14:785

    CAS  Google Scholar 

  27. Kobayashi Y, Imai Y, Kurokawa Y (1988) J Non-Cryst Solids 105:198

    Article  CAS  Google Scholar 

  28. Altshuler GB, Bakhanos VA, Dulneva EG, Erofeev AV, Mazurin OV, Roskova GP, Tsckhomskaya TS (1987) Opt Spectrosc USSR 62:709

    Google Scholar 

  29. Dunn B, Mackenzie JD, Zink JI, Stafsudd OM (1990) SPIE Proc Sol-gel Optics 1328:174

    CAS  Google Scholar 

  30. Martínez JR, Ruiz F, Vorobiev YV, Pérez-Robles F, González-Hernández J (1998) J Chem Phys 109:7511

    Article  Google Scholar 

  31. Gross J (1991) Pigment in vegetables: Chlorophyll and carotenoids. Van Nostrand Reinhold, New York

    Google Scholar 

  32. Steffen R (2003) Time-resolved spectroscopic investigation of photosystem II, Thesis: Doktor der Naturwissenschaften, Technischen Universität, Berlin

    Google Scholar 

  33. Briantais JM, Vernotte C, Krause GH, Weiss E (1986) In light emission by plants and bacteria. Academic Press, New York, pp 539–583

    Google Scholar 

  34. Baker NR, Webber AN (1987) Adv Bot Res 13:1

    Article  CAS  Google Scholar 

  35. Groot ML, Frese RN, de Weerd FL, Bromek K, Pettersson A, Peterman EJG, van Stokkum IHM, van Grondelle R, Dekker JP (1999) Biophys J 77:3328

    CAS  Google Scholar 

  36. Peterman EJG, van Amerongen H, van Grondelle R, Dekker JP (1998) Proc Natl Acad Sci USA 95:6128

    Article  CAS  Google Scholar 

  37. Ilík P, Kouřil R, Fiala J, Nauš J, Vácha F (2000) J Photochem Photobiol 59:103

    Article  Google Scholar 

  38. Screiber U, Berry JA (1977) Planta 136:233

    Article  Google Scholar 

Download references

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Correspondence to J. R. Martínez.

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Vázquez-Durán, A., Araujo-Andrade, C., Castañón, G.M. et al. Spectral characterization of chlorophyll fluorescence in extract of barley leaves embedded in silica xerogel matrix. J Sol-Gel Sci Technol 39, 223–227 (2006). https://doi.org/10.1007/s10971-006-7877-x

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